LUAN Yueting, ZHU Yingdan, DUAN Zhangqun, et al. Effect of Carnosic Acid on Quality Characteristics of Rapeseed Oil during Thermal Processing[J]. Science and Technology of Food Industry, 2024, 45(15): 45−55. (in Chinese with English abstract). doi: 10.13386/j.issn1002-0306.2023050075.
Citation: LUAN Yueting, ZHU Yingdan, DUAN Zhangqun, et al. Effect of Carnosic Acid on Quality Characteristics of Rapeseed Oil during Thermal Processing[J]. Science and Technology of Food Industry, 2024, 45(15): 45−55. (in Chinese with English abstract). doi: 10.13386/j.issn1002-0306.2023050075.

Effect of Carnosic Acid on Quality Characteristics of Rapeseed Oil during Thermal Processing

More Information
  • Received Date: May 09, 2023
  • Available Online: June 17, 2024
  • In order to reveal the influence of carnosic acid on the quality characteristics of thermal processed rapeseed oil, the changes of color, acid value, peroxide value, tocopherol, viscosity, fatty acid composition and total polar compound were investigated during thermal processing (180 ℃, 0, 8, 16, 24, 32 h) by adding different concentrations of carnosic acid (0, 200, 400, 700 mg/kg) and 200 mg/kg tert-butylhydroquinone as antioxidants. The results indicated that the addition of 700 mg/kg carnosic acid showed a better performance in the thermal processed rapeseed oil: The color deterioration was delayed and the increase of viscosity was inhibited; the increased value of acid value was the smallest which was from 0.280±0.030 mg/g to 0.757±0.020 mg/g, as well as the minimum peroxide value (0.138 g/100 g) was obtained at 32 h; the loss rate of α-tocopherol and γ-tocopherol were 95.51%±0.96% and 83.37%±0.39%, respectively; the content of polar components was 26.62%±0.03%, prolonging the thermal processing life of rapeseed oil by delaying the increase of total polar compound. It was found that the use of carnosic acid could better control the risk factors in rapeseed oil during thermal processing and reduce the waste of oils.
  • [1]
    王瑞元. 2021年我国粮油产销和进出口情况[J]. 中国油脂,2022,47(6):1−7. [WANG R Y. State of grain and oil production sales import and export in 2021[J]. China Oil and Fats,2022,47(6):1−7.]

    WANG R Y. State of grain and oil production sales import and export in 2021[J]. China Oil and Fats, 2022, 47(6): 1−7.
    [2]
    张冉, 曹娟娟, 濮超, 等. 中国油菜籽和菜籽油的生产、进出口及供需分析[J]. 中国油脂,2022,47(6):8−14,52. [ZHANG R, CAO J J, PU C, et al. Supply and demand analysis and development suggestions of rapeseed and rapeseed oil in China[J]. China Oils and Fats,2022,47(6):8−14,52.]

    ZHANG R, CAO J J, PU C, et al. Supply and demand analysis and development suggestions of rapeseed and rapeseed oil in China[J]. China Oils and Fats, 2022, 47(6): 8−14,52.
    [3]
    CHW S H. Cold-pressed rapeseed (Brassica napus) oil:Chemistry and functionality[J]. Food Research International,2020,131(C):108997.
    [4]
    邓龙. 菜籽油特征香气成分和营养物质组成的研究[D]. 南昌:南昌大学, 2017. [DENG L. Study on characteristic aroma components and nutrient composition of rapeseed oil[D]. Nanchang:Nanchang University, 2017.]

    DENG L. Study on characteristic aroma components and nutrient composition of rapeseed oil[D]. Nanchang: Nanchang University, 2017.
    [5]
    YE Z, LIU Y F. Polyphenolic compounds from rapeseeds (Brassica napus L.):The major types, biofunctional roles, bioavailability, and the influences of rapeseed oil processing technologies on the content[J]. Food Research International,2023,163:112282. doi: 10.1016/j.foodres.2022.112282
    [6]
    刘玉兰, 刘海兰, 黄会娜, 等. 煎炸方式和煎炸食材对花生煎炸油中3-氯丙醇酯和缩水甘油酯含量的影响[J]. 食品科学,2019,40(11):42−48. [LIU Y L, LIU H L, HUANG H N, et al. Effects of frying method and frying ingredients on contents of 3-chloropropanol ester and glycidyl ester in frying oil of peanut[J]. Food Science,2019,40(11):42−48.] doi: 10.7506/spkx1002-6630-20180504-042

    LIU Y L, LIU H L, HUANG H N, et al. Effects of frying method and frying ingredients on contents of 3-chloropropanol ester and glycidyl ester in frying oil of peanut[J]. Food Science, 2019, 40(11): 42−48. doi: 10.7506/spkx1002-6630-20180504-042
    [7]
    高浩祥, 陈南, 徐乾达, 等. 油炸过程中茶多酚对油脂品质的影响[J]. 食品科学,2021,42(4):1−7. [GAO H X, CHEN N, XU G D, et al. Effects of tea polyphenols on oil quality during frying[J]. Food Science,2021,42(4):1−7.] doi: 10.7506/spkx1002-6630-20191010-075

    GAO H X, CHEN N, XU G D, et al. Effects of tea polyphenols on oil quality during frying[J]. Food Science, 2021, 42(4): 1−7. doi: 10.7506/spkx1002-6630-20191010-075
    [8]
    LIU Y, TAN J J, DUAN Z H, et al. Effect of oil surface activity on oil absorption behavior of potato strips during frying process[J]. Food Chemistry,2021,365:130427−130427. doi: 10.1016/j.foodchem.2021.130427
    [9]
    KERRIHARD A L, NAGY K, CRAFT B D, et al. Oxidative stability of commodity fats and oils:Modeling based on fatty acid composition[J]. JAOCS, Journal of the American Oil Chemists' Society,2015,92(8):1153−1163. doi: 10.1007/s11746-015-2686-4
    [10]
    YUAN L Y, XU Z Y, TAN C P, et al. Biohazard and dynamic features of different polar compounds in vegetable oil during thermal oxidation[J]. LWT,2021,146:111450. doi: 10.1016/j.lwt.2021.111450
    [11]
    SITI H N, KAMISAH Y, ILIYANI M I N, et al. Citrus leaf extract reduces blood pressure and vascular damage in repeatedly heated palm oil diet-induced hypertensive rats[J]. Biomedicine & Pharmacotherapy,2017,87:451−460.
    [12]
    LIN Y S, LU S Y, WU H P, et al. Is frying oil a dietary source of an endocrine disruptor? Anti-estrogenic effects of polar compounds from frying oil in rats[J]. Ecotoxicology and Environmental Safety,2019,169:18−27. doi: 10.1016/j.ecoenv.2018.10.111
    [13]
    JU J J, ZHENG Z J, XU Y J, et al. Influence of total polar compounds on lipid metabolism, oxidative stress and cytotoxicity in HepG2 cells[J]. Lipids in Health and Disease,2019,18(1):37. doi: 10.1186/s12944-019-0980-0
    [14]
    SAVANI P, PUTHIYEDATH A, RAMESH C K, et al. Evaluation of the sensory properties and antioxidant activity of clean rosemary extracts for an effective replacement of EDTA in mayonnaise[J]. Applied Food Research,2023,3(1):100302. doi: 10.1016/j.afres.2023.100302
    [15]
    MUTSCHLECHNER B, SCHWAIGER S, SCHNEIDER P, et al. Degradation study of carnosic acid[J]. Planta Medica, 2016, 81(S01):1−381.
    [16]
    王莹, 仝飞飞, 薛刚, 等. 迷迭香脂溶性提取物在花生油中抗氧化性能研究[J]. 中国粮油学报, 2021, 36(12):72-77. [WANG Y, TONG F F, XUE G, et al. Antioxidant activity of soluble extract of rosemary in peanut oil [J]. Journal of Cereals and Oils, 2019, 36(12):72−77.]

    WANG Y, TONG F F, XUE G, et al. Antioxidant activity of soluble extract of rosemary in peanut oil [J]. Journal of Cereals and Oils, 2019, 36(12): 72−77.
    [17]
    赵昕. 鼠尾草酸对棕榈油氧化稳定性的影响研究[J]. 食品科技,2019,44(11):222−226. [ZHAO X. Effects of carnosic acid on oxidation stability of palm oil[J]. Food Science and Technology,2019,44(11):222−226.]

    ZHAO X. Effects of carnosic acid on oxidation stability of palm oil[J]. Food Science and Technology, 2019, 44(11): 222−226.
    [18]
    匡婷. 鼠尾草酸对椰子油热氧化稳定性影响研究[D]. 海口:海南大学, 2019. [KUANG T. Effect of carnosic acid on thermal oxidation stability of coconut oil[D]. Haikou:Hainan University, 2019.]

    KUANG T. Effect of carnosic acid on thermal oxidation stability of coconut oil[D]. Haikou: Hainan University, 2019.
    [19]
    HOUSSEM B. Modeling the peroxyl radical scavenging behavior of carnosic acid:Mechanism, kinetics, and effects of physiological environments[J]. Phytochemistry,2021,192:112950. doi: 10.1016/j.phytochem.2021.112950
    [20]
    CHEN J N, WANG Y, LIU W, et al. Effects of free fatty acids and peroxide on thermal loss of sesamol and formation of its transformation products in soybean oil[J]. LWT,2022,159:113136. doi: 10.1016/j.lwt.2022.113136
    [21]
    卫生部. 食品中酸价的测定:GB 5009.229-2016[S]. 北京:中国标准出版社, 2016. [Ministry of Health. Determination of acid value in food:GB 5009.229-2016[S]. Beijing:Standards Press of China, 2016.]

    Ministry of Health. Determination of acid value in food: GB 5009.229-2016[S]. Beijing: Standards Press of China, 2016.
    [22]
    卫生部. 食品中过氧化值的测定:GB 5009.227-2016[S]. 北京:中国标准出版社, 2016. [Ministry of Health. Determination of peroxide value in food:GB 5009.227-2016[S]. Beijing:Standards Press of China, 2016.]

    Ministry of Health. Determination of peroxide value in food: GB 5009.227-2016[S]. Beijing: Standards Press of China, 2016.
    [23]
    卫生部. 动植物油脂 生育酚及生育三烯酚含量测定 高效液相色谱法:GB 26635-2011[S]. 北京:中国标准出版社, 2011. [Ministry of Health. Determination of tocopherol and tocotrienol in animal and vegetable oils by high performance liquid chromatography:GB 26635-2011[S]. Beijing:Standards Press of China, 2011.]

    Ministry of Health. Determination of tocopherol and tocotrienol in animal and vegetable oils by high performance liquid chromatography: GB 26635-2011[S]. Beijing: Standards Press of China, 2011.
    [24]
    卫生部. 食品中脂肪酸的测定:GB 5009.168-2016[S]. 北京:中国标准出版社, 2016. [Ministry of Health. Determination of fatty acids in food:GB 5009.168-2016[S]. Beijing:Standards Press of China, 2016.]

    Ministry of Health. Determination of fatty acids in food: GB 5009.168-2016[S]. Beijing: Standards Press of China, 2016.
    [25]
    卫生部. 食用油中极性组分的测定:GB 5009.202-2016[S]. 北京:中国标准出版社, 2016. [Ministry of Health. Determination of polar components in edible oil:GB 5009.202-2016[S]. Beijing:Standards Press of China, 2016.]

    Ministry of Health. Determination of polar components in edible oil: GB 5009.202-2016[S]. Beijing: Standards Press of China, 2016.
    [26]
    董会娟. 菜籽油煎炸过程中品质变化及氧化稳定性研究[D]. 天津:天津科技大学, 2018. [DONG H J. Study on quality change and oxidation stability of rapeseed oil during frying[D]. Tianjin:Tianjin University of Science and Technology, 2018.]

    DONG H J. Study on quality change and oxidation stability of rapeseed oil during frying[D]. Tianjin: Tianjin University of Science and Technology, 2018.
    [27]
    KETAONA D, CLERGE T. Quality of Ricinodendron heudelotii (Bail.) Pierre ex Pax seedsoil as affected by heating[J]. Int J Eng Res Sci Technol,2013,2:94−100.
    [28]
    CAO J, JIANG X, CHEN Q, et al. Oxidative stabilities of olive and camellia oils:Possible mechanism of aldehydes formation in oleic acid triglyceride at high temperature[J]. LWT,2020,118(C):108858.
    [29]
    SHAZIYA M, MASOODI F A, RUBIYA R, et al. Effect of apple pomace-based antioxidants on the stability of mustard oil during deep frying of French fries[J]. LWT,2022,163:113576. doi: 10.1016/j.lwt.2022.113576
    [30]
    李荣蕊, 袁媛. 复合抗氧化剂对油炸鲜切薯片中丙烯酰胺和氯丙醇酯的抑制作用[J]. 食品安全质量检测学报,2023,14(17):241−251. [LI R R, YUAN Y. Inhibition effect of compound antioxidant on acrylamide and chloropropanol ester in fried fresh cut potato chips[J]. Journal of Food Safety and Quality Inspection,2023,14(17):241−251.]

    LI R R, YUAN Y. Inhibition effect of compound antioxidant on acrylamide and chloropropanol ester in fried fresh cut potato chips[J]. Journal of Food Safety and Quality Inspection, 2023, 14(17): 241−251.
    [31]
    姚梦莹, 匡婷, 云永欢, 等. 鼠尾草酸对椰子油热加工过程中主要理化性质、脂肪酸组成与自由基的影响研究[J]. 中国油脂,2020,45(8):39−44. [YAO M Y, KUANG T, YUN Y H, et al. Effects of carnosic acid on main physicochemical properties, fatty acid composition and free radicals of coconut oil during hot processing[J]. China Oil and Fats,2020,45(8):39−44.] doi: 10.12166/j.zgyz.1003-7969/2020.08.009

    YAO M Y, KUANG T, YUN Y H, et al. Effects of carnosic acid on main physicochemical properties, fatty acid composition and free radicals of coconut oil during hot processing[J]. China Oil and Fats, 2020, 45(8): 39−44. doi: 10.12166/j.zgyz.1003-7969/2020.08.009
    [32]
    JIANG Y F, SU M K, YU T, et al. Quantitative determination of peroxide value of edible oil by algorithm-assisted liquid interfacial surface enhanced Raman spectroscopy[J]. Food Chemistry,2021,344:128709. doi: 10.1016/j.foodchem.2020.128709
    [33]
    徐子扬. 高油酸植物油在加热过程中的组分变化与评价[D]. 无锡:江南大学, 2020. [XU Z Y. Composition change and evaluation of high oleic acid vegetable oil during heating[D]. Wuxi:Jiangnan University, 2020.]

    XU Z Y. Composition change and evaluation of high oleic acid vegetable oil during heating[D]. Wuxi: Jiangnan University, 2020.
    [34]
    UJONG A E, EMELIKE N, OWUNO F, et al. Effect of frying cycles on the physical, chemical and antioxidant properties of selected plant oils during deep-fat frying of potato chips[J]. Food Chemistry Advances,2023,3:100338. doi: 10.1016/j.focha.2023.100338
    [35]
    SIMONA B, PIERRE D, FRANCOIS X P, et al. Carnosic acid[J]. Phytochemistry,2015,115:9−19. doi: 10.1016/j.phytochem.2014.12.026
    [36]
    PAGANI M A, BALTANAS M A. Production of natural antioxidants from vegetable oil deodorizer distillates:Effect of catalytic hydrogenation[J]. Bioresource Technology,2010,101(4):1369−1376. doi: 10.1016/j.biortech.2009.09.068
    [37]
    尹浩, 姜碧若, 曾裕, 等. 迷迭香提取物对一级大豆油煎炸品质的影响[J]. 食品工业,2022,43(2):153−156. [YIN H, JIANG B R, ZENG Y, et al. Effects of rosemary extract on frying quality of primary soybean oil[J]. Food Industry,2022,43(2):153−156.]

    YIN H, JIANG B R, ZENG Y, et al. Effects of rosemary extract on frying quality of primary soybean oil[J]. Food Industry, 2022, 43(2): 153−156.
    [38]
    李徐. 加热和煎炸过程油脂极性物质组成的变化规律及应用研究[D]. 无锡:江南大学, 2021. [LI X. Study on variation and application of polar substance composition of oil in heating and frying process[D]. Wuxi:Jiangnan University, 2021.]

    LI X. Study on variation and application of polar substance composition of oil in heating and frying process[D]. Wuxi: Jiangnan University, 2021.
    [39]
    DAVID A, DAVID M, LESNIAREK P, et al. Oleogelation of rapeseed oil with cellulose fibers as an innovative strategy for palm oil substitution in chocolate spreads[J]. Journal of Food Engineering,2021,292:110315. doi: 10.1016/j.jfoodeng.2020.110315
    [40]
    ZHAO L L, ZHANG M, WANG H X, et al. Effects of carbon dots in combination with rosemary-inspired carnosic acid on oxidative stability of deep frying oils[J]. Food Control,2021,125:107968. doi: 10.1016/j.foodcont.2021.107968
    [41]
    DANIEL P G, JOHN W G. Rheology of vegetable oil analogs and triglycerides[J]. Journal of the American Oil Chemists' Society,2000,77(2):111−114. doi: 10.1007/s11746-000-0018-4
    [42]
    杨雪莲, 张翔宇, 谢建春, 等. 部分食品煎炸用油的反式脂肪酸比较[J]. 中国食品学报,2021,21(1):327−333. [YANG X L, ZHANG X Y, XIE J C, et al. Comparison of trans fatty acids in frying oil of some foods[J]. Chinese Journal of Food Science,2021,21(1):327−333.]

    YANG X L, ZHANG X Y, XIE J C, et al. Comparison of trans fatty acids in frying oil of some foods[J]. Chinese Journal of Food Science, 2021, 21(1): 327−333.
    [43]
    MADIHA D, ZAHRA A, MNARI B A, et al. Comparative study of the phenolic profile and antioxidant activities of Moringa (Moringa oleifera Lam.) and Jujube (Ziziphus lotus Linn.) leaf extracts and their protective effects in frying stability of corn oil[J]. Measurement:Food, 2022, 7:3665−3672.
    [44]
    卫星华, 董曼曼, 李涛, 等. 影响煎炸油中极性组分含量的研究[J]. 食品安全质量检测学报,2018,9(7):1660−1664. [WEI X H, DONG M M, LI T, et al. Study on the influence of polar components content in frying oil[J]. Journal of Food Safety and Quality Inspection,2018,9(7):1660−1664.] doi: 10.3969/j.issn.2095-0381.2018.07.033

    WEI X H, DONG M M, LI T, et al. Study on the influence of polar components content in frying oil[J]. Journal of Food Safety and Quality Inspection, 2018, 9(7): 1660−1664. doi: 10.3969/j.issn.2095-0381.2018.07.033
    [45]
    李鹏娟. 迷迭香源抗氧化物对薯条煎炸油品质的影响研究[D]. 广州:暨南大学, 2021. [LI P J. Effect of rosemary source antioxidants on the quality of fries oil[D]. Guangzhou:Jinan University, 2021.]

    LI P J. Effect of rosemary source antioxidants on the quality of fries oil[D]. Guangzhou: Jinan University, 2021.
    [46]
    LI P, YANG X, LEE J W, et al. Comparison between synthetic and rosemary-based antioxidants for the deep frying of French fries in refined soybean oils evaluated by chemical and non-destructive rapid methods[J]. Food Chemistry,2021,335:127638. doi: 10.1016/j.foodchem.2020.127638
  • Other Related Supplements

  • Cited by

    Periodical cited type(3)

    1. 张敏杰,杨武德,代叶,李玮,魏晴,梁珊珊. 黔产不同商品规格金钗石斛质量评价研究. 亚太传统医药. 2024(04): 39-43 .
    2. 林鑫静,张明,李鑫,周春阳,蒲跃,袁斌,范艺缤,范润勇,夏天琴,尤俊,杨晓曦,胥正敏. 调脏舒秘合剂小鼠急性毒性实验研究. 现代中医药. 2023(02): 91-95 .
    3. 杨吉容,石京山. 金钗石斛破壁粉对自发性高血压大鼠血压及心功能的影响. 遵义医科大学学报. 2022(06): 699-705 .

    Other cited types(2)

Catalog

    Article Metrics

    Article views (78) PDF downloads (22) Cited by(5)

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return