蜜柚套袋种植中氯硝胺的迁移规律研究

陈婷茹; 王瑞龙; 陈练洪; 陈泳; 江洲; 傅红

doi:10.13386/j.issn1002-0306.2019090241

蜜柚套袋种植中氯硝胺的迁移规律研究

陈婷茹¹,
王瑞龙²,
陈练洪²,
陈泳²,
江洲³,
傅红^1,4, ,

1. 福州大学生物科学与工程学院, 福建福州 350108;
2. 漳州海关, 福建漳州 363100;
3. 福建天马科技集团股份有限公司, 福建福州 350108;
4. 福州大学福建省海洋酶工程重点实验室, 福建福州 350108

详细信息

作者简介:
陈婷茹(1994-),女,硕士研究生,研究方向:食品安全检测,E-mail:ctr1003533034@163.com。

通讯作者:
傅红(1970-),女,博士,教授,研究方向:食用油脂科学与工程,E-mail:fuhong7766@126.com。

中图分类号: TS255
计量
- 文章访问数: 226
- HTML全文浏览量: 9
- PDF下载量: 20
出版历程
- 收稿日期: 2019-09-19
- 网络出版日期: 2021-03-15
- 刊出日期: 2021-03-14

Migration of Dicloran during Bagging Planting of Honey Pomelo

1. College of Biological Science and Engineering, Fuzhou University, Fuzhou 350108, China;
2. Zhangzhou Customs, Zhangzhou 363100, China;
3. Fujian Tianma Science and Technology Group Co., Ltd., Fuzhou 350108, China;
4. Fujian Provincial Key Laboratory of Marine Enzyme Engineering, Fuzhou University, Fuzhou 350108, China

摘要

摘要: 采用气相色谱-串联质谱法检测套袋纸及蜜柚中氯硝胺的含量，并通过田间试验研究了氯硝胺从五种套袋纸向蜜柚不同部位的迁移规律。结果表明四种含有氯硝胺的套袋纸处理的蜜柚全果中氯硝胺的残留浓度随着套袋时间的延长逐渐升高，到第40 d达到最高值。以第70 d蜜柚正常成熟采收为计，全果中氯硝胺的最终残留浓度与套袋纸中氯硝胺的初始含量的相关关系符合预测方程y=-0.048×e^{（-x/26.156）}+0.048，当全果中氯硝胺的最终残留浓度为0.01 mg/kg时，套袋纸中氯硝胺的初始临界含量为6.126 mg/kg。蜜柚套袋全过程中，五种套袋蜜柚果肉均未检出氯硝胺残留。通过提前10 d摘袋，全果中氯硝胺的残留量可降低23.8%。本研究为揭示蜜柚中氯硝胺残留污染的来源提供了科学依据，为今后蜜柚套袋种植以及套袋纸生产管理具有重要的指导意义。
- 蜜柚 /
- 套袋 /
- 氯硝胺 /
- 迁移规律 /
- 残留
Abstract: The content of dicloran in bagging paper and honey pomelo was determined by gas chromatography-tandem mass spectrometry. Meanwhile, the migration of dicloran from five kinds of bagging paper to different parts of honey pomelo was studied through field experiments. The results showed that the residual concentration of dicloran in honey pomelo treated with four kinds of bagging paper with dicloran gradually increased with the prolongation of bagging time, and reached the maximum value on the 40th day. When the normal harvest of whole honey pomelo on the 70th day, the correlation between the final residual concentration of dicloran in whole honey pomelo and the initial content of dicloran in bagging paper was in line with the prediction equation: y=-0.048×e^(-x/26.156)+0.048. The initial critical content of dicloran in bagging paper was 6.126 mg/kg when the final residual concentration of dicloran in whole honey pomelo was 0.01 mg/kg. No dicloran was detected in the pulp of all pomelos during bagging process. By picking bags 10 days in advance, the residues of dicloran in whole honey pomelo could be reduced by 23.8%.This study provides a scientific basis for revealing the source of residual pollution of dicloran in honey pomelo, and has important guiding significance for pomelo bagging cultivation, bagging paper production and management in the future.
- honey pomelo /
- bagging /
- dicloran /
- migration /
- residue

HTML全文

参考文献(38)

[1]	黄颖颖,陆东和,杨成龙,等.酶法脱苦对琯溪蜜柚汁主要苦味物质及营养风味的影响[J].福建农业学报,2016,31(8):886-891.
[2]	林燕金,林旗华,卢艳清,等.套袋时期对黄金蜜柚果实外观和内质的影响[J].中国南方果树,2016,45(6):47-48.
[3]	周成敏,尤根彪,吴家学,等.不同套袋模式对2种柚子果实品质及效益的影响[J].湖南农业科学,2016(2):80-82.
[4]	Liu T,Song S,Yuan Y B,et al. Improved peach peel color development by fruit bagging.Enhanced expression of anthocyanin biosynthetic and regulatory genes using white non-woven polypropylene as replacement for yellow paper[J].Scientia Horticulturae,2015,184:142-148.
[5]	Kalsum U,Susanto S,Junaedi A.Quality improvement of pummelo(Citrus maxima(Burm.)Merr.)using leaf-to-fruit ratio arrangement and fruit bagging[J].American Journal of Plant Physiology,2015,10(2):68-76.
[6]	冯方茂,曾丽萍,姜成东,等.套袋对‘马来西亚’蜜柚果实品质的影响[J].食品工业科技,2017,38(17):264-267.
[7]	Dutta P,Majumder D. Influence of bagging on fruit quality and mineral composition of Himsagar mango grown in new alluvial zones of West Bengal[J]. Advances in Horticultural Science,2012,26(3-4):158-162.
[8]	周继芬.套袋对凤凰柚果实品质的影响[J].西南师范大学学报(自然科学版),2011,36(5):159-162.
[9]	赵晓玲,佘文琴,林慧颖.不同套袋处理对琯溪蜜柚果实品质的影响[J].中国南方果树,2012,41(4):62-64.
[10]	Xu G F,Nie J Y,Wu Y L,et al. The effects of fruit bagging on residue behavior and dietary risk for four pesticides in apple[J].Scientific Reports,2018,8:14348.
[11]	Han J L,Fang P,Xu X M,et al. Study of the pesticides distribution in peel,pulp and paper bag and the safety of pear bagging[J].Food Control,2015,54:338-346.
[12]	Sharma R R,Reddy S V R,Jhalegar M J.Pre-harvest fruit bagging:A useful approach for plant protection and improved post-harvest fruit quality-a review[J].The Journal of Horticultural Science and Biotechnology,2014,89(2):101-113.
[13]	黄崇杏,王志伟,王双飞.纸质食品包装材料中的残留污染物[J].包装工程,2007,28(7):12-15.
[14]	杨伟和.造纸杀菌剂在文化纸生产上应用研究[J].广东化工,2009,36(9):244-245.
[15]	de Oliveira D P,Sakagami M,Warren S,et al. Evaluation of dicloran's contribution to the mutagenic activity of cristais river,Brazil,water samples[J].Environmental Toxicology and Chemistry,2009,28(9):1881.
[16]	欧盟委员会. 欧盟食品和饲料快速预警系统[DB/OL].[2017-09-10]. http://db.foodmate.net/rasff/.
[17]	Iuchi A,Nagai Y,Kuroshima T. Persistence of organophosphorous insecticide residues in Japanese pears[J]. Reports of Tokushima Agricultural Experiment Station,1978,16:74-78.
[18]	Katami T,Nakamura M,Yasuhara A,et al. Migration of organophosphorus insecticides cyanophos and prothiofos residues from impregnated paper bags to Japanese apple-pears(Pyrus pyrifolia nakai cv.Nijisseiki)[J].Journal of Agricultural and Food Chemistry,2000,48(6):2499-2501.
[19]	中华人民共和国农业农村部. NY/T 788-2018农作物中农药残留试验准则[S]. 北京:中国农业出版社,2018:2-6.
[20]	明道绪.田间试验与统计分析[M].北京:科学出版社,2005:1-37.
[21]	孟宪勇,王晶,刘彭.生物统计学[M].北京:海洋出版社,2016:19-22.
[22]	谢景丽. 改进的QuEChERS-色谱串联质谱法快速检测中草药中212种农药多残留[D]. 北京:中国农业科学院,2016.
[23]	Hou X,Han M,Dai X H,et al. A multi-residue method for the determination of 124 pesticides in rice by modified QuEChERS extraction and gas chromatography-tandem mass spectrometry[J].Food Chemistry,2013,138(2/3):1198-1205.
[24]	魏畅,傅红,郑俊超,等.QuECHERS-液质联用同步检测蘑菇中多菌灵等3种杀菌剂残留[J].中国食品学报,2016,16(11):189-195.
[25]	胡西洲,程运斌,胡定金.农药多残留分析中QuEchERS方法介绍[J].现代农药,2006,5(4):24-29 ,44.
[26]	王峰恩,邓立刚,李霞,等.QuEChERS-气相色谱-串联质谱法同时测定饲草中10种农药残留[J].农药学学报,2017,19(1):68-75.
[27]	中华人民共和国国家质量监督检验检疫总局,中国国家标准化管理委员会. GBT 27404-2008实验室质量控制规范食品理化检测[S]. 北京:中国标准出版社,2008:26-27.
[28]	中华人民共和国国家卫生和计划生育委员会,中华人民共和国农业部,国家食品药品监督管理总局. GB 2763-2016食品安全国家标准食品中农药最大残留限量[S]. 北京:中国标准出版社,2016:229.
[29]	舒梅,冯绍卫,岩吞,等.农药降解及其影响因素研究进展[J].农家参谋,2018(4):74-75,53.
[30]	王玉涛. 氯化苦在土壤及作物中的检测及消解规律的研究[D]. 济南:山东大学,2009.
[31]	赵小云,谢德芳.套袋对水果中农药残留的影响研究进展[J].农业资源与环境学报,2018,35(2):104-110.
[32]	张莹,师校欣,杜国强,等.毒死蜱在梨果实不同部位的残留及消解动态[J].农药学学报,2017,19(2):231-237.
[33]	刘蕾庆,焦自高,艾希珍,等.套袋对厚皮甜瓜果实中农药残留量的影响[J].西北农业学报,2012,21(5):151-154.
[34]	郭畅,傅曼琴,徐玉娟,等.沙田柚皮精油分子蒸馏分离及成分分析[J].现代食品科技,2018,34(6):260-266.
[35]	Xu X M,Yu S,Li R,et al. Distribution and migration study of pesticides between peel and pulp in grape by online gel permeation chromatography-gas chromatography/mass spectrometry[J].Food Chemistry,2012,135(1):161-169.
[36]	赵小云,谢德芳,田海.套袋微环境对香蕉中苯醚甲环唑和噻呋酰胺内吸性和降解速率的影响及机制[J].江苏农业科学,2019,47(3):154-159.
[37]	李胤均,钱程,谢德芳.芒果套袋前后喷施吡虫啉·噻嗪酮农药的消解动态研究[J].江苏农业科学,2016,44(3):276-278.
[38]	武红霞,王松标,马蔚红,等.不同除袋时期对红芒6号芒果果实品质的影响[J].热带作物学报,2009,30(10):1458-1461.

施引文献(23)

期刊类型引用(13)

1.	陈树俊，李子琦，王世强，张丽珍. 山西老陈醋多糖提取纯化及结构鉴定. 中国酿造. 2024(05): 111-117 . 百度学术
2.	曲航，吴奕，刘常武，杨海龙，罗自生，戴晨义. 鲍鱼多糖的大孔树脂纯化工艺及其免疫调节活性分析. 食品工业科技. 2024(13): 186-194 . 本站查看
3.	李海松，杜娟，马彦江. 均匀设计法结合AHP-熵权TOPSIS混合加权法优化地黄九蒸九制炮制工艺. 医药论坛杂志. 2024(12): 1305-1310 . 百度学术
4.	刘煜珺，刘桂英，于笛，李龙，傅志宇，郑杰，刘俣彤，周遵春. 响应面法优化大孔树脂纯化仿刺参中皂苷工艺研究. 水产科学. 2024(05): 727-736 . 百度学术
5.	王清泉，宋景，李亚男，魏玉民，李晓雨，董伟超，孙志强，代龙. 地黄多糖的提取纯化及药理作用研究进展. 中草药. 2023(11): 3734-3744 . 百度学术
6.	郭静，赵鸿燕，李莉，汪海琴，晚娇，魏琴，方琼，解廷娜. 油樟叶多糖的大孔树脂纯化工艺研究. 离子交换与吸附. 2023(02): 147-156 . 百度学术
7.	詹梦茹，王彦斌，康淑荷，罗兴平. 党参多糖的大孔树脂纯化及其美白、吸湿保湿性能. 林产化学与工业. 2023(03): 79-88 . 百度学术
8.	张宏妍，李晗熙，国宇晴，白鈴泓，廉美兰. 利用大孔吸附树脂纯化东北刺人参不定根多糖的研究. 延边大学农学学报. 2023(03): 9-17+24 . 百度学术
9.	张秀丽，钟珍林，马雯芳，张超裕. 响应面法优化大孔树脂纯化桑椹多糖工艺. 壮瑶药研究. 2023(02): 68-75+383-384 . 百度学术
10.	胡迎丽，黄金福，杨建林，丁猛，雷福厚，夏璐. 松香基大孔吸附树脂对三七总皂苷的吸附特性研究. 食品工业科技. 2022(04): 73-81 . 本站查看
11.	穆娜，李凤伟，柳晓晨，王笃军，商曰玲，余晓红. 苜蓿多糖脱蛋白工艺及其对鼠李糖乳杆菌增殖作用研究. 中国食品添加剂. 2022(03): 99-105 . 百度学术
12.	靳铁柱. 响应面法优化桑葚多糖纯化工艺及不同产物的抗运动疲劳活性比较. 保鲜与加工. 2022(04): 67-73 . 百度学术
13.	钮婧杰，孙延平，李霄，吴丹，匡海学. 树脂在中药多糖脱色工艺中的研究进展. 化学工程师. 2021(01): 48-51 . 百度学术