Fluorescence Detection Characteristic of Heavy-metal Chromium Ions in Water by Photoluminescent Tungsten-oxide Cluster Material

WANG Zhenwei; CHEN Xiliang; HU Xiaobing; LU Changyuan

doi:10.13386/j.issn1002-0306.2021120324

Volume 43 Issue 22

Nov. 2022

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Science and Technology of Food Industry > 2022 > 43(22): 303-309. > DOI: 10.13386/j.issn1002-0306.2021120324

WANG Zhenwei, CHEN Xiliang, HU Xiaobing, et al. Fluorescence Detection Characteristic of Heavy-metal Chromium Ions in Water by Photoluminescent Tungsten-oxide Cluster Material[J]. Science and Technology of Food Industry, 2022, 43(22): 303−309. (in Chinese with English abstract). doi: 10.13386/j.issn1002-0306.2021120324.

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Fluorescence Detection Characteristic of Heavy-metal Chromium Ions in Water by Photoluminescent Tungsten-oxide Cluster Material

1.
Yellow River Conservancy Technical Institute, Kaifeng Key Laboratory of Food Composition and Quality Assessment, Kaifeng 475004, China
2.
Yellow River Conservancy Technical Institute, Kaifeng Key Laboratory of Materials for Water Remediation, Kaifeng 475004, China
3.
Henan University, State Key Laboratory of Crop Stress Adaptation and Improvement, Kaifeng 475004, China

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Received Date: December 29, 2021
Available Online: September 05, 2022

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Abstract

Abstract

In this work, using Eu³⁺ embedded tungsten-oxygen cluster (compound 1) as the fluorescent probe material, the rapid and sensitive fluorescence detection of heavy metal Cr³⁺ ions in aqueous solution by compound 1 has been systematically studied. The selectivity, anti-interference ability and detection limit of compound 1 for fluorescence detection of Cr³⁺ ions in water were characterized and analyzed by steady-state transient fluorescence spectrometer. The results showed that compound 1 exhibited a rapid and sensitive fluorescence quenching response to heavy metal Cr³⁺ ions with strong anti-interference ability. The calculated value of quenching constant (1.41×10⁸ L·mol⁻¹·s⁻¹) was far lower than the maximum scattering collision quenching constant (2.00×10¹⁰ L·mol⁻¹·s⁻¹), which showed that compound 1 exhibited a rapid and sensitive fluorescence quenching response to heavy metal Cr³⁺ ions. Fluorescence detection results of compound 1 in the aqueous solution containing different cations and anions showed that compound 1 had strong anti-interference ability for fluorescence detection of Cr³⁺ ions in aqueous solution. The calculated results indicated that detection limit of compound 1 for Cr³⁺ ions in aqueous solution was 4.21×10⁻⁷ mol/L, which showed that compound 1 had a good detection effect on Cr³⁺ ions in water environment. This study was supposed to provide a sensitive and reliable method for the fluorescence detection of heavy metal Cr³⁺ ions in water.
- Cr³⁺ ions,
- fluorescence detection,
- tungsten-oxide cluster material,
- rare earth,
- heavy-metal,
- water

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