Rapid Detection of the Oxidation of Almonds Based on Surface Enhanced Raman Spectroscopy

QIAN Yu; LIU Shuai; JIN Long; SUN Mei; YAN Ling; LIU Changhong; DONG Baolei; ZHENG Lei

doi:10.13386/j.issn1002-0306.2023020173

Volume 44 Issue 24

Dec. 2023

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Science and Technology of Food Industry > 2023 > 44(24): 286-293. > DOI: 10.13386/j.issn1002-0306.2023020173

QIAN Yu, LIU Shuai, JIN Long, et al. Rapid Detection of the Oxidation of Almonds Based on Surface Enhanced Raman Spectroscopy[J]. Science and Technology of Food Industry, 2023, 44(24): 286−293. (in Chinese with English abstract). doi: 10.13386/j.issn1002-0306.2023020173.

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Rapid Detection of the Oxidation of Almonds Based on Surface Enhanced Raman Spectroscopy

1.
School of Food and Biological Engineering, Hefei University of Technology, Hefei 230031, China
2.
ChaCha Food Co., Ltd, Hefei 230031, China

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Received Date: February 19, 2023
Available Online: October 20, 2023

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Abstract

Abstract

The oxidation of almonds during the storage and processing would seriously affect their nutrition and quality. The purpose of this study was to establish a sensitive and reliable method for rapid detection of the oxidation of almonds. A rapid and simple phase-transfer of gold nanoparticles (AuNPs) from aqueous solution to toluene was achieved via a strategy of surface ligand exchange. The results of UV-Vis and transmission electron microscopy showed that the morphology of AuNPs after phase-transfer changed no obvious. The AuNPs in toluene could be successfully used as an efficient SERS substrate for detecting the oxidation of almond oil. The characteristic Raman signal of the cis-double bond at 1655 cm⁻¹ of almonds oil gradually decreased during oxidation. Raman signal at 1747 cm⁻¹ of the ester bond was selected as the reference, and the relative intensity of I₁₆₅₅/I₁₇₄₇ showed a good linear relationship with the time of accelerated ageing of almonds (R²=0.98). By virtue of principal component analysis, the developed method was able to quickly and accurately distinguish the almonds with different oxidation levels. This study also provided a new strategy for the preparation and application of SERS substrates for fatty foods.
- almonds,
- oxidation,
- surface-enhanced raman spectroscopy,
- gold nanoparticles,
- rapid detection

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References (36)

References

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