Analysis and Identification of Volatile Profiles in Qinghai Flaxseed Oil by SPME-GC-MS

HAN Yuze; WANG Xingrui; LI Yingxia; WANG Shuzhen; CHEN Yunyun; WANG Jinying

doi:10.13386/j.issn1002-0306.2021010089

Volume 42 Issue 20

Oct. 2021

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Science and Technology of Food Industry > 2021 > 42(20): 255-260. > DOI: 10.13386/j.issn1002-0306.2021010089

HAN Yuze, WANG Xingrui, LI Yingxia, et al. Analysis and Identification of Volatile Profiles in Qinghai Flaxseed Oil by SPME-GC-MS[J]. Science and Technology of Food Industry, 2021, 42(20): 255−260. (in Chinese with English abstract). doi: 10.13386/j.issn1002-0306.2021010089.

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Analysis and Identification of Volatile Profiles in Qinghai Flaxseed Oil by SPME-GC-MS

1.
College of Agriculture and Animal Husbandry, Qinghai University, Xining 810016, China
2.
State Key Laboratory of Plateau Ecology and Agriculture, Qinghai University, Xining 810016, China

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Received Date: January 14, 2021
Available Online: August 15, 2021

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Abstract

Abstract

Flaxseed oil was prepared from 40 kinds of flaxseed of different region in Qinghai by soxhlet extraction. And the volatile profiles were analyzed by headspace sampling combined with GC-MS method. In order to obtain the best solid phase microextraction conditions and GC-MS condition, the stirring rate, extraction temperature, equilibrium time, extraction time, desorption time and heating program were optimized. The results indicated that when using DVB/CAR/PDMS fiber, the optimum extraction conditions of the volatile compounds were: 20 min equilibrium time, 40 min adsorption time at 80 ℃ , stirring intensity of 400 r/min, and 5 min desorption time. Under this extraction condition, a total of 58 volatile components of 40 kinds of flaxseeds oil in Qinghai could be detected, including 12 aldehydes, 8 acids, 9 alcohols, 2 ketones, 5 esters, 13 hydrocarbon compounds, 3 heterocycles and 6 other types, which achieved a good chromatographic separation. According to cluster analysis, aldehydes were the main volatile components that distinguished flaxseed oil samples, which would provide a theoretical basis for the quality identification and development of flaxseed oil.
- flaxseeds oil,
- volatile components,
- headspace solid phase microextraction,
- GC-MS

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References

[1]	Bushra S, Pang Z H, Liu X Q, et al. Structural and functional properties of raw and defatted flaxseed flour and degradation of cynogenic contents using different processing methods[J]. Journal of Food Process Engineering,2020,43(6):e13406.
[2]	Yang R N, Zang L X, Li P W, et al. A review of chemical composition and nutritional properties of minor vegetable oils in China[J]. Trends in Food Science & Technology,2018,74:26−32.
[3]	邹仙果. 亚麻籽环肽组成、氧化结构变化及其体外抗肿瘤抗炎活性研究[D]. 南昌: 南昌大学, 2019. Zou X G. The profiles, structural changes during oxidation and in vitro antitumor and anti-inflammatory activities of linusorbs in flaxseed[D]. Nanchang: Nanchang University, 2019.
[4]	Han Y, Deng X, Zhang Y, et al. Antidepressant-like effect of flaxseed in rats exposed to chronic unpredictable stress[J]. Brain and Behavior,2020,10(6):e01626.
[5]	安骏, 李昌模, 金青哲, 等. 含油溶性营养成分食用油的安全性研究[J]. 粮食与食品工业,2016,23(6):3−7, 12. [An J, Li C M, Jin Q Z, et al. Study on the safety of edible oil with oil soluble nutrients[J]. Cereal & Food Industry,2016,23(6):3−7, 12. doi: 10.3969/j.issn.1672-5026.2016.06.002
[6]	马良, 王若兰. 顶空固相微萃取-气质联用技术在粮油食品中的应用进展[J]. 粮食与油脂,2015,28(1):6−10. [Ma L, Wang R L. Research advances on the application of HS-SPME/GC-MS technology in cereals, oils and foods[J]. Cereals & Oils,2015,28(1):6−10. doi: 10.3969/j.issn.1008-9578.2015.01.002
[7]	Zquezarau J, Verdu A, Navar R, et al. Changes in volatile compounds and sensory quality during toasting of Spanish almonds[J]. Int J Food Sci Tech,2009,44(11):2225−2233. doi: 10.1111/j.1365-2621.2009.02063.x
[8]	Lasekan O, Abbas K. Analysis of volatile flavour compounds and acrylamide in roasted Malaysian tropical almond(Terminalia catappa) nuts using supercritical fluid extraction[J]. Food Chem Toxicol,2010,48(8/9):2212−2216.
[9]	Curtis M, Kalua, Danny R, et al. Development of a headspace solid phase microextraction-gas chromatography method for monitoring volatile compounds in extended time-course experiments of olive oil[J]. Analytica Chimica Acta,2005,556(2):407−414.
[10]	Min H P, Min K J, Ju D Y, et al. Application of solid phase-microextraction(SPME) and electronic nose techniques to differentiate volatiles of sesame oils prepared with diverse roasting conditions[J]. Journal of Food Science,2011,76(1):80−88. doi: 10.1111/j.1750-3841.2010.01954.x
[11]	周波, 孙亚娟, 王进英, 等. 茶油挥发性成分指纹图谱的构建及掺伪定量检测方法研究[J]. 中南林业科技大学学报,2017,37(9):118−123. [Zhou B, Sun Y J, Wang J Y, et al. Detection method research on adulteration of Camellia seed oil based on fingerprint of volatile components[J]. Journal of Central South University of Forestry & Technology,2017,37(9):118−123.
[12]	秦早, 杨冉, 高桂园, 等. 顶空固相微萃取结合气质联用分析芝麻油和芝麻香精的挥发性成分[J]. 食品科学,2012,33(24):263−268. [Qin Z, Yang R, Gao G Y, et al. Analysis of volatile components of sesame oil and sesame flavor by headspace solid phase microextraction combined with GC-MS[J]. Food Science,2012,33(24):263−268. doi: 10.7506/spkx1002-6630-201224056
[13]	Dierkes G, Bongartz A, Guth H, et al. Quality evaluation of olive oil by statistical analysis of multicomponent stable isotope dilution assay data of aroma active compounds[J]. Journal of Agricultural & Food Chemistry,2012,60(1):394−401.
[14]	于文龙, 郝楠, 吴凯晋, 等. HS-SPME-GC-MS-O联用分析不同加工工艺亚麻籽油特征香气成分[J]. 食品科学,2019,40(18):266−272. [Yu W L, Hao N, Wu K J, et al. Analysis of characteristic aroma components of flaxseed oils obtained by different processing techniques by HS-SPME-GC-MS-O[J]. Food Science,2019,40(18):266−272. doi: 10.7506/spkx1002-6630-20181009-073
[15]	杨柳, 吴翠蓉, 朱杰丽, 等. 顶空-气质联用法鉴别油茶籽油真伪[J]. 中国粮油学报,2012,27(11):105−109, 113. [Yang L, Wu C R, Zhu J L, et al. Identification of Camellia seed oil by headspace-GC-MS[J]. Journal of The Chinese Cereals and Oils Association,2012,27(11):105−109, 113. doi: 10.3969/j.issn.1003-0174.2012.11.024
[16]	陈超, 黄景霞, 李梦, 等. 新疆胡麻油香气萃取条件研究[J]. 食品工业科技,2014,35(2):242−246. [Chen C, Huang J X, Li M, et al. Study on extraction conditions of Xinjiang flaxseed oil aroma[J]. Science and Technology of Food Industry,2014,35(2):242−246.
[17]	邓龙, 刘雄飞, 刘贤标, 等. GC-MS-O结合电子鼻对橄榄油挥发性成分的分析与鉴别[J]. 中国食品学报,2019,19(5):276−286. [Deng L, Liu X F, Liu X B, et al. Analysis and identification of volatile components in olive oil by GC-MS-O combined with electronic nose[J]. Journal of Chinese Institute of Food Science and Technology,2019,19(5):276−286.
[18]	李晓颍, 王海静, 徐宁伟, 等. 顶空固相微萃取-气相色谱-质谱联用法分析欧李果实挥发性成分[J]. 中国农业科学,2019,52(19):3448−3459. [Li X Y, Wang H J, Xu N W, et al. Analysis of volatile components of plum fruit by headspace solid phase microextraction-gas chromatography-mass spectrometry[J]. Journal of Integrative Agriculture,2019,52(19):3448−3459. doi: 10.3864/j.issn.0578-1752.2019.19.014
[19]	王丹, 王永瑞, 魏哲文, 等. 顶空固相微萃取结合GC-MS对大豆油香气成分分析[J]. 农产品加工,2020,1:53−55. [Wang D, Wang Y R, Wei Z W, et al. Analysis of soybean oil aroma components by headspace solid phase microextraction combined with GC-MS[J]. Roducts Rocessing,2020,1:53−55.
[20]	芦鑫, 张丽霞, 王奕芳, 等. 不同品种花生乳挥发性组分分析[J]. 中国油脂,2018,43(5):139−144. [Lu X, Zhang L X, Wang Y F, et al. Analysis of volatile omponents in different varieties of peanut milk[J]. China Oils and Fats,2018,43(5):139−144. doi: 10.3969/j.issn.1003-7969.2018.05.032
[21]	王笑园, 宋章弈, 张延琦, 等. 精炼过程对亚麻籽油风味物质的影响[J]. 食品工业科技,2016,37(18):55−59. [Wang X Y, Song Z Y, Zhang Y Q, et al. Influence of refining process on flaxseed oil flavor[J]. Science and Technology of Food Industry,2016,37(18):55−59.
[22]	Franc A, Maurizio S, Roberto S, et al. Volatile compounds in virgin olive oil: Occurrence and their relationship with the quality[J]. Journal of Chromatography A,2004,1054(1):18−27.
[23]	Wei C Q, Liu W Y, Xi W P, et al. Comparison of volatile compounds of hot-pressed, cold-pressed and solvent-extracted flaxseed oils analyzed by SPME-GC/MS combined with electronic nose: Major volatiles can be used as markers to distinguish differently processed oils[J]. J Lipid Sci Technol,2015,117:320−330. doi: 10.1002/ejlt.201400244
[24]	Li X, Gao Y, Chen Z Y, et al. Development of a chromatographic fingerprint of tobacco flavor by use of GC and GC-MS[J]. Chromatographia,2009,69(7−8):735−742. doi: 10.1365/s10337-009-0968-4

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