Determination of 16 Kinds of Organochlorine and Pyrethroid Pesticide Residues in Nuts by Gas Chromatography

LI Na; ZHU Wenfeng; CHENG Guodong; JIANG Tingting; WANG Ting; JI Changfei

doi:10.13386/j.issn1002-0306.2023030024

Volume 45 Issue 1

Dec. 2023

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Science and Technology of Food Industry > 2024 > 45(1): 268-276. > DOI: 10.13386/j.issn1002-0306.2023030024

LI Na, ZHU Wenfeng, CHENG Guodong, et al. Determination of 16 Kinds of Organochlorine and Pyrethroid Pesticide Residues in Nuts by Gas Chromatography[J]. Science and Technology of Food Industry, 2024, 45(1): 268−276. (in Chinese with English abstract). doi: 10.13386/j.issn1002-0306.2023030024.

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Determination of 16 Kinds of Organochlorine and Pyrethroid Pesticide Residues in Nuts by Gas Chromatography

Anhui Zhongchuang Food Testing Co., Ltd., Wuhu 241000, China

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Received Date: March 02, 2023
Available Online: November 02, 2023

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Abstract

Abstract

The purpose of this paper is to establish an analytical method for the determination of 16 organochlorine and pyrethroid pesticide residues in nuts by gas chromatography (GC). The samples were extracted by acetone:hexane (3:7, V:V), purified by 0.2 mL concentrated sulfuric acid sulfonation, and the organochlorines and pyrethroids were separated by a DB-17MS column (30 m×0.32 mm, 0.25 μm), and quantified by gas chromatography-electron capture detector (GC-ECD). The results showed that the organochlorine and pyrethroid pesticides showed good linearity in the concentration range of 0.01~0.20 μg/mL and the corresponding peak areas. The determination coefficients (r²) were above 0.996, and the limits of detection were 0.1~0.4 μg/kg. In this study, the spiked recovery experiments were also performed on samples of different matrices (pistachios, macadamia nuts, cashew nuts, pistachios, walnuts, and padanuts) at low (10 μg/kg), medium (40 μg/kg), and high (100 μg/kg) concentrations, respectively. The extraction rates ranged from 81.6% to 119.5% with the relative standard deviations (RSDs) of 1.03%~5.36%. The method is simple, accurate, reproducible and suitable for the determination of 16 organochlorine and pyrethroid pesticide residues in nuts.
- nuts,
- organochlorine,
- pyrethroid,
- concentrated sulfuric acid sulfonation,
- gas chromatography

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