GUO Chunli, YU Xiaofeng, HAN Fang, et al. Determination of 19 Organophosphorus Pesticide Residues in Green Tea by Magnetic Solid Phase Extraction Combined with Ultra High Performance Liquid Chromatography Tandem Mass Spectrometry[J]. Science and Technology of Food Industry, 2024, 45(3): 253−261. (in Chinese with English abstract). doi: 10.13386/j.issn1002-0306.2023030116.
Citation: GUO Chunli, YU Xiaofeng, HAN Fang, et al. Determination of 19 Organophosphorus Pesticide Residues in Green Tea by Magnetic Solid Phase Extraction Combined with Ultra High Performance Liquid Chromatography Tandem Mass Spectrometry[J]. Science and Technology of Food Industry, 2024, 45(3): 253−261. (in Chinese with English abstract). doi: 10.13386/j.issn1002-0306.2023030116.

Determination of 19 Organophosphorus Pesticide Residues in Green Tea by Magnetic Solid Phase Extraction Combined with Ultra High Performance Liquid Chromatography Tandem Mass Spectrometry

More Information
  • Received Date: March 12, 2023
  • Available Online: November 25, 2023
  • Magnetic graphene (Fe3O4@G) was synthesized as a magnetic solid phase extractor for the extraction and enrichment of organophosphorus pesticides in green tea by chemical coprecipitation method. Based on this, ultra high performance liquid chromatography tandem mass spectrometry method was developed for the determination of 19 organophosphorus pesticide residues in green tea. 40 mg adsorbent and 4 g sodium chloride were used in this experiment with the pH of sample solution at 7 for 20 min extraction time, 3.0 mL acetone desorption. The result showed that the prepared Fe3O4@G material had good stability and reusability with the linear correlation coefficients greater than 0.999 in the range of 5~500 μg/L. The limits of detection (LOD) and the limits of quantitation (LOQ) were 5.0~6.0 μg/kg and 15.0~20.0 μg/kg, respectively. The recoveries were between 61.2% and 94.9% with the relative standard deviations (RSD, n=6) in the range of 2.6%~10.2% when the samples were labeled at 20.0, 40.0 and 200.0 μg/kg. This method was safe and economy with a wide application range, easier control of pretreatment, less amount of organic solvent and reusable materials, which has a good application prospect in the enrichment and separation of pesticides in tea by the magnetic dispersion solid phase extraction technology.
  • [1]
    NARENDERAN S T, MEYYANATHAN S N, BABU B. Review of pesticide residue analysis in fruits and vegetables pre-treatment, extraction and detection techniques[J]. Food Research International,2020,133:109141. doi: 10.1016/j.foodres.2020.109141
    [2]
    赵广西, 刘志梅. 磁性石墨烯分散固相萃取测定水果中多种农药的残留量[J]. 食品安全导刊,2021,56(24):104−106. [ZHAO G X, LIU Z M. Determination of pesticide residues in fruit by magnetic graphene dispersed solid phase extraction[J]. China Food Safety,2021,56(24):104−106. doi: 10.16043/j.cnki.cfs.2021.24.056

    ZHAO G X, LIU Z M. Determination of pesticide residues in fruit by magnetic graphene dispersed solid phase extraction[J]. China Food Safety, 2021, 5624): 104106. doi: 10.16043/j.cnki.cfs.2021.24.056
    [3]
    朱凤, 丁荣, 徐浩, 等. 三维石墨烯金属网固相萃取测定有机磷农药残留[J]. 分析测试技术与仪器,2021,27(3):149−157. [ZHU F, DING R, XU H, et al. Three-dimensional graphene-based stainless-steel mesh as solid-phase extraction material for determination of organophosphorus pesticides[J]. Analy and Testing Eechnilogy and Instruments,2021,27(3):149−157.

    ZHU F, DING R, XU H, et al. Three-dimensional graphene-based stainless-steel mesh as solid-phase extraction material for determination of organophosphorus pesticides[J]. Analy and Testing Eechnilogy and Instruments, 2021, 273): 149157.
    [4]
    富利祥, 卓晓聪, 徐峰, 等. 测定人血中有机磷农药[J]. 中国法医学杂质,2022,37(6):565−570. [FU L X, ZHUO X C, XU F, et al. Determination of organophosphorus pesticides in human blood[J]. Chinese Journal of Forensic Medicine,2022,37(6):565−570.

    FU L X, ZHUO X C, XU F, et al. Determination of organophosphorus pesticides in human blood[J]. Chinese Journal of Forensic Medicine, 2022, 376): 565570.
    [5]
    TEODORO M, BRIGUGLIO G, FENGA C, et al. Genetic polymorphisms as determinants of pesticide toxicity:Recent advances[J]. Toxicology Reports,2019,6:564−570. doi: 10.1016/j.toxrep.2019.06.004
    [6]
    吴肖肖, 梅秀明, 蒋迪尧, 等. 碳纳米材料在有机磷农药检测样品前处理中的应用研究进展[J]. 食品科技,2022,47(3):318−323. [WU X X, MEI X M, JIANG D Y, et al. Progress on application of carbon nanomaterials in sample pretreatment for organophosphorus pesticide detection[J]. Food Science and Technology,2022,47(3):318−323. doi: 10.3969/j.issn.1005-9989.2022.3.spkj202203046

    WU X X, MEI X M, JIANG D Y, et al. Progress on application of carbon nanomaterials in sample pretreatment for organophosphorus pesticide detection[J]. Food Science and Technology, 2022, 473): 318323. doi: 10.3969/j.issn.1005-9989.2022.3.spkj202203046
    [7]
    张玉琪, 张瑾如, 王锋, 等. 对硫磷纳米抗体筛选及分子识别机制研究[J]. 分析化学,2019,47(9):1419−1428. [ZHANG Y Q, ZHANG J R, WANG F, et al. Selection of nanobody and recognition mechanism between nanobody and parathion[J]. Chinese Journal of Analytical Chemistry,2019,47(9):1419−1428.

    ZHANG Y Q, ZHANG J R, WANG F, et al. Selection of nanobody and recognition mechanism between nanobody and parathion[J]. Chinese Journal of Analytical Chemistry, 2019, 479): 14191428.
    [8]
    冯春, 石志红, 吴兴强, 等. 加速溶剂萃取结合气相色谱三重四极杆质谱测定枸杞中有机磷农药多残留[J]. 分析测试学报,2019,38(4):417−422. [FENG C, SHI Z H, WU X Q, et al. Determination of organophosphorus pesticide residues in chinese wolfberry by gas chromatography-triple quadrupole mass spectrometry with accelerated solvent extraction[J]. Journal of Instrumental Analysis,2019,38(4):417−422.

    FENG C, SHI Z H, WU X Q, et al. Determination of organophosphorus pesticide residues in chinese wolfberry by gas chromatography-triple quadrupole mass spectrometry with accelerated solvent extraction[J]. Journal of Instrumental Analysis, 2019, 384): 417422.
    [9]
    中华人民共和国国家卫生和计划生育委员会, 中华人民共和国农业部, 国家食品药品监督管理总局. GB 2763-2021 食品安全国家标准 食品中农药最大残留限量[S]. 北京:中国标准出版社, 2021. [National Health and Family Planning Commission, People's Republic of China, Ministry of Agriculture of the People's Republic of China, State Food and Drug Administration. GB 2763-2021 National food safety standard-maximum residue limits for pesticides in food[S]. Beijing:China Standards Press, 2021.

    National Health and Family Planning Commission, People's Republic of China, Ministry of Agriculture of the People's Republic of China, State Food and Drug Administration. GB 2763-2021 National food safety standard-maximum residue limits for pesticides in food[S]. Beijing: China Standards Press, 2021.
    [10]
    丁浩东, 万红友, 秦攀, 等. 环境中有机磷农药污染状况、来源及风险评价[J]. 环境化学, 2019, 38(3):463−479. [DING H D, WAN H Y, QIN P, et al. Pollution status, sources and risk assessment of organophosphorus pesticides in the environment[J]. Environmental Chemistry, 2019, 38(3):463-479.
    [11]
    AZZOUZ A, KAILASA S K, IEE S S, et al. Review of nanomaterials as sorbents in solid-phase extraction for environmental samples[J]. TrAC Trends in Analytical Chemistry,2018,108:347−369. doi: 10.1016/j.trac.2018.08.009
    [12]
    AMIRI A, TAYEBEE R, ABDAR A, et al. Synthesis of a zinc-based metal-organic framework with histamine as an organic linker for the dispersive solid-phase extraction of organophosphorus pesticides in water and fruit juice samples[J]. Journal of Chomatography A,2019,1597:39−45.
    [13]
    PANG L, IANG P J, PANG R, et al. Ionogel-based ionic liquid coating for solid-phase microextraction of organophos-phorus pesticides from wine and juice samples[J]. Food Analytical Methods,2018,11(1):270−281.
    [14]
    JIA C H, ZHUX D, WANG J H, et al. Combination of dispersive solid-phase extraction and salting-out homogeneous liquid-iquid extraction for the determination of organophosphorus pesticides in cereal grains[J]. Journal of Separation Science,2014,37(14):1862−1866. doi: 10.1002/jssc.201400251
    [15]
    CHEN B, WU F Q, WU W D, et al. Determination of 27 pesticides in wine by dispersive liquid-liquid microextraction and gas chomatography-mass spectrometry[J]. Microchemical Journal,2016,126:415−422. doi: 10.1016/j.microc.2015.11.003
    [16]
    CACHO J I, CAMPIILO N, VIÑAS P, et al. In situ ionic liquid dispersive liquid-liquid microextraction coupled togas chromatography-mass spectrometry for the determination of organophosphorus pesticides[J]. Journal of Chromatography A,2018,1559:95−101. doi: 10.1016/j.chroma.2017.12.059
    [17]
    MAO X J, YAN A P, WANY Q, et al. Dispersive solid-phase extraction using micmpomus sorbent UiO-66 coupled to gas chromatography tandem mass spectrometry:A QuEChERS type method for the determination of organophosphorus pesticide residues in edible vegetable oils without matrix interfernce[J]. Journal of Agricultural and Food Chemistry,2019,67(6):1760−1770. doi: 10.1021/acs.jafc.8b04980
    [18]
    古飞燕, 邹玉婷, 段宁馨, 等. 茶叶中有机磷农药残留检测前处理技术的研究进展[J]. 食品科技,2022,47(4):335−442. [Gu F Y, ZHOU Y T, DUAN N X, et al. Research progress on pretreatment technology of detecting organophosphorus pesticides in tea[J]. Food Science and Technology,2022,47(4):335−442.

    Gu F Y, ZHOU Y T, DUAN N X, et al. Research progress on pretreatment technology of detecting organophosphorus pesticides in tea[J]. Food Science and Technology, 2022, 474): 335442.
    [19]
    ASFARAM A, DIL E A, ARABKHANI P, et al. Magnetic Cu:CuO-GO nanocomposite for efficient dispersive micro-solid phase extraction of polycyclic aromatic hydrocarbons from vegetable, fruit, and environmental water samples by liquid chromatographic determination[J]. Talanta,2020,218:121131. doi: 10.1016/j.talanta.2020.121131
    [20]
    HE X Q, CUI Y Y, ZHANG Y, et al. Fabrication of magnetic polydopamine@naphthyl microporous organic network nanosphere for efficient extraction of hydroxylated polycyclic aromatic hydrocarbons and p-nitrophenol from wastewater samples[J]. Journal of Chromatography A,2021,1651:462347. doi: 10.1016/j.chroma.2021.462347
    [21]
    彭俊标, 马晓国, 陈圆. 聚乙烯亚胺修饰磁性纳米材料固相萃取-火焰原子吸收光谱法测定水样中痕量Mo(VI)[J]. 分析测试学报,2021,40(6):960−964. [PENG J B, MA X G, CHEN Y. Determination of trace Mo(VI) in water samples by flame atomic absorption spectrometry with poly ethyleneimine modified magnetic nanomaterials based solid phase extraction[J]. Journal of Instrumental Analysis,2021,40(6):960−964.

    PENG J B, MA X G, CHEN Y. Determination of trace Mo(VI) in water samples by flame atomic absorption spectrometry with poly ethyleneimine modified magnetic nanomaterials based solid phase extraction[J]. Journal of Instrumental Analysis, 2021, 406): 960964.
    [22]
    CAI K Q, ZHENG M X, XU H, et al. Gellan gum/graphene oxide aerogels for methylene blue purification[J]. Carbohydrate Polymers,2021,257:117624. doi: 10.1016/j.carbpol.2021.117624
    [23]
    ZHAN W W, ZHU M, LAN J L, et al. Sb2S3@nitrogen-doped carbon coaxial nanotubes uniformly encapsulated with in 3D porous graphene aerogel for fast and stable sodium storage[J]. Chemical Engineering Journal,2021,408:128007. doi: 10.1016/j.cej.2020.128007
    [24]
    WU Q, WU W, ZHAN X X, et al. Three-dimensional chitosan/graphene oxide aerogel for high efficiency solid-phase extraction of acidic herbicides in vegetables[J]. New Journal of Chemistry,2020,44(25):10654−10661. doi: 10.1039/D0NJ01960G
    [25]
    汤振华, 阅都盛. 四氧化三铁/还原氧化石墨烯合成及其在有机磷农药检测中应用研究[J]. 食品工业科技,2014,21(57):306−315. [TANG Z H, YUE D S. Synthesis of Fe3O4/reduced graphene oxide and its application in the determination of organophosphorus pesticide[J]. Science and Technology of Food Industry,2014,21(57):306−315.

    TANG Z H, YUE D S. Synthesis of Fe3O4/reduced graphene oxide and its application in the determination of organophosphorus pesticide[J]. Science and Technology of Food Industry, 2014, 2157): 306315.
    [26]
    何晓明, 余鹏飞, 陈可, 等. 磁性石墨烯/ β-环糊精复合材料固相萃取-HPLC-MS/MS法检测饲料中的6中镇静剂和5种 β-受体激动剂[J]. 江苏农业科学,2019,47(24):188−193. [HE X M, YU P F, CHEN K, et al. Determination of 6 sedatives and 5 β-agonists in feed by magnetic graphene/ β-cyclodextrin composite solid phase extraction-HPLC-MS/MS method[J]. Jiangsu Agricultural Sciences,2019,47(24):188−193.

    HE X M, YU P F, CHEN K, et al. Determination of 6 sedatives and 5β-agonists in feed by magnetic graphene/β-cyclodextrin composite solid phase extraction-HPLC-MS/MS method[J]. Jiangsu Agricultural Sciences, 2019, 4724): 188193.
    [27]
    白云, 李琴梅, 刘奕忍, 等. 石墨烯材料表面含氧官能团的表征研究[J]. 分析仪器,2020(4):83−88 [BAI Y, LI Q M, LIU Y R, et al. Analysis of oxygencontaining functional groups on the surface of graphene material[J]. Analytical Instrumentation,2020(4):83−88.

    BAI Y, LI Q M, LIU Y R, et al. Analysis of oxygencontaining functional groups on the surface of graphene material[J]. Analytical Instrumentation, 20204): 8388.
    [28]
    董婵婵, 胡艳云, 吕亚宁, 等. 磁性石墨烯分散微固相萃取-液相色谱-四极杆串联质谱法测定畜禽肉中9 种非甾体抗炎剂[J]. 色谱,2016,34(9):850−859. [DONG C C, HU Y Y, LÜ Y N, et al. Magnetic graphene based dispersive micro -solid-phase extractioncoupled with liquid chromatography-tandemquadrupole mass spectrometry for the analysis of nine non steroidal anti-inflammatory drugs in livestock andpoultry meat[J]. Chinese Journal of Chromatography,2016,34(9):850−859. doi: 10.3724/SP.J.1123.2016.04039

    DONG C C, HU Y Y, LÜ Y N, et al. Magnetic graphene based dispersive micro -solid-phase extractioncoupled with liquid chromatography-tandemquadrupole mass spectrometry for the analysis of nine non steroidal anti-inflammatory drugs in livestock andpoultry meat[J]. Chinese Journal of Chromatography, 2016, 349): 850859. doi: 10.3724/SP.J.1123.2016.04039
    [29]
    HUMMER JR W S, OFFEMAN R E. Preparation of graphitic oxide[J]. Journal of the American Chemical Society,1958,80(6):1339. doi: 10.1021/ja01539a017
    [30]
    YANG H F, LI F H, SHAN C S. Covalent functionalization of chemically converted graphene sheets via silane and its reinforcement[J]. Journal of Materials Chemistry,2009,19(26):4632−4638. doi: 10.1039/b901421g
    [31]
    ZHAO Y B, QIU Z M, HUANG J Y. Preparation and analysis of Fe3O4 magnetic nanoparticles used as targeted-drug carriers[J]. Chinese Journal of Chemical Engineering,2008,16(3):451−455. doi: 10.1016/S1004-9541(08)60104-4
    [32]
    国家卫生健康委员会, 农业农村部, 国家市场监督管理总局. GB 23200.121-2021 《食品安全国家标准 植物源性食品中331种农药及其代谢物残留量的测定 液相色谱-质谱联用法》[S]. 北京:中国标准出版社, 2021. [National Health Commission, Ministry of Agriculture and Rural Affairs, State Administration for Market Supervision and Administration. GB 23200.121-2021 National food safety standard Determination of 331 pesticides and metabolites residues in foods of plant origin-liquid chromatography-tandem mass spectrometry method[S]. Beijing:China Standards Press, 2021.

    National Health Commission, Ministry of Agriculture and Rural Affairs, State Administration for Market Supervision and Administration. GB 23200.121-2021 National food safety standard Determination of 331 pesticides and metabolites residues in foods of plant origin-liquid chromatography-tandem mass spectrometry method[S]. Beijing: China Standards Press, 2021.
    [33]
    刘丽文, 李炳志, 曹晓林, 等. 基于金属有机骨架的磁固相萃取-高效液相色谱串联质谱法测定环境水样中的有机磷农药[J]. 烟台大学学报(自然科学与工程版),2022,35(1):19−27. [LIU L W, LI B Z, CAO X L, et al. Determination of organophosphorus pesticides in environmental water samples by high performance liquid chromatography-tandem mass spectrometry with magnetic solid phase extraction based on metal-organic frame works[J]. Jourmal of Yantai University ( Natural Science and Engineering Edition),2022,35(1):19−27.

    LIU L W, LI B Z, CAO X L, et al. Determination of organophosphorus pesticides in environmental water samples by high performance liquid chromatography-tandem mass spectrometry with magnetic solid phase extraction based on metal-organic frame works[J]. Jourmal of Yantai University ( Natural Science and Engineering Edition), 2022, 351): 1927.
    [34]
    AFKHAMI A, MOOSAVI R. Cloud point extraction for the spectrophotometric determination of phosphorus(V) in water samples[J]. Journal of Hazardous Materials,2009,167(174):752−755.
    [35]
    操江飞, 谢春生, 李志安, 等. 碳气凝胶分散固相萃取-气相色谱法检测蔬果中有机磷农药残留[J]. 食品科学,2022,44(20):387−392. [CAO J F, XIE C S, LI Z A, et al. Determination of organophosphorus pesticide residues in vegetables based on carbon aerogel dispersive solid phase extraction-gas chromatography[J]. Food Science,2022,44(20):387−392.

    CAO J F, XIE C S, LI Z A, et al. Determination of organophosphorus pesticide residues in vegetables based on carbon aerogel dispersive solid phase extraction-gas chromatography[J]. Food Science, 2022, 4420): 387392.
    [36]
    韩芳, 胡艳云, 张磊, 等. 虚拟分子印记固相萃取技术检测食品中10中三嗪类除草剂残留[J]. 分析化学,2012,40(11):1648−1653. [HAN F, HUY Y, ZHANG L, et al. Determination of triazanes residues in food dummy moleculary imprinted solid phase extraction based on molecular simulation[J]. Chinese Journal of Analytical Chemistry,2012,40(11):1648−1653.

    HAN F, HUY Y, ZHANG L, et al. Determination of triazanes residues in food dummy moleculary imprinted solid phase extraction based on molecular simulation[J]. Chinese Journal of Analytical Chemistry, 2012, 4011): 16481653.
    [37]
    ZHOU D B, HAN F, DING L, et al. Magnetic C60 nanospheres based solid-phase extraction coupled with isotope dilution gas chromatography-mass spectrometry method for the determination of sixteen polycyclic aromatic hydrocarbons in Chinese herbal medicines[J]. Journal of Chromatography B,2020,1144:122076. doi: 10.1016/j.jchromb.2020.122076
    [38]
    宋仲容, 周翔, 蒋清香, 等. 基于Fe3O4@SiO2@NH2@C60的磁固相萃取/气相色谱-质谱联用检测中药材中多环芳烃[J]. 分析测试学报,2023,42(2):131−140. [SONG Z R, ZHOU X, JIANG Q X, et al. Determination of polycyclic aromatic hydrocarbons in chinese herbal medicines by gas chromatography-mass spectrometry with Fe3O4@SiO2@NH2@C60 magnetic solid phase extraction[J]. Journal of Instrumental Analysis,2023,42(2):131−140.

    SONG Z R, ZHOU X, JIANG Q X, et al. Determination of polycyclic aromatic hydrocarbons in chinese herbal medicines by gas chromatography-mass spectrometry with Fe3O4@SiO2@NH2@C60 magnetic solid phase extraction[J]. Journal of Instrumental Analysis, 2023, 422): 131140.
  • Related Articles

    [1]ZHENG Wei, ZHANG Xiangzhao, DENG Xinfeng, MA Jingwen, LU Zhoumin. Optimization of Loquat Puree Color Protection Formula and Quality Change During Storage[J]. Science and Technology of Food Industry, 2024, 45(14): 184-193. DOI: 10.13386/j.issn1002-0306.2023080271
    [2]TONG Moru, LI Peipei, ZHANG Wei, YU Hao, WU Deling. Optimization of Composite Coating Film for Optimal Color Protection Process of Scraped Ginger by Response Surface Methodology[J]. Science and Technology of Food Industry, 2023, 44(24): 175-182. DOI: 10.13386/j.issn1002-0306.2023020160
    [3]CHENG Chenyaqiong, ZHAO Pengtao, WANG Xiaoyu, WANG Shengnan, ZHAO Qinghao, DU Guorong, HUANG Ke, CHENG Yuwen. Research Progress in the Browning Mechanism of Apple Juice and Their Color Protection Mechanism by Antioxidants[J]. Science and Technology of Food Industry, 2022, 43(18): 447-455. DOI: 10.13386/j.issn1002-0306.2021080291
    [4]YANG Zihan, CHEN Dandan, JI Junfu, CHEN Fang, LIAO Xiaojun, WU Jihong, MA Lingjun, HU Xiaosong. Research Progress on Non-enzymatic Browning Mediated by Polyphenols in Fruit and Vegetable Juice[J]. Science and Technology of Food Industry, 2021, 42(24): 367-375. DOI: 10.13386/j.issn1002-0306.2020080207
    [5]XU Jia, TU Zhihong, YANG Jianfei, HUANG Xueqin, MA Qian, YI Yuan, ZUO Yong. Optimization of Compound Color-preserving Agent to Inhibit Browning of Apricot Wine[J]. Science and Technology of Food Industry, 2021, 42(12): 168-175. DOI: 10.13386/j.issn1002-0306.2020080187
    [6]WU Min, HU Zhuo-yan. Effects of packaging materials on the quality and non-enzymatic browning of litchi juice during storage[J]. Science and Technology of Food Industry, 2018, 39(7): 202-209. DOI: 10.13386/j.issn1002-0306.2018.07.037
    [7]WANG Zhao-yu, CHI Xue-wen, BI Yan-hong, ZHAO Xiang-jie, FU Rui-ping, LI Ning-yang. Optimization of anti-browning technology of Agaricus bisporus by response surface methodology[J]. Science and Technology of Food Industry, 2017, (16): 167-171. DOI: 10.13386/j.issn1002-0306.2017.16.031
    [8]HU Yun-feng, TANG Yu-xuan, LI Ning-ning, HU Han-yan, ZHU Yan-hua, . Study on browning reaction in hot air drying processing of Lycium barbarum[J]. Science and Technology of Food Industry, 2016, (22): 159-163. DOI: 10.13386/j.issn1002-0306.2016.22.023
    [9]LIU Xuan, ZHAO Li-qin. Research of sulfur free color protecting liquid on color keeping effects of freeze dried apricot[J]. Science and Technology of Food Industry, 2014, (15): 286-288. DOI: 10.13386/j.issn1002-0306.2014.15.054
    [10]ZHANG Yue-ting, CHEN Zhong, LIN Wei-feng. Study on the control of non-enzymatic browning of papaya candied fruit[J]. Science and Technology of Food Industry, 2014, (02): 255-258. DOI: 10.13386/j.issn1002-0306.2014.02.050
  • Other Related Supplements

  • Cited by

    Periodical cited type(11)

    1. 吕素媛,商冰清,孙璐颜,刘国龙,赵发,梁秀清,吴秋,耿越. 微波辅助萃取油松松针精油的工艺优化及抗氧化活性研究. 食品工业科技. 2025(02): 184-191 . 本站查看
    2. 向晨曦,付文军,张阳阳,孙鹤,赵子旭,焦豫慧. 信阳茶树花精油的成分、抗氧化性及抑菌作用分析. 食品工业. 2024(03): 279-283 .
    3. 卢泳强,周朝曦,张丽丽,俞永婷,娜迪热木·肖克拉提,王新玲,丛媛媛. 苹果果胶的理化特性、抗氧化及降血脂作用研究. 食品与发酵工业. 2024(07): 61-68 .
    4. 陈丹燕,罗雯萃,黎凤玲,李海花,张沛清,刘惠娜,许良政,吕汉清. 基于GC-MS结合ROAV法分析不同柚皮精油挥发性成分及其特征香型物质. 广东化工. 2024(13): 130-133+137 .
    5. 王祎赫,夏燕莉,张欣,杨航,梅国富,余波,易建明,薛慧玲. 佛手果皮精油的提取工艺优化及其成分与抗氧化活性分析. 食品工业科技. 2023(03): 230-239 . 本站查看
    6. 段雪娟,张潼,曾洁滢,李晓拉,陈桂涛,程梓轩,韩雅莉,吴克刚. 植物精油的熏蒸抗菌活性及其机理研究. 食品工业科技. 2023(09): 135-145 . 本站查看
    7. 郑璇杏,佘溢彬,蔡杏粧,王彦瑶,刘燕妮. 浅谈国内儿童化妆品中的常见植物提取物及其质量管控. 山东化工. 2023(04): 151-153 .
    8. 司喜艳,王香玉,皇甫新燕,王琦,赵仁勇. 油茶籽饼中茶皂苷的超声-微波辅助法提取工艺优化. 中国油脂. 2023(07): 130-136 .
    9. 宗宪春,石芮,吴海悦,张雨馨,习秋香. 金盏花提取物的生物学功能及其在动物生产中的应用研究进展. 饲料研究. 2023(18): 183-187 .
    10. 丁岗芯,尹金芳,崔恩浩,邹维,石峰,赵建松,熊华斌,杨志,高云涛. 基于原位反应性顶空系统对金花清感颗粒挥发油抗氧化活性研究. 中草药. 2022(13): 3972-3979 .
    11. 郑雨欣,叶心慧,廖明江,叶智贤,潘育方. 复方山茶花精华油的制备及护肤功效. 广东化工. 2022(15): 40-42 .

    Other cited types(7)

Catalog

    Article Metrics

    Article views (102) PDF downloads (29) Cited by(18)

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return