HUANG Dou, CAO Luowen, CEN Yanxiang, et al. Detection of Aroma Components in Three Cultivars of Mango with Headspace Solid Phase Microextraction-Comprehensive Two-dimensional Gas Chromatograph/Time of Flight Mass Spectrometer[J]. Science and Technology of Food Industry, 2021, 42(15): 218−226. (in Chinese with English abstract). doi: 10.13386/j.issn1002-0306.2020070275.
Citation: HUANG Dou, CAO Luowen, CEN Yanxiang, et al. Detection of Aroma Components in Three Cultivars of Mango with Headspace Solid Phase Microextraction-Comprehensive Two-dimensional Gas Chromatograph/Time of Flight Mass Spectrometer[J]. Science and Technology of Food Industry, 2021, 42(15): 218−226. (in Chinese with English abstract). doi: 10.13386/j.issn1002-0306.2020070275.

Detection of Aroma Components in Three Cultivars of Mango with Headspace Solid Phase Microextraction-Comprehensive Two-dimensional Gas Chromatograph/Time of Flight Mass Spectrometer

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  • Received Date: July 22, 2020
  • Available Online: June 01, 2021
  • A headspace solid-phase microextraction coupled with comprehensive two-dimensional gas chromatography time-of-flight mass spectrometer was used to compare different extraction heads, extraction temperature, extraction time, desorption temperature and time on the extraction effect, aroma components of the three mango varieties were analyzed and identified. The results showed that the optimum extraction conditions were as follows: extraction head 50/30 μm DVB/CAR/PDMS, extraction temperature 60 ℃, extraction time 60 min and desorption temperature 250 ℃. With the powerful separation and qualitative capabilities of the comprehensive two-dimensional gas chromatography time-of-flight mass spectrometer, more information about aroma components c be obtained than the conventional one-dimensional gas chromatography mass spectrometer. A total of 170 aroma components were detected in the three types of mangoes. A total of 96, 90 and 68 aroma components were detected in the JinHuang mango, XiaoTai mango and QingPi mango, respectively, and the peak area content of these aroma components accounted for 74.04%, 90.75% and 78.91% of the total volatile components, respectively. In the 170 aroma components, 25 were alcohols, 4 were aromatic hydrocarbons, 15 were aldehydes, 6 were acids, 18 were ketones, 56 were olefins, 46 were esters. Among the 7 kinds of compounds, olefins were found in three kinds of mangoes. The highest content in the golden mango, JinHuang mango contained more esters, aldehydes and alcohols than the other two mangoes, and the corresponding unique aroma components of the QingPi mango were relatively less, which was also golden. This was also the reason why the aroma of JinHuang mango was full-bodied while the aroma of QingPi mango was relatively less aromatic.There were 26 types of aroma components shared by the three types of mangoes, such as terpene olefins, 3-carene, β-laurelene, stigmene, cobalene and γ-ylangene which made up the basic aroma of mangoes, but the contents of common components in different varieties of mango were significantly different. For example, the content of 3-carene in JinHuang mango was significantly higher with 10.783%, and the content of terpinene in XiaoTai mango was significantly higher with 17.545%.
  • [1]
    Engel K H, Tressl R. Studies on the volatile components of two mango varieties[J]. Journal of Agricultural & Food Chemistry,1983,31(4):796−801.
    [2]
    高爱平, 陈业渊, 朱敏, 等. 中国芒果科研进展综述[J]. 中国热带农业,2006(6):21−23. doi: 10.3969/j.issn.1673-0658.2006.06.009
    [3]
    顾承真, 刘菲菲, 姚元成, 等. 芒果叶的化学成分研究[J]. 天然产物研究与开发,2013,25(1):36−39. doi: 10.3969/j.issn.1001-6880.2013.01.008
    [4]
    乜兰春, 孙建设, 黄瑞虹. 果实香气形成及其影响因素[J]. 植物学通报,2004,21(5):631−637.
    [5]
    张涵, 鲁周民, 王锦涛, 等. 4种主要柑橘类香气成分比较[J]. 食品科学,2017,38(4):198−202.
    [6]
    刘传和, 刘岩. 四种芒果香气品质分析[J]. 广东农业科学,2016,43(10):123−127.
    [7]
    张浩, 安可婧, 徐玉娟, 等. 基于电子舌与SPME-GC-MS技术的芒果风味物质的比较分析[J]. 现代食品科技,2018,34(10):214−224.
    [8]
    Liu Z, Phillips J B. Comprehensive two-dimensional gas chromatography using an on-column thermal modulator interface[J]. Journal of Chromatographic Science,1991,29(6):227−231. doi: 10.1093/chromsci/29.6.227
    [9]
    Marriott P J, Shellie R, Cornwell C. Gas chromatographic technologies for the analysis of essential oils[J]. Journal of Chromatography A,2001,936(1):1−22.
    [10]
    花瑞香, 阮春海, 王京华, 等. 全二维气相色谱法用于不同石油馏分的族组成分布研究[J]. 化学学报,2002,60(12):2185−2191. doi: 10.3321/j.issn:0567-7351.2002.12.018
    [11]
    Santos F J, Galceran M T. Modem developments in gas chromatography-mass spectrometry-based environmental analysis[J]. Journal of Chromatography A,2003,1000(1-2):125−151. doi: 10.1016/S0021-9673(03)00305-4
    [12]
    Shellie R, Mondello L, Marriott P, et al. Characterisation of lavender essential oils by using gas chromatography-mass spectrometry with correlation of linear retention indices and comparison with comprehensive two-dimensional gas chromatography[J]. Journal of Chromatography A,2002,970(1-2):225−234. doi: 10.1016/S0021-9673(02)00653-2
    [13]
    吴曼曼, 岑延相, 杨丽华, 等. 用于与全二维气相色谱联用的高通量飞行时间质谱仪的研制[J]. 分析化学,2016(11):1786−1792.
    [14]
    Eganhouse R P, Pontolillo J, Gaines R B, et al. Isomer-specific determination of 4-nonylphenols using comprehensive two-dimensional gas chromatography/time-of-flight mass spectrometry[J]. Environmental Science & Technology,2009,43(24):9306− 9313.
    [15]
    路鑫, 武建芳, 吴建华, 等. 全二维气相色谱/飞行时间质谱用于柴油组成的研究[J]. 色谱,2004,22(1):5−11. doi: 10.3321/j.issn:1000-8713.2004.01.002
    [16]
    Cheong K W, Tan C P, Mirhosseini H, et al. Optimization of equilibrium headspace analysis of volatile flavor compounds of malaysian soursop (Annona muricata): Comprehensive two-dimensional gas chromatography time-of-flight mass spectrometry (GC×GC-TOFMS)[J]. Food Chemistry,2011,125(4):1481−1489. doi: 10.1016/j.foodchem.2010.10.067
    [17]
    Weldegergis B T, Crouch A M, Tadeusz Górecki, et al. Solid phase extraction in combination with comprehensive two-dimensional gas chromatography coupled to time-of-flight mass spectrometry for the detailed investigation of volatiles in South African red wines[J]. Analytica Chimica Acta,2011,701(1):98−111. doi: 10.1016/j.aca.2011.06.006
    [18]
    Gao X, Yang X, Mitrevski B S, et al. Headspace solid-phase microextraction combined with GC×GC-TOFMS for the analysis of volatile compounds of Coptis species rhizomes[J]. Journal of Separation Science,2011,34(10):81−89.
    [19]
    何晓蕾, 俞勇梅, 李咸伟, 等. 全二维气相色谱/飞行时间质谱法快速定性分析飞灰样品中的二噁英[J]. 分析化学,2010,38(7):28−33.
    [20]
    Pangallo K, Nelson R K, Teuten E L, et al. Expanding the range of halogenated 1prime-methyl-1, 2prime-bipyrroles (MBPs) using GC/ECNI-MS and GCxGC/TOF-MS[J]. Chemosphere Oxford,2008,71(8):1557−1565. doi: 10.1016/j.chemosphere.2007.11.051
    [21]
    Torregiani E, Lorier S, Sagratini G, et al. Comparative analysis of the volatile profile of 20 commercial samples of truffles, truffle sauces, and truffle-flavored oils by using HS-SPME-GC-MS[J]. Food Anal Methods,2018,10(6):1857−1862.
    [22]
    王建霞, 郭洪伟, 刘一涵, 等. GC-MS结合保留指数分析轮钟花果实的挥发性成分[J]. 西南民族大学学报,2020,26(4):380−385.
    [23]
    唐会周, 明建, 程月皎, 等. 顶空固相微萃取-气质联用技术分析芒果的芳香成分[J]. 食品科技,2008(5):229−232. doi: 10.3969/j.issn.1005-9989.2008.05.068
    [24]
    Pandi S S, Chidley H G, Kulkarni R S, et al. Cultivar relationships in mango based on fruit volatile profiles[J]. Food Chemistry,2009,114:363−372. doi: 10.1016/j.foodchem.2008.09.107
    [25]
    乜兰春, 孙建设, 黄瑞虹. 果实香气形成及其影响因素[J]. 植物学通报,2004(5):631−637.
    [26]
    张宝明. 芒果香精的调配[J]. 中国食品添加剂,2013(3):198−204. doi: 10.3969/j.issn.1006-2513.2013.03.027
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