Ultrasound-assisted Sulfuric Acid Hydrolysis Method for Preparation and Characterization of Nanocellulose from Ginkgo Nut Shell

XUE Gang; HE Yi; LI Xiaobai; ZHANG Zhi; ZHANG Youzuo; XU Guangzhi

doi:10.13386/j.issn1002-0306.2020120006

Volume 42 Issue 14

Jul. 2021

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Science and Technology of Food Industry > 2021 > 42(14): 204-211. > DOI: 10.13386/j.issn1002-0306.2020120006

XUE Gang, HE Yi, LI Xiaobai, et al. Ultrasound-assisted Sulfuric Acid Hydrolysis Method for Preparation and Characterization of Nanocellulose from Ginkgo Nut Shell [J]. Science and Technology of Food Industry, 2021, 42(14): 204−211. (in Chinese with English abstract). doi: 10.13386/j.issn1002-0306.2020120006.

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Ultrasound-assisted Sulfuric Acid Hydrolysis Method for Preparation and Characterization of Nanocellulose from Ginkgo Nut Shell

1.
Zhejiang Provincial Key Laboratory of Agricultural Product Quality Improvement Technology, School of Agriculture and Food Science, Zhejiang A＆F University, Hangzhou 311300, China
2.
Datong Comprehensive Testing Center for Food and Drug Control, Datong 037000, China

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Received Date: December 01, 2020
Available Online: May 18, 2021

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Abstract

Abstract

In order to make full use of the by-products of industrial production of ginkgo, this study used ginkgo nut shell as raw materials and adopt ultrasonic-assisted sulfuric acid hydrolysis to prepare ginkgo nut shell nanocrystalline cellulose (nanocrystalline cellulose isolated from ginkgo nut shell, NCC-GNS). The effects of three factors (e.g. sulfuric acid mass fraction, reaction temperature, reaction time) on nanocellulose yield were investigated by single-factor tests, and orthogonal experiments were used to optimize them to obtain the best preparation conditions for NCC-GNS. Taking nanocrystalline cellulose (nanocrystalline cellulose, NCC) prepared by conventional sulfuric acid hydrolysis (without ultrasound assistance) as a control, analyzed the impact of ultrasound-assisted processing on NCC-GNS through scanning electron microscopy (SEM), transmission electron microscopy (TEM), Zeta potential and dynamic light scattering (DLS), X-ray diffraction (x-ray diffraction, XRD), Fourier transform infrared spectroscopy (FT-IR), thermogravimetric analysis (TGA), etc. The results showed that the optimal conditions for preparing NCC-GNS were sulfuric acid mass fraction of 48%, reaction temperature of 60 °C, reaction time of 25 min under the condition of ultrasonic power of 120 W. The NCC-GNS yield under optimal conditions was 37.01%. The NCC-GNS prepared by ultrasonic-assisted and conventional sulfuric acid hydrolysis methods were long rods with no significant difference in size. The length and diameter of the NCC-GNS prepared by ultrasonic-assisted were relatively concentrated with a length of 80~180 nm and a diameter of 3.5~5.5 nm. The crystallinity of NCC-GNS prepared by ultrasound was 88%, which was higher than 75% of conventional sulfuric acid hydrolysis. The NCC-GNS prepared by the two methods had lower Zeta potential and good thermal stability. In summary, the yield of NCC-GNS prepared by ultrasonic-assisted sulfuric acid hydrolysis was high, and the obtained NCC-GNS had high crystallinity and good thermal stability, which was expected to have better applications in the field of biomass composite materials.
- optimization,
- ginkgo nut shell,
- nanocrystalline cellulose,
- ultrasound-assisted,
- preparation,
- characterization

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