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中国精品科技期刊2020
陈涵, 陶阳, 吴越, 罗鑫涛, 韩永斌. 超声波辅助不同吸附剂吸附蓝莓渣花色苷效果的比较[J]. 食品工业科技, 2020, 41(10): 52-57,62. DOI: 10.13386/j.issn1002-0306.2020.10.009
引用本文: 陈涵, 陶阳, 吴越, 罗鑫涛, 韩永斌. 超声波辅助不同吸附剂吸附蓝莓渣花色苷效果的比较[J]. 食品工业科技, 2020, 41(10): 52-57,62. DOI: 10.13386/j.issn1002-0306.2020.10.009
CHEN Han, TAO Yang, WU Yue, LUO Xin-tao, HAN Yong-bin. Effects Comparison of Ultrasound-assisted Adsorption of Anthocyanins from Blueberry Pomace Extracts by Different Adsorbents[J]. Science and Technology of Food Industry, 2020, 41(10): 52-57,62. DOI: 10.13386/j.issn1002-0306.2020.10.009
Citation: CHEN Han, TAO Yang, WU Yue, LUO Xin-tao, HAN Yong-bin. Effects Comparison of Ultrasound-assisted Adsorption of Anthocyanins from Blueberry Pomace Extracts by Different Adsorbents[J]. Science and Technology of Food Industry, 2020, 41(10): 52-57,62. DOI: 10.13386/j.issn1002-0306.2020.10.009

超声波辅助不同吸附剂吸附蓝莓渣花色苷效果的比较

Effects Comparison of Ultrasound-assisted Adsorption of Anthocyanins from Blueberry Pomace Extracts by Different Adsorbents

  • 摘要: 采用超声波(20 kHz)辅助四种不同材料(大孔树脂XAD-7HP、酿酒酵母、活性炭、膨润土)吸附蓝莓渣花色苷,比较在水浴振荡和超声波辅助下不同吸附剂对花色苷的吸附效果,研究其吸附动力学过程,进行动力学模型拟合,并采用红外光谱法分析超声波辅助吸附前后吸附剂结构变化,确定在吸附过程中可能发挥作用的官能团。结果表明:超声波辅助下四种吸附剂对花色苷的吸附量均显著高于水浴振荡(P<0.05),吸附量大小:大孔树脂XAD-7HP>活性炭>膨润土>酿酒酵母;超声作用下酿酒酵母对花色苷吸附量提高程度最大,提高了19.56%,其余吸附剂按超声作用下吸附量提高程度由大到小依次为膨润土、活性炭和树脂,分别提高了16.48%、11.90%和8.62%;与一级动力学模型相比,Lagergren二级动力学模型能更好地拟合这四种吸附剂对花色苷的吸附过程;傅里叶变换红外光谱分析显示在吸附过程中,大孔树脂表面的酚羟基发生了位移,可能用于形成氢键;酿酒酵母中-COOH和-OH参与了吸附过程,可能发生氢键的位移,多糖和酰胺基团也发挥了作用;活性炭吸附花色苷过程受C=C和C-O影响,O-H变形振动或者-CH2变形振动也可能参与其中;膨润土在吸附过程中发生了Si-O的变形和弯曲振动,原-OH吸收峰发生移动,这表明膨润土能成功吸附花色苷的原因可能是氢键发生了位移。

     

    Abstract: Ultrasonic wave(20 kHz)was used to adsorb anthocyanins from blueberry pomace by four different materials(macroporous resin XAD-7HP,Saccharomyces cerevisiae,activated carbon,bentonite). The adsorption effects of different adsorbents on anthocyanin assisted by water bath oscillation and ultrasonic were compared. The adsorption kinetics process was studied and the kinetic model was fitted. Infrared spectroscopy was used to analyze the structural changes of adsorbents before and after ultrasonic-assisted adsorption to find out the functional groups that might play a role in the adsorption process. The results showed that the adsorption capacity of anthocyanin by the four adsorbents was significantly higher than that by water bath oscillation(P<0.05). The ranking of adsorption capacity was macroporous resin XAD-7HP>activated carbon>bentonite>Saccharomyces cerevisiae. Under the action of ultrasound,the adsorption capacity of anthocyanin by Saccharomyces cerevisiae increased by 19.56%,and the other adsorbents were bentonite,activated carbon and resin with the increasing of 16.48%,11.90% and 8.62%,respectively. Compared with the first-order kinetic model,the Lagergren second-order kinetic model could better fit the adsorption process of anthocyanin by the four adsorbents. Fourier transform infrared spectroscopy showed that the phenolic hydroxyl group on the surface of macroporous resin shifted during the adsorption process,which might be used to form hydrogen bond.-COOH and-OH in Saccharomyces cerevisiae were involved in the adsorption process,and the hydrogen bond shift might occur,the polysaccharides and amide groups also played a role. The adsorption process of anthocyanin by activated carbon was affected by C=C and C-O,and O-H deformation vibration or-CH2 deformation vibration might also be involved. The deformation and bending vibration of Si-O occurred in the adsorption process of bentonite,and the absorption peak of original -OH shifted,which indicated that the successful adsorption of anthocyanin by bentonite might be due to the displacement of hydrogen bond.

     

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