YU Shiyou, XUE Qingzhuo, ZHANG Lan, et al. Preparation of Nano-sized Ceria and Analysis of Its Peroxidase Activity[J]. Science and Technology of Food Industry, 2022, 43(22): 76−82. (in Chinese with English abstract). doi: 10.13386/j.issn1002-0306.2022010277.
Citation: YU Shiyou, XUE Qingzhuo, ZHANG Lan, et al. Preparation of Nano-sized Ceria and Analysis of Its Peroxidase Activity[J]. Science and Technology of Food Industry, 2022, 43(22): 76−82. (in Chinese with English abstract). doi: 10.13386/j.issn1002-0306.2022010277.

Preparation of Nano-sized Ceria and Analysis of Its Peroxidase Activity

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  • Received Date: February 09, 2022
  • Available Online: September 18, 2022
  • In order to prepare mimetic enzyme with hydrogen peroxide catalytic activity, CeO2 was used as the research object in this paper, and nano-sized CeO2 particles with peroxidase activity were prepared by hydrothermal method. The effect of preparation conditions of hydrothermal synthesis on catalytic performance of nano-sized CeO2 for hydrogen peroxide was studied by the color reaction of Tetramethylbenzidine (TMB), including solid-liquid ratio, reaction temperature and reaction time. A nano-sized CeO2 with the best catalytic activity was selected. Its structure was characterized and its steady-state kinetics of catalytic reaction was studied. The results showed that when the ratio of solid to liquid was 1:60 g/mL, the reaction temperature was 80 ℃ and the reaction time was 8 h, the absorbance value was the largest, which was 0.501, and the catalytic performance of nano-sized CeO2 prepared by hydrothermal method was the best. The nano-sized CeO2 crystals synthesized possessed fluorite structure. The catalytic reaction was in good agreement with the Michaelis-Menten equation, and the Km value for H2O2 was 0.021 mmol/L. The results demonstrated that CeO2 synthesized under simple reaction conditions in excellent purity showed high performance catalysts for H2O2.
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