CHEN Qi, CHENG Ting, XIAO Gengsheng, et al. Preparation, Characterization and Adsorption Performance of Activated Carbon from Durian Shell and Longan Shell[J]. Science and Technology of Food Industry, 2023, 44(15): 46−54. (in Chinese with English abstract). doi: 10.13386/j.issn1002-0306.2022070280.
Citation: CHEN Qi, CHENG Ting, XIAO Gengsheng, et al. Preparation, Characterization and Adsorption Performance of Activated Carbon from Durian Shell and Longan Shell[J]. Science and Technology of Food Industry, 2023, 44(15): 46−54. (in Chinese with English abstract). doi: 10.13386/j.issn1002-0306.2022070280.

Preparation, Characterization and Adsorption Performance of Activated Carbon from Durian Shell and Longan Shell

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  • Received Date: July 21, 2022
  • Available Online: June 05, 2023
  • Biomass activated carbon was prepared from discarded durian shell and longan shell by KOH chemical activation method, and their adsorption capacity of methylene blue (MB) in water was also investigated. The surface area test (BET), Fourier infrared spectroscopy (FT-IR), scanning electron microscopy (SEM) and X-ray diffraction (XRD) were used to characterize the prepared biomass activated carbon, and the effects of activated carbon amount, initial concentration of MB solution, reaction time, temperature and pH on the adsorption of MB were studied. Results indicated that the maximum adsorption capacity of durian shell (longan shell) activated carbon was 363 mg/g under the optimum conditions (initial MB solution concentration of 200 mg/L, carbon amount of 30 mg, pH8.0, 120 min). The specific surface area of durian shell and longan shell activated carbon were 999.63 m2/g and 1377.95 m2/g, respectively, and their average pore sizes were 2.13 nm and 2.20 nm, respectively. In addition, the surface of durian shell and longan shell activated carbon had a large number of pores and a certain laminar structure. The existence of these pores provides rich adsorption sites for activated carbon adsorption, and compared with commercially available activated carbon, it has a more dense pore structure and has a stronger adsorption capacity for methylene blue.
  • [1]
    蒋剑春, 孙康. 活性炭制备技术及应用研究综述[J]. 林产化学与工业,2017,37(1):1−13. [JIANG J C, SUN K. A review of activated carbon preparation technology and application research[J]. Forest Chemistry and Industry,2017,37(1):1−13.

    JIANG J C, SUN K. A review of activated carbon preparation technology and application research[J]. Forest Chemistry and Industry, 2017, 37(1): 1-13.
    [2]
    吕静波, 胡洪君, 王晓红, 等. 糖液脱色用活性炭的性能研究[C]//2016年第一届今日财富论坛论文集. 2016.

    LÜ J B, HU H J, WANG X H, et al. Performance study of activated carbon for decolorization of sugar liquor [C]// Proceedings of the First Today's Fortune Forum. 2016.
    [3]
    任艳娇, 赵换萍, 许慧杰. 生物炭基活性炭吸附CO2研究进展[J]. 山东化工,2022,51(14):90−93. [REN Y J, ZHAO H P, XU H J. Research progress of CO2 adsorption by biochar-based activated carbon[J]. Shandong Chemical Industry,2022,51(14):90−93. doi: 10.3969/j.issn.1008-021X.2022.14.028

    REN Y J, ZHAO H P, XU H J. Research progress of CO2 adsorption by biochar-based activated carbon[J]. Shandong Chemical Industry, 2022, 51(14): 90-93 doi: 10.3969/j.issn.1008-021X.2022.14.028
    [4]
    史嘉辰, 韩及华, 李运通, 等. 活性炭微观结构对玉米朊脱色效果的影响[J]. 食品科学,2018,39(13):100−105. [SHI J C, HAN J H, LI Y T, et al. Effect of activated carbon microstructure on the decolorization effect of corn prion[J]. Food Science,2018,39(13):100−105.

    SHI J C, HAN J H, LI Y T, et al. Effect of activated carbon microstructure on the decolorization effect of corn prion[J]. Food Science, 2018, 39(13): 100-105.
    [5]
    DEVESA-REY R, BUSTOS G, CRUZ A B, et al. Optimisation of entrapped activated carbon conditions to remove coloured compounds from winery wastewaters[J]. Bioresource Technology,2011,102(11):6437−6442. doi: 10.1016/j.biortech.2011.03.072
    [6]
    魏宝程. 果壳废弃物厌氧消化产甲烷性能的研究[D]. 北京: 北京化工大学, 2018.

    WEI B C. Study on the performance of methane production from anaerobic digestion of fruit shell waste[D]. Beijing: Beijing University of Chemical Technology, 2018.
    [7]
    NCIBI M C, JEANNE-ROSE V, MAHJOUB B, et al. Preparation and characterisation of raw chars and physically activated carbons derived from marine Posidonia oceanica (L.) fibres[J]. Journal of Hazardous Materials,2009,165(1-3):240−249. doi: 10.1016/j.jhazmat.2008.09.126
    [8]
    谢子楠, 沈家国, 张亚萍. 思南稻壳制备活性炭的初步研究[J]. 应用化工,2015,44(10):1829−1831. [XIE Z N, SHEN J G, ZHANG Y P. Preliminary study on the preparation of activated carbon from Sinan rice husk[J]. Applied Chemistry,2015,44(10):1829−1831.

    XIE Z N, SHEN J G, ZHANG Y P. Preliminary study on the preparation of activated carbon from Sinan rice husk[J]. Applied Chemistry, 2015, 44(10): 1829-1831.
    [9]
    史蕊, 李依丽, 尹晶, 等. 玉米秸秆活性炭的制备及其吸附动力学研究[J]. 环境工程学报,2014,8(8):3428−3432. [SHI R, LI Y L, YIN J, et al. Preparation of corn stover activated carbon and its adsorption kinetics[J]. Journal of Environmental Engineering,2014,8(8):3428−3432.

    SHI R, LI Y L, YIN J, et al. Preparation of corn stover activated carbon and its adsorption kinetics[J]. Journal of Environmental Engineering, 2014, 8(8): 3428-3432.
    [10]
    邱松山. 龙眼加工废弃物的综合利用探讨[J]. 甘肃农业科技,2016(5):59−64. [QIU S H. Exploration of comprehensive utilization of longan processing waste[J]. Gansu Agricultural Science and Technology,2016(5):59−64.

    QIU S H. Exploration of comprehensive utilization of longan processing waste[J]. Gansu Agricultural Science and Technology, 2016(5): 59-64.
    [11]
    孟庆梅, 孟迪, 张艳丽, 等. 榴莲壳生物炭对磺胺嘧啶的吸附性能[J]. 化工进展,2020,39(11):4651−4659. [MENG Q M, MENG D, ZHANG Y L, et al. Adsorption performance of durian shell biochar on sulfadiazine[J]. Chemical Progress,2020,39(11):4651−4659.

    MENG Q M, MENG D, ZHANG Y L, et al. Adsorption performance of durian shell biochar on sulfadiazine[J]. Chemical Progress, 2020, 39(11): 4651-4659.
    [12]
    黄慧珍. 硝酸改性龙眼壳活性炭对Pb(Ⅱ)的吸附性能研究[J]. 长江大学学报(自科版),2018,15(10):46−49, 56. [HUANG H Z. Study on the adsorption performance of nitric acid modified longan shell activated carbon for Pb(II)[J]. Journal of Changjiang University (Self Science Edition),2018,15(10):46−49, 56.

    HUANG H Z. Study on the adsorption performance of nitric acid modified longan shell activated carbon for Pb(II)[J]. Journal of Changjiang University (Self Science Edition), 2018, 15(10): 46-49, 56.
    [13]
    柏松, 梁健, 蔡勤, 等. 龙眼核活性炭制备工艺及其吸附性能研究[J]. 湖北农业科学,2015,54(7):1681−1684. [BAI S, LIANG J, CAI Q, et al. Study on the preparation process of longan kernel activated carbon and its adsorption performance[J]. Hubei Agricultural Science,2015,54(7):1681−1684.

    BAI S, LIANG J, CAI Q, et al. Study on the preparation process of longan kernel activated carbon and its adsorption performance[J]. Hubei Agricultural Science, 2015, 54(7): 1681-1684.
    [14]
    温俊峰, 刘侠, 马向荣, 等. 沙柳基磁性多孔炭的制备及其吸附亚甲基蓝性能研究[J]. 功能材料,2021,52(4):4184−4191. [WEN J F, LIU X, MA X R, et al. Preparation of salix-based magnetic porous carbon and its performance in adsorption of methylene blue[J]. Functional Materials,2021,52(4):4184−4191. doi: 10.3969/j.issn.1001-9731.2021.04.028

    WEN J F, LIU X, MA X R, et al. Preparation of salix-based magnetic porous carbon and its performance in adsorption of methylene blue[J]. Functional Materials, 2021, 52(4): 4184-4191. doi: 10.3969/j.issn.1001-9731.2021.04.028
    [15]
    崔笑颖. 活性炭改性方法及其对水中氨氮吸附性能的技术研究[D]. 张家口: 河北建筑工程学院, 2019.

    CUI X Y. Technical study on the modification method of activated carbon and its adsorption performance on ammonia nitrogen in water[D]. Zhangjiakou: Hebei College of Construction Engineering, 2019.
    [16]
    窦诗童, 廖颖敏, 余婷, 等. 改性榴莲壳对水中亚甲基蓝的吸附研究[J]. 化工技术与开发,2020,49(10):64−68. [DOU S T, LIAO Y M, YU T, et al. Study on the adsorption of methylene blue in water by modified durian shells[J]. Chemical Technology and Development,2020,49(10):64−68.

    DOU S T, LIAO Y M, YU T, et al. Study on the adsorption of methylene blue in water by modified durian shells[J]. Chemical Technology and Development, 2020, 49(10): 64-68.
    [17]
    匡瑜. 表面活性剂改性活性炭对亚甲基蓝和镉离子的吸附研究[D]. 广州: 华南理工大学, 2020.

    KUANG Y. Study on the adsorption of methylene blue and cadmium ions by surfactant-modified activated carbon[D]. Guangzhou: South China University of Technology, 2020.
    [18]
    YOSHIZAWA N, MARUYAMA K, YAMADA Y, et al. XRD evaluation of KOH activation process and influence of coal rank[J]. Fuel,2002,81(13):1717−1722. doi: 10.1016/S0016-2361(02)00101-1
    [19]
    TSENG R L, TSENG S K. Pore structure and adsorption performance of the KOH-activated carbons prepared from corncob[J]. Academic Press,2005,287(2):428−437.
    [20]
    程青, 周月, 黄琳娜, 等. 榴莲壳基多级孔炭材料的制备及其对染料吸附行为研究[J]. 化学试剂,2019,41(9):937−943. [CHENG Q, ZHOU Y, HUANG L N, et al. Preparation of durian shell-based multistage pore carbon materials and their adsorption behavior on dyes[J]. Chemical Reagents,2019,41(9):937−943.

    CHENG Q, ZHOU Y, HUANG L N, et al. Preparation of durian shell-based multistage pore carbon materials and their adsorption behavior on dyes[J]. Chemical Reagents, 2019, 41 (9): 937-943.
    [21]
    李羚. 磁性榴莲壳基活性炭的制备及其吸附性能的研究[D]. 鞍山: 辽宁科技大学, 2021.

    LI L. Preparation of magnetic durian shell-based activated carbon and its adsorption performance[D]. Anshan: University of Science and Technology of Liaoning, 2021.
    [22]
    郭刚军, 马尚玄, 胡小静, 等. 氯化锌活化制备澳洲坚果壳活性炭试验[J]. 林业工程学报,2020,5(6):106−113. [GUO G J, MA S X, HU X J, et al. Experimental preparation of macadamia nut shell activated carbon by zinc chloride activation[J]. Journal of Forestry Engineering,2020,5(6):106−113.

    GUO G J, MA S X, HU X J, et al. Experimental preparation of macadamia nut shell activated carbon by zinc chloride activation[J]. Journal of Forestry Engineering, 2020, 5(6): 106-113.
    [23]
    黄明堦, 陈卫群, 陈燕丹, 等. 草酸钾活化法制备榴莲壳活性炭及其表征[J]. 环境工程学报,2012,6(10):3730−3734. [HUANG M K, CHEN W Q, CHEN Y D, et al. Preparation and characterization of durian shell activated carbon by potassium oxalate activation[J]. Journal of Environmental Engineering,2012,6(10):3730−3734.

    HUANG M K, CHEN W Q, CHEN Y D, et al. Preparation and characterization of durian shell activated carbon by potassium oxalate activation[J]. Journal of Environmental Engineering, 2012, 6(10): 3730-3734.
    [24]
    GREGG S J, SING K S W. Adsorption: Surface area and porosity[M]. London: Academic Press, 1982: 1−5.
    [25]
    何云鹏, 杨水金. BET比表面积法在材料研究中的应用[J]. 精细石油化工进展,2018,19(4):5. [HE Y P, YANG S J. Application of BET specific surface area method in materials research[J]. Advances in Fine Petrochemicals,2018,19(4):5. doi: 10.3969/j.issn.1009-8348.2018.04.012

    HE Y P, YANG S J. Application of BET specific surface area method in materials research[J]. Advances in Fine Petrochemicals, 2018, 19(4): 5. doi: 10.3969/j.issn.1009-8348.2018.04.012
    [26]
    陈华泉. 茶渣活性炭的制备、改性及其在印染废水处理中的应用研究[D]. 广州: 华南理工大学, 2020.

    CHEN H Q. Preparation and modification of activated carbon from tea residue and its application in the treatment of printing and dyeing wastewater[D]. Guangzhou: South China University of Technology, 2020.
    [27]
    赵阳, 高建民, 郝新敏, 等. 基于KOH活化法的核桃壳基活性炭制备及其表征[J]. 安全与环境学报,2016,16(2):262−266. [ZHAO Y, GAO J M, HAO X M, et al. Preparation and characterization of walnut shell-based activated carbon based on KOH activation method[J]. Journal of Safety and Environment,2016,16(2):262−266.

    ZHAO Y, GAO J M, HAO X M, et al. Preparation and characterization of walnut shell-based activated carbon based on KOH activation method[J]. Journal of Safety and Environment, 2016, 16(2): 262-266.
    [28]
    汪树军. X射线衍射法对树脂炭微观结构测试分析[J]. 炭素技术,2000(6):8−12. [WANG S J. Microstructural analysis of resin charcoal by X-ray diffraction[J]. Carbon Technology,2000(6):8−12.

    WANG S J. Microstructural analysis of resin charcoal by X-ray diffraction[J]. Carbon Technology, 2000(6): 8-12.
    [29]
    辛赫, 张娜, 柴洋洋, 等. 薄皮核桃壳基活性炭的制备及表征[J]. 中南林业科技大学学报,2021,41(2):171−178. [XIN H, ZHANG N, CHAI Y Y, et al. Preparation and characterization of thin-skinned walnut shell-based activated carbon[J]. Journal of Central South University of Forestry Science and Technology,2021,41(2):171−178.

    XIN H, ZHANG N, CHAI Y Y, et al. Preparation and characterization of thin-skinned walnut shell-based activated carbon[J]. Journal of Central South University of Forestry Science and Technology, 2021, 41(2): 171-178.
    [30]
    王亚. 柚皮基生物炭的制备及其吸附性能研究[D]. 镇江: 江苏大学, 2017.

    WANG Y. Preparation of teak peel-based biochar and its adsorption performance[D]. Zhenjiang: Jiangsu University, 2017.
    [31]
    OZER C, IMAMOGLU M, TURHAN Y, et al. Removal of methylene blue from aqueous solutions using phosphoric acid activated carbon produced from hazelnut husks[J]. Toxicological & Environmental Chemistry Reviews,2012,94(7/8):1283−1293.
    [32]
    MAIA L S, SILVA A, CARNEIRO E S, et al. Activated carbon from palm fibres used as an adsorbent for methylene blue removal[J]. Journal of Polymers and the Environment,2021,29:1162−1175. doi: 10.1007/s10924-020-01951-0
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