Thermal Stability of Ginkgolic Acids and Thermal Decomposition Kinetics of Ginkgolic Acid C15:1

LI Yuanyuan; CHEN Xiaofeng; YANG Xiaoming; LI Fengnan

doi:10.13386/j.issn1002-0306.2021100297

Volume 43 Issue 14

Jul. 2022

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Science and Technology of Food Industry > 2022 > 43(14): 77-84. > DOI: 10.13386/j.issn1002-0306.2021100297

LI Yuanyuan, CHEN Xiaofeng, YANG Xiaoming, et al. Thermal Stability of Ginkgolic Acids and Thermal Decomposition Kinetics of Ginkgolic Acid C15:1[J]. Science and Technology of Food Industry, 2022, 43(14): 77−84. (in Chinese with English abstract). doi: 10.13386/j.issn1002-0306.2021100297.

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Thermal Stability of Ginkgolic Acids and Thermal Decomposition Kinetics of Ginkgolic Acid C15:1

1.
Zhenjiang Food and Drug Supervision and Inspection Center, Zhenjiang 212004, China
2.
School of Food and Biological Engineering, Jiangsu University, Zhenjiang 212013, China

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Received Date: October 27, 2021
Available Online: May 08, 2022

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Abstract

Abstract

Thermal stability of ginkgolic acids and thermal decomposition kinetics ginkgolic acid C15:1 were investigated. Ginkgolic acid was heated at 70 ℃ for 30 d, a small amount of ginkgols were determined by liquid chromatography electrospray spray ionization mass spectrometry (LC-ESI-MS). The thermal decomposition behavior and kinetics of ginkgolic acid C15:1 were investigated by thermogravimetric analysis (TG) under the static air atmosphere at the heating rates of 5.0, 10.0, 15.0 and 20.0 ℃·min⁻¹. The thermogravimetric differential scanning curve of ginkgolic acid C15:1 was recorded and the thermal decomposition parameters were calculated by Ozawa-Flynn-Wall, Friedman, Šatava-Šesták and Coats-Redfern methods. The most obvious weight loss on the TG curves of ginkgolic acid C15:1 occurred in the first weight loss stage, the peak temperature was 243 ℃, and the weight loss rate was 14.37%, which was the decarboxylation reaction of ginkgolic acid C15:1. The calculated activation energy using Ozawa-Flynn-Wall and Friedman method was 67.44 kJ·mol⁻¹. The dynamic model function of ginkgolic acid C15:1 decarboxylation was Avrami-Erofeev equation, its integral form was G(α)=[−ln(1−α)]^1/2, and the decomposition mechanism was random nucleation and subsequent growth, and the reaction order was n=1/2. This study would provide help for the control of silver apricot acid content in ginkgo products.
- ginkgolic acid,
- thermal decomposition,
- thermogravimetric analysis,
- decomposition mechanism.

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