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中国精品科技期刊2020
王晓婷,康明丽,宋丽君,等. 单宁酸改性明胶脂肪替代物结构及功能性质的研究[J]. 食品工业科技,2022,43(11):104−111. doi: 10.13386/j.issn1002-0306.2021090109.
引用本文: 王晓婷,康明丽,宋丽君,等. 单宁酸改性明胶脂肪替代物结构及功能性质的研究[J]. 食品工业科技,2022,43(11):104−111. doi: 10.13386/j.issn1002-0306.2021090109.
WANG Xiaoting, KANG Mingli, SONG Lijun, et al. Study on Structure and Functional Properties of Tannic Acid Modified Gelatin Fat Substitute[J]. Science and Technology of Food Industry, 2022, 43(11): 104−111. (in Chinese with English abstract). doi: 10.13386/j.issn1002-0306.2021090109.
Citation: WANG Xiaoting, KANG Mingli, SONG Lijun, et al. Study on Structure and Functional Properties of Tannic Acid Modified Gelatin Fat Substitute[J]. Science and Technology of Food Industry, 2022, 43(11): 104−111. (in Chinese with English abstract). doi: 10.13386/j.issn1002-0306.2021090109.

单宁酸改性明胶脂肪替代物结构及功能性质的研究

Study on Structure and Functional Properties of Tannic Acid Modified Gelatin Fat Substitute

  • 摘要: 为了改善明胶在加热过程中因热稳定性差而出现的融化现象,利用单宁酸改性明胶,探究对改性后明胶脂肪替代物结构及功能性质的影响。利用傅里叶变换红外光谱仪(FTIR)、扫描电镜(SEM)、热重分析(TGA)和冻融稳定性、耐蒸煮性、持水性和质构特性等方法探究单宁酸改性明胶脂肪替代物结构及功能性质的变化。结果表明:在pH为5,明胶与单宁酸质量比为1.2:1,36 ℃加热30 min的情况下,单宁酸与明胶之间官能团相互结合,二者发生化学反应,改变明胶的蛋白质结构,微观结构由致密均匀的团状结构改变为疏松多孔的孔隙结构;冻融稳定性和耐蒸煮性增强,持水性和溶胀能力下降,硬度和咀嚼性增强,弹性、凝聚性和胶着性下降,L*a*b*均增加。经过改性后,提高了明胶脂肪替代物热稳定性,改善了明胶脂肪替代物的结构特性,提高产品质地,为多酚改性明胶的脂肪替代物的制备提供理论基础。

     

    Abstract: In order to improve the melting phenomenon of gelatin due to poor thermal stability during heating, gelatin was modified with tannic acid to explore the effects of modified gelatin fat substitutes on the structure and functional properties. Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), thermogravimetric analysis (TGA), freeze-thaw stability, cooking resistance, water holding capacity and texture properties were used to explore the effects of tannic acid modified gelatin fat substitutes on the structure and functional properties. The results showed that when the pH value was 5, the mass ratio of gelatin to tannic acid was 1.2:1, and heated at 36 ℃ for 30 min, the functional groups between tannic acid and gelatin combined with each other, the two reacted and changed the protein structure of gelatin, and the microstructure changed from dense and uniform mass structure to loose and porous pore structure; Freeze thaw stability and cooking resistance increased, water holding capacity and swelling capacity decreased, hardness and chewability increased, elasticity, cohesion and adhesion decreased, and L*, a* and b* increased. After modification, the thermal stability of gelatin fat substitute was improved, the structural characteristics of gelatin fat substitute were improved, and the product texture was improved, which provided a theoretical basis for the preparation of fat substitute of polyphenol modified gelatin.

     

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