HAN Qian, CHEN Si, HUANG Xiaoling, et al. Preparation of Clove Essential Oil-Chitosan Composite Film and Its Application in Rice Preservation[J]. Science and Technology of Food Industry, 2025, 46(8): 322−330. (in Chinese with English abstract). doi: 10.13386/j.issn1002-0306.2024040261.
Citation: HAN Qian, CHEN Si, HUANG Xiaoling, et al. Preparation of Clove Essential Oil-Chitosan Composite Film and Its Application in Rice Preservation[J]. Science and Technology of Food Industry, 2025, 46(8): 322−330. (in Chinese with English abstract). doi: 10.13386/j.issn1002-0306.2024040261.

Preparation of Clove Essential Oil-Chitosan Composite Film and Its Application in Rice Preservation

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  • Received Date: April 21, 2024
  • Available Online: February 09, 2025
  • Objective: To investigate the effect of adding clove oil (CEO) on the properties of CEO/chitosan (CS) composite films, including optical and mechanical properties. Additionally, it explored the effectiveness of these films with varying amounts of CEO in maintaining the freshness of cooked rice under room temperature. Methods: Composite films were developed using a chitosan matrix and blended with varying CEO contents (0%, 0.5%, 1%, 1.5%, 2%). Their physicochemical properties and internal structure were characterized. These films were applied to cooked rice, and the total colony count and sensory evaluation indicators were monitored during the rice's storage period. Results: The composite film with a 1.5% addition of CEO exhibited the optimum overall performance, with the water vapor permeability of 3.80×10−3 g/(h·m·kPa) and the elongation at break of 40.33%. Additionally, the film efficiently decreased the total colony count of rice during storage. Compared with the control (group CK and PE), the rice treated with the film could effectively extending shelf life by an additional 2 d. Conclusion: Adding CEO was able to enhance the properties of chitosan composite films. The addition content of 1.5% efficiently maintained the quality of cooked rice during storage. This study can provide a reference for the application of CEO in the preservation of ready-to-eat rice.
  • [1]
    李建婷, 陈慧, 秦丹. 我国方便米饭研究现状及发展前景[J]. 农产品加工,2016(16):64−67. [LI J T, CHEN H, QIN D. Research status and development prospect of convenience rice in china[J]. Farm Products Processing,2016(16):64−67.]

    LI J T, CHEN H, QIN D. Research status and development prospect of convenience rice in china[J]. Farm Products Processing, 2016(16): 64−67.
    [2]
    曾宪泽. 冷链盒装米饭加工和配送过程中品质控制的研究[D]. 广州:华南理工大学, 2014. [ZENG X Z. Research on quality control during processing and distribution of cold chain boxed rice[D]. Guangzhou:South China University of Technology, 2014.]

    ZENG X Z. Research on quality control during processing and distribution of cold chain boxed rice[D]. Guangzhou: South China University of Technology, 2014.
    [3]
    ANIS A, PAL K, AL-ZAHRANI S M. Essential oil-containing polysaccharide-based edible films and coatings for food security applications[J]. Polymers,2021,13(4):575. doi: 10.3390/polym13040575
    [4]
    VIANNA T C, MARINHO C O, MARANGONI J L, et al. Essential oils as additives in active starch-based food packaging films:A Review[J]. International Journal of Biological Macromolecules,2021,182:1803−1819. doi: 10.1016/j.ijbiomac.2021.05.170
    [5]
    BHAVANIRAMYA S, VISHNUPRIYA S, AL-ABOODY M S, et al. Role of essential oils in food safety:Antimicrobial and antioxidant applications[J]. Grain and Oil Science and Technology,2019,2(2):49−55. doi: 10.1016/j.gaost.2019.03.001
    [6]
    李结瑶, 罗文翰, 肖更生, 等. 丁香/香茅精油复合涂膜对百香果采后保鲜的研究[J]. 食品与发酵工业,2023,49(4):59−67. [LI J Y, LUO W H, XIAO G S, et al. Study on the Post-harvest freshness preservation of passion fruit by clove/lemongrass essential oil composite coating[J]. Food and Fermentation Industries,2023,49(4):59−67.]

    LI J Y, LUO W H, XIAO G S, et al. Study on the Post-harvest freshness preservation of passion fruit by clove/lemongrass essential oil composite coating[J]. Food and Fermentation Industries, 2023, 49(4): 59−67.
    [7]
    HYLDGAARD M, MYGIND T, MEYER R L. Essential oils in food preservation:mode of action, synergies, and interactions with food matrix components[J]. Frontiers in Microbiology,2012,3:12.
    [8]
    HE S, REN X, LU Y, et al. Microemulsification of clove essential oil improves its in vitro and in vivo control of penicillium digitatum[J]. Food Control,2016,65:106−111. doi: 10.1016/j.foodcont.2016.01.020
    [9]
    GUO Y, CHEN X, YANG F, et al. Preparation and characterization of chitosan-based ternary blend edible films with efficient antimicrobial activities for food packaging applications[J]. Journal of Food Science,2019,84(6):1411−1419. doi: 10.1111/1750-3841.14650
    [10]
    石洁, 王雪嵘, 徐朝阳. 食品包装用壳聚糖薄膜的研究进展[J]. 包装工程,2022,43(3):42−50. [SHI J, WANG X R, XU C Y. Research progress of chitosan film for food packaging[J]. Packaging Engineering,2022,43(3):42−50.]

    SHI J, WANG X R, XU C Y. Research progress of chitosan film for food packaging[J]. Packaging Engineering, 2022, 43(3): 42−50.
    [11]
    张萌萌, 董蕾, 王东芹, 等. 花椒精油/壳聚糖复合膜的制备及其在猪肉冷藏保鲜中的应用[J]. 食品研究与开发,2023,44(6):93−101. [ZHANG M M, DONG L, WANG D Q, et al. Preparation of peppercorn essential oil/chitosan composite film and its application in the cold storage and preservation of pork[J]. Food Research and Development,2023,44(6):93−101.] doi: 10.12161/j.issn.1005-6521.2023.06.014

    ZHANG M M, DONG L, WANG D Q, et al. Preparation of peppercorn essential oil/chitosan composite film and its application in the cold storage and preservation of pork[J]. Food Research and Development, 2023, 44(6): 93−101. doi: 10.12161/j.issn.1005-6521.2023.06.014
    [12]
    钟婷, 普涵, 茹素梅, 等. 壳聚糖-生姜精油复合膜的优化制备[J]. 山东化工,2022,51(23):46−50. [ZHONG T, PU H, RU S M, et al. Optimized preparation of chitosan-ginger essential oil composite film[J]. Shandong Chemical Industry,2022,51(23):46−50.] doi: 10.3969/j.issn.1008-021X.2022.23.012

    ZHONG T, PU H, RU S M, et al. Optimized preparation of chitosan-ginger essential oil composite film[J]. Shandong Chemical Industry, 2022, 51(23): 46−50. doi: 10.3969/j.issn.1008-021X.2022.23.012
    [13]
    唐森, 付美杨, 韦巧艳, 等. 壳聚糖-连翘精油复合可食膜的制备及其在草莓中保鲜应用[J]. 食品研究与开发,2023,44(21):98−105. [TANG S, FU M Y, WEI Q Y, et al. Preparation of chitosan-conjugate essential oil composite edible film and its application in strawberry preservation[J]. Food Research and Development,2023,44(21):98−105.] doi: 10.12161/j.issn.1005-6521.2023.21.014

    TANG S, FU M Y, WEI Q Y, et al. Preparation of chitosan-conjugate essential oil composite edible film and its application in strawberry preservation[J]. Food Research and Development, 2023, 44(21): 98−105. doi: 10.12161/j.issn.1005-6521.2023.21.014
    [14]
    唐森, 李孟玲, 陈显玲, 等. 紫苏精油壳聚糖复合膜的制备及其对鲜切雪莲果的保鲜效果研究[J]. 粮食与油脂,2023,36(9):61−65,83. [TANG S, LI M L, CHEN X L, et al. Preparation of chitosan composite film with perilla essential oil and its preservation effect on fresh-cut snow lotus fruit[J]. Cereals and Oils,2023,36(9):61−65,83.] doi: 10.3969/j.issn.1008-9578.2023.09.014

    TANG S, LI M L, CHEN X L, et al. Preparation of chitosan composite film with perilla essential oil and its preservation effect on fresh-cut snow lotus fruit[J]. Cereals and Oils, 2023, 36(9): 61−65,83. doi: 10.3969/j.issn.1008-9578.2023.09.014
    [15]
    钟秋夏, 郑海英, 朱燕丽, 等. 百里香酚微胶囊的制备及其对草莓的保鲜效果[J]. 食品科学,2023,44(11):167−176. [ZHONG Q X, ZHENG H Y, ZHU Y L, et al. Preparation of thymol microcapsules and their preservation effect on strawberries[J]. Journal of Food Science,2023,44(11):167−176.] doi: 10.7506/spkx1002-6630-20220426-331

    ZHONG Q X, ZHENG H Y, ZHU Y L, et al. Preparation of thymol microcapsules and their preservation effect on strawberries[J]. Journal of Food Science, 2023, 44(11): 167−176. doi: 10.7506/spkx1002-6630-20220426-331
    [16]
    ROY S, RHIM J W, JAISWAL L. Bioactive agar-based functional composite film incorporated with copper sulfide nanoparticles[J]. Food Hydrocolloids,2019,93:156−166. doi: 10.1016/j.foodhyd.2019.02.034
    [17]
    郭丽, 王鹏, 刘东琦, 等. 透明质酸-明胶复合膜的制备及理化性质研究[J]. 食品工业科技,2019,40(22):217−222. [GUO L, WANG P, LIU D Q, et al. Preparation and physicochemical properties of hyaluronic acid-gelatin composite film[J]. Food Industry Science and Technology,2019,40(22):217−222.]

    GUO L, WANG P, LIU D Q, et al. Preparation and physicochemical properties of hyaluronic acid-gelatin composite film[J]. Food Industry Science and Technology, 2019, 40(22): 217−222.
    [18]
    张晓绘, 李汴生, 阮征, 等. 基于主成分分析法综合评价即食米饭品质特性[J]. 中国调味品,2024,49(1):1−7. [ZHANG X H, LI B S, RUAN Z, et al. Comprehensive evaluation of quality characteristics of ready-to-eat rice based on principal component analysis[J]. China Condiment,2024,49(1):1−7.] doi: 10.3969/j.issn.1000-9973.2024.01.001

    ZHANG X H, LI B S, RUAN Z, et al. Comprehensive evaluation of quality characteristics of ready-to-eat rice based on principal component analysis[J]. China Condiment, 2024, 49(1): 1−7. doi: 10.3969/j.issn.1000-9973.2024.01.001
    [19]
    河北省食品检验研究院、中国食品科学技术学会. GB4789.2-2022食品安全国家标准 食品微生物学检验 菌落总数测定[S]. 北京:中国标准出版社, 2022. [Hebe Institute of Food Inspection, Chinese Society of Food Science and Technology. GB 4789.2-2022 National Standard for Food Safety Food Microbiological Tests Determination of Total Colony [S]. Beijing:China Standard Press, 2022.]

    Hebe Institute of Food Inspection, Chinese Society of Food Science and Technology. GB 4789.2-2022 National Standard for Food Safety Food Microbiological Tests Determination of Total Colony [S]. Beijing: China Standard Press, 2022.
    [20]
    全国粮油标准化技术委员会. GBT15682-2008 粮油检验 稻谷 大米蒸煮食用品质感官评价方法[S]. 北京:中国标准出版社, 2008. [National Cereals and Oils Standardization Technical Commtttee. GB/T 15682-2008 Grain and Oil Inspection Methods for Sensory Evaluation of Cooking and Edible Quality of Rice [S]. Beijing:China Standard Press, 2008.]

    National Cereals and Oils Standardization Technical Commtttee. GB/T 15682-2008 Grain and Oil Inspection Methods for Sensory Evaluation of Cooking and Edible Quality of Rice [S]. Beijing: China Standard Press, 2008.
    [21]
    ROTA M C, HERRERA A, MARTINEZ R M, et al. Antimicrobial activity and chemical composition of thymus vulgaris, thymus zygis and thymus hyemalis essential oils[J]. Food Control,2008,19(7):681−687. doi: 10.1016/j.foodcont.2007.07.007
    [22]
    DEBCZAK A, TYSKIEWICZ K, FEKNER Z, et al. Molecular distillation of lavender supercritical extracts:physicochemical and antimicrobial characterization of feedstocks and assessment of distillates enriched with oxygenated fragrance components:5[J]. Molecules,2022,27(5):1470. doi: 10.3390/molecules27051470
    [23]
    何守魁, 刘欣悦, 李慧珍, 等. 壳聚糖-丁香精油微乳液复合膜的制备及其对猪肉的保鲜作用[J]. 食品安全质量检测学报,2022,13(17):5650−5655. [HE S K, LIU X Y, LI H Z, et al. Preparation of chitosan-clove essential oil microemulsion composite film and its preservation effect on pork[J]. Journal of Food Safety and Qualit,2022,13(17):5650−5655.] doi: 10.3969/j.issn.2095-0381.2022.17.spaqzljcjs202217027

    HE S K, LIU X Y, LI H Z, et al. Preparation of chitosan-clove essential oil microemulsion composite film and its preservation effect on pork[J]. Journal of Food Safety and Qualit, 2022, 13(17): 5650−5655. doi: 10.3969/j.issn.2095-0381.2022.17.spaqzljcjs202217027
    [24]
    PIRES C, RAMOS C, TEIXEIRA G, et al. Characterization of biodegradable films prepared with hake proteins and thyme oil[J]. Journal of Food Engineering,2011,105(3):422−428. doi: 10.1016/j.jfoodeng.2011.02.036
    [25]
    LIU T, LIU L, GONG X, et al. Fabrication and comparison of active films from chitosan incorporating different spice extracts for shelf life extension of refrigerated Pork[J]. LWT,2021,135:110181. doi: 10.1016/j.lwt.2020.110181
    [26]
    ELSHAMY S, KHADIZATUL K, UEMURA K, et al. Chitosan-based film incorporated with essential oil nanoemulsion foreseeing enhanced antimicrobial Effect[J]. Journal of Food Science and Technology,2021,58(9):3314−3327. doi: 10.1007/s13197-020-04888-3
    [27]
    NORDIN N, OTHMAN S H, RASHID S A, et al. Effects of glycerol and thymol on physical, mechanical, and thermal properties of corn starch films[J]. Food Hydrocolloids,2020,106:105884. doi: 10.1016/j.foodhyd.2020.105884
    [28]
    HAN LYN F, NUR HANANI Z A. Effect of lemongrass (Cymbopogon citratus) essential oil on the properties of chitosan films for active packaging[J]. Journal of Packaging Technology and Research,2020,4(1):33−44. doi: 10.1007/s41783-019-00081-w
    [29]
    WANG Y, WANG J, LAI J, et al. Preparation and characterization of chitosan/whey isolate protein active film containing TiO2 and white pepper essential Oil[J]. Frontiers in Nutrition,2022,9:1047988. doi: 10.3389/fnut.2022.1047988
    [30]
    ZENG Z, YANG Y J, TU Q, et al. Preparation and characterization of carboxymethyl chitosan/pullulan composite film incorporated with eugenol and its application in the preservation of chilled Meat[J]. Meat Science,2023,198:109085. doi: 10.1016/j.meatsci.2022.109085
    [31]
    KAMKAR A, MOLAEE-AGHAEE E, KHANJARI A, et al. Nanocomposite active packaging based on chitosan biopolymer loaded with Nano-liposomal essential oil:Its characterizations and effects on microbial, and chemical properties of refrigerated chicken breast Fillet[J]. International Journal of Food Microbiology,2021,342:109071. doi: 10.1016/j.ijfoodmicro.2021.109071
    [32]
    LEE J Y, GARCIA C V, SHIN G H, et al. Antibacterial and antioxidant properties of hydroxypropyl Methylcellulose-based active composite films incorporating oregano essential oil Nanoemulsions[J]. LWT,2019,106:164−171. doi: 10.1016/j.lwt.2019.02.061
    [33]
    王兰兰. 载药水凝胶及水凝胶纤维伤口敷料的制备与性能研究[D]. 无锡:江南大学, 2023. [WANG L L. Preparation and properties of drug-carrying hydrogel and hydrogel fiber wound dressings[D]. Wuxi:Jiangnan University, 2023.]

    WANG L L. Preparation and properties of drug-carrying hydrogel and hydrogel fiber wound dressings[D]. Wuxi: Jiangnan University, 2023.
    [34]
    王小雪. 含丁香精油Pickering乳液的多糖活性复合膜的制备及应用研究[D]. 雅安:四川农业大学, 2023. [WANG X X. Preparation and application study of polysaccharide-active composite membrane containing Pickering emulsion of clove essential oil [D]. Yaan:Sichuan Agricultural University, 2023.]

    WANG X X. Preparation and application study of polysaccharide-active composite membrane containing Pickering emulsion of clove essential oil [D]. Yaan: Sichuan Agricultural University, 2023.
    [35]
    徐婧. 紫外光响应控释抗氧化包装膜的制备及控释行为研究[D]. 无锡:江南大学, 2023. [XU J. Preparation of UV-responsive controlled-release antioxidant packaging film and study of controlled-release behavior[D]. Wuxi:Jiangnan University, 2023.]

    XU J. Preparation of UV-responsive controlled-release antioxidant packaging film and study of controlled-release behavior[D]. Wuxi: Jiangnan University, 2023.
    [36]
    杨育静. 丁香酚-羧甲基壳聚糖/普鲁兰多糖复合膜的制备及其在冷鲜猪肉保鲜中的应用[D]. 雅安:四川农业大学, 2023. [YANG Y J. Preparation of eugenol-carboxymethyl chitosan/purulan polysaccharide composite film and its application in the preservation of chilled pork [D]. Yaan:Sichuan Agricultural University, 2023.]

    YANG Y J. Preparation of eugenol-carboxymethyl chitosan/purulan polysaccharide composite film and its application in the preservation of chilled pork [D]. Yaan: Sichuan Agricultural University, 2023.
    [37]
    印晓玉. 基于丁香精油纳米乳液的抗菌材料制备与应用[D]. 南京:南京财经大学, 2022. [YIN X Y. Preparation and application of antimicrobial materials based on clove essential oil nanoemulsion [D]. Nanjing:Nanjing University of Finance and Economics, 2022.]

    YIN X Y. Preparation and application of antimicrobial materials based on clove essential oil nanoemulsion [D]. Nanjing: Nanjing University of Finance and Economics, 2022.
    [38]
    中华人民共和国国家卫生健康委员会, 国家市场监督管理总局. GB 19295-2021 食品安全国家标准 速冻面米与调制食品[S]. 北京:中国标准出版社, 2021. [National Health Commission of the Peoples's Rerublic of China, State Administration for Market Superrvsion and Administration of the People's Republic og China. GB 19295-2021 National Standard for Food Safety Frozen Noodles, Rice and Prepared Foods [S]. Beijing:China Standard Press, 2021.]

    National Health Commission of the Peoples's Rerublic of China, State Administration for Market Superrvsion and Administration of the People's Republic og China. GB 19295-2021 National Standard for Food Safety Frozen Noodles, Rice and Prepared Foods [S]. Beijing: China Standard Press, 2021.
    [39]
    CHANDRASEKARAN M, KIM K, CHUN S. Antibacterial activity of chitosan nanoparticles:A Review[J]. Processes,2020,8(9):1173. doi: 10.3390/pr8091173
    [40]
    CUI H, ZHANG C, LI C, et al. Antimicrobial mechanism of clove oil on Listeria Monocytogenes[J]. Food Control,2018,94:140−146. doi: 10.1016/j.foodcont.2018.07.007
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