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中国精品科技期刊2020
姜波, 胡文忠, 刘长建, 马堃, 王薇. 超声波萃取-原子吸收光谱法测定不同植物油中多种矿物质元素[J]. 食品工业科技, 2013, (14): 63-66. DOI: 10.13386/j.issn1002-0306.2013.14.026
引用本文: 姜波, 胡文忠, 刘长建, 马堃, 王薇. 超声波萃取-原子吸收光谱法测定不同植物油中多种矿物质元素[J]. 食品工业科技, 2013, (14): 63-66. DOI: 10.13386/j.issn1002-0306.2013.14.026
Determination of mineral elements in vegetable oils by atomic absorption with ultrasonication[J]. Science and Technology of Food Industry, 2013, (14): 63-66. DOI: 10.13386/j.issn1002-0306.2013.14.026
Citation: Determination of mineral elements in vegetable oils by atomic absorption with ultrasonication[J]. Science and Technology of Food Industry, 2013, (14): 63-66. DOI: 10.13386/j.issn1002-0306.2013.14.026

超声波萃取-原子吸收光谱法测定不同植物油中多种矿物质元素

Determination of mineral elements in vegetable oils by atomic absorption with ultrasonication

  • 摘要: 研究采用索氏提取法提取了大豆、葵花籽、花生、油菜籽、芝麻、棉籽,以及蓖麻和油桐种的油脂。油样用硝酸和过氧化氢经超声波处理,经过过滤,得到了清澈透明的样品溶液。采用原子吸收光谱法(回收率97.5%~103.8%)测定了所提油中镁、钾、钠、钙、铁、铜、锌、锶和锰含量,在6种食用植物油中白花生油Na/K比值最小,其次为葵花籽油;Ca/Mg和Cu/Zn比值,葵花籽油高于白花生油。从金属元素角度来考虑,对于预防和治疗高血压有益的首选植物油应为葵花籽油。对人体有害的蓖麻油和桐油金属元素含量与食用植物油相当,若食用植物油中添加了蓖麻油和桐油,仅依靠金属元素含量检测是难以鉴别的,应结合油中有机成分的分析加以区分。 

     

    Abstract: Oils were extracted from soybean, sunflower seed, peanut, rapeseed, sesame, castor bean and tung tree seed with Soxhlet extraction method.The oil samples were treated with ultrasonic extraction by adding nitric acid and hydrogen peroxide, the clear transparent sample solutions were obtained after filtrated.The contents of magnesium, potassium, sodium, calcium, iron, copper, zinc, strontium and manganese were determined by atomic absorption spectrometry (recovery ratios of the elements was 97.3% to 103.8%) .Na/K specific value of white peanut oil was the smallest;secondly one was of sunflower seed oil among the six kinds of edible vegetable oils, and Ca/Mg and Cu/Zn specific values of sunflower seed oil were higher than white peanut oil.Therefore sunflower seed oil should be chosen prior for preventing and treating hypertension considering the metallic element content.The metallic element contents of castor oil and tung oil being harmful to human were matched with the six edible vegetable oils, so it was not able to distinguish the oil which was added the them into the edible vegetable oils, and should combine the analysis of organic components.

     

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