Determination of 9, 10-Anthraquinone in Tea Packaging Paper by GC-MS/MS

LIANG Jianfeng; LI Ya; WEI Shiqin; QIAO Ruying; CHEN Meiban

doi:10.13386/j.issn1002-0306.2020080128

Volume 42 Issue 12

Jun. 2021

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Science and Technology of Food Industry > 2021 > 42(12): 246-252. > DOI: 10.13386/j.issn1002-0306.2020080128

LIANG Jianfeng, LI Ya, WEI Shiqin, et al. Determination of 9, 10-Anthraquinone in Tea Packaging Paper by GC-MS/MS[J]. Science and Technology of Food Industry, 2021, 42(12): 246−252. (in Chinese with English abstract). doi: 10.13386/j.issn1002-0306. 2020080128.

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Determination of 9, 10-Anthraquinone in Tea Packaging Paper by GC-MS/MS

College of Chemical Engineering and Resource Recycling, Wuzhou University, Wuzhou 543002, China

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Received Date: August 13, 2020
Available Online: June 02, 2021

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Abstract

Abstract

A gas chromatography-mass spectrometry (GC-MS-MS) method was established for the detection of 9, 10-anthraquinone in tea packaging paper. The sample was extracted with acetone-n-hexane mixed solution, and then the extract was concentrated by centrifugation and nitrogen blowing, and then purified by SPE with a Florisil solid phase extraction column. The purified liquid was analyzed by a gas-mass spectrometer. The instrument used DB-5MS gas chromatography. Column (20 m×0.18 mm×0.18 μm) was separated, scanning in multi-reaction monitoring mode was selected, and internal standard method was used for quantification. The results showed that the method had a good linear relationship in the mass concentration range of 10~200 ng/mL, the linear regression equation was Y=0.23249X+0.001203, the fit R² was 0.9989, the detection limit of the method was 3 μg/kg, the limit of quantification was 10 μg/kg, the recovery rate of standard addition was 89.3%~98.7%, and the relative standard deviation (RSD) was 3.01%~4.42%. This method was suitable for the qualitative and quantitative detection of 9, 10-anthraquinone in tea packaging paper.
- tea packaging paper,
- anthraquinone,
- gas chromatography tandem mass spectrometry,
- internal standard method

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References

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