Adsorption of Phenolic Acids from Sucrose Solution by Chitosan Modified Montmorillonite

LIU Fujie; WU Hailing; PAN Yanmei; LIAO Zhengda; SU Long

doi:10.13386/j.issn1002-0306.2020100058

Volume 42 Issue 21

Oct. 2021

Turn off MathJax

Article Contents

Abstract

References

Science and Technology of Food Industry > 2021 > 42(21): 17-24. > DOI: 10.13386/j.issn1002-0306.2020100058

LIU Fujie, WU Hailing, PAN Yanmei, et al. Adsorption of Phenolic Acids from Sucrose Solution by Chitosan Modified Montmorillonite[J]. Science and Technology of Food Industry, 2021, 42(21): 17−24. (in Chinese with English abstract). doi: 10.13386/j.issn1002-0306.2020100058.

Citation:

PDF (2577 KB)

Adsorption of Phenolic Acids from Sucrose Solution by Chitosan Modified Montmorillonite

College of Food and Biochemical Engineering, Guangxi Science and Technology Normal University, Laibin 546119, China

More Information

Received Date: October 11, 2020
Available Online: August 26, 2021

Graphical Abstract

Abstract

Abstract

Chitosan modified montmorillonite was prepared by coprecipitation method and used to adsorb phenolic acids in sucrose solution. It was characterized by SEM, FT-IR, XPS and BET. The results showed that chitosan was successfully loaded on the surface of montmorillonite to prepare chitosan modified montmorillonite. The isoelectric point of modified montmorillonite was 7.84, and gallic acid in sucrose solution was mainly adsorbed by electrostatic force and amine group. The results of adsorption test showed that the modified montmorillonite had better adsorption performance for gallic acid. The optimal pH of chitosan modified montmorillonite for gallic acid adsorption in sucrose solution was 7.0, and the equilibrium time was 600 min. The adsorption process of chitosan modified montmorillonite for gallic acid was more in line with Freundlich model and quasi second order adsorption kinetic equation. The adsorption process was mainly multimolecular layer adsorption and chemical adsorption, and the saturated adsorption capacity reached 58.82 mg/g. Chitosan modified montmorillonite exhibited a good regeneration performance and good adsorption effect on phenolic acids in sucrose solution. It performed a promising clarifier for sugar.
- montmorillonite,
- chitosan,
- phenolic acid,
- adsorption,
- sugarcane juice

FullText(HTML)

References (27)

References

[1]	林波. 广西甘蔗糖业二次创业竞争性研究[D]. 南宁: 广西大学, 2018. Lin Bo. Study on the second entrepreneurship competitiveness of Guangxi Sugarcane industry[D]. Nanning: Guangxi University, 2018.
[2]	Song X R, Chai Z H, Zhu Y, et al. Preparation and characterization of magnetic chitosan-modified diatomite for the removal of gallic acid and caffeic acid from sugar solution[J]. Carbohydrate Polymers,2019,274:48−55.
[3]	程江玲. 以原糖为原料制备高纯蔗糖糖浆的工艺研究[D]. 广州: 华南理工大学, 2014. Cheng Jiangling. Study on the process of preparing high purity sucrose syrup from raw sugar[D]. Guangzhou: South China University of Technology, 2014.
[4]	何惠欢, 梁贤慧, 陆登俊. 蔗汁澄清过程各种酚类含量变化的研究[J]. 食品科技,2015,40(5):105−109. [He Huihuan, Liang Xiaohui, Lu Dengjun. Study on the changes of phenolic contents in sugarcane juice during clarification process[J]. Food Science and Technology,2015,40(5):105−109.
[5]	Aparecida D S S J, Figueiredo Angolini C F, Eberlin M N, et al. Criegee mechanism as a safe pathway of color reduction in sugarcane juice by ozonation[J]. Food Chemistry,2017,225(15):181−187.
[6]	Susanto H, Roihatin A, Widiasa I N. Production of colorless liquid sugar by ultrafiltration coupled with ion exchange[J]. Food & Bioproducts Processing,2016,98:11−20.
[7]	Saha N K, Balakrishnan M, Ulbricht M. Fouling control in sugarcane juice ultraﬁltration with surface modiﬁed polysulfone and polyethersulfone membranes[J]. Desalination,2009,249(3):1124−1131. doi: 10.1016/j.desal.2009.05.013
[8]	Laksameethanasana P, Somla N, Janprem S, et al. Clarification of sugarcane juice for syrup production[J]. Procedia Engineering,2012,32:141−147. doi: 10.1016/j.proeng.2012.01.1248
[9]	Zhou Youquan, Tang Tingfan, Cheng Hao, et al. Science and Technology of Food Industry[J], 2020, 41(3): 12-15, 21.
[10]	Ma J, Lei Y, Khan M A, et al. Adsorption properties, kinetics & thermodynamics of tetracycline on carboxymethyl-chitosan reformed montmorillonite[J]. International Journal of Biological Macromolecules,2019,124:557−567. doi: 10.1016/j.ijbiomac.2018.11.235
[11]	Wang G, Xu J, Sun Z, et al. Surface functionalization of montmorillonite with chitosan and role of surface properties on its adsorptive performance: A comparative study on mycotoxins adsorption[J]. Langmuir,2020,2:1−35.
[12]	王静, 孙美乔. 壳聚糖改性沸石吸附性能的影响因素研究[J]. 供水技术,2019,13(2):6−9. [Wang Jing, Sun Meiqiao. Study on influencing factors of adsorption properties of Chitosan modified zeolites[J]. Water Supply Technology,2019,13(2):6−9. doi: 10.3969/j.issn.1673-9353.2019.02.002
[13]	胡超, 王有宁, 郑足红. 蒙脱石-壳聚糖复合物对磷吸附性能的研究[J]. 农业环境科学学报,2017,36(10):2086−2091. [Hu Chao, Wang Youning, Zheng Zuhong. Study on phosphorus adsorption properties of montmorillonite-chitosan complex[J]. Journal of Agro-Environment Science,2017,36(10):2086−2091. doi: 10.11654/jaes.2017-0402
[14]	Gatabi M P, Moghaddam H M, Ghorbani M. Point of zero charge of maghemite decorated multiwalled carbon nanotubes fabricated by chemical precipitation method[J]. Journal of Molecular Liquids,2016,216:117−125. doi: 10.1016/j.molliq.2015.12.087
[15]	Wei J, Tu C, Yuan G, et al. Carbon-coated montmorillonite nanocomposite for the removal of chromium(VI) from aqueous Solutions[J]. Journal of Hazardous Materials,2019,368:541−549. doi: 10.1016/j.jhazmat.2019.01.080
[16]	Aswin K I, Viswanathan N. Development and reuse of amine-Grafted chitosan hybrid beads in the retention of nitrate and phosphate[J]. Journal of Chemical and Engineering Data,2018,63(1):147−158. doi: 10.1021/acs.jced.7b00751
[17]	Lee M Y, Hong K J, Kajiuchi T, et al. Synthesis of chitosan-based polymeric surfactants and their adsorption properties for heavy metals and fatty acids[J]. International Journal of Biological Macromolecules,2005,36(3):152−158. doi: 10.1016/j.ijbiomac.2005.05.004
[18]	Akyuz L, Kaya M, Koc B, et al. Diatomite as a novel composite ingredient for chitosan ﬁlm with enhanced physicochemical prop-erties[J]. International Journal of Biological Macromolecules,2017,105:1401−1411. doi: 10.1016/j.ijbiomac.2017.08.161
[19]	梁兴唐, 李凤枝, 钟书明, 等. 聚乙烯亚胺原位改性多孔灯芯草高效吸附废水中的Cr(Ⅵ)[J]. 化工学报,2019,72(6):3380−3389. [Liang Xingtang, Li Fengzhi, Zhong Shuming, et al. Adsorption of Cr(Ⅵ) from wastewater by polythyleneimine modified porous cordwood[J]. Journal of Chemical Engineering and Technology,2019,72(6):3380−3389.
[20]	Fan L, Zhang Y, Li X, et al. Removal of alizarin red from water environment using magnetic chitosan with Alizarin Red as imprinted molecules[J]. Colloids Surf B Biointerfaces,2012,91:250−257. doi: 10.1016/j.colsurfb.2011.11.014
[21]	Fan S L, Huang Z Q, Zhang Y J, et al. Magnetic chitosan-hydroxyapatite composite microspheres: Preparation, characterization, and application for the adsorption of phenolic substances[J]. Bioresource Technology,2019,274:48−55. doi: 10.1016/j.biortech.2018.11.078
[22]	张宇松. Fe₂O₃/MCM-41吸附去除及催化H₂O₂/PMS降解RhB的研究[D]. 青岛: 青岛科技大学, 2016. Zhang Yusong. Adsorption removal of Fe₂O₃/McM-41 and catalytic degradation of RhB by H₂O₂/PMS[D]. Qingdao: Qingdao University of Science and Technology, 2016.
[23]	Wang G F, Xu J, Sun Z M. Surface functionalization of montmorillonite with chitosan and the role of surface properties on its adsorptive performance: A comparative study on mycotoxins adsorption[J]. Langmuir: the ACS Journal of Surfaces and Colloids,2020,36(10):2601−2611. doi: 10.1021/acs.langmuir.9b03673
[24]	Yang M J, Lin J W, Zhan Y H, et al. Immobilization of phosphorus from water and sediment using zirconium-modified zeolites[J]. Environmental Science and Pollution Research International,2015,22(5):3606−3619. doi: 10.1007/s11356-014-3604-2
[25]	Ahmat A M, Thiebault T, Guegan R. Phenolic acids interactions with clay minerals: A spotlight on the adsorption mechanisms of Gallic Acid onto montmorillonite[J]. Applied Clay Science,2019,180:1−8.
[26]	彭莎. 改性沸石吸附水中典型污染物的性能与机理研究[D]. 武汉: 武汉大学, 2016. Peng Sha. Study on the performance and mechanism of modified zeolite adsorption of typical pollutants in water[D]. Wuhan: Wuhan University, 2016.
[27]	张晓涛. 木质纤维素/层状硅酸盐纳米复合材料的制备及吸附性能研究[D]. 内蒙古: 内蒙古农业大学, 2018. Zhang Xiaotao. Preparation and adsorption properties of lignocellulose/layered silicate nanocomposites[D]. Inner Mongolia: Inner Mongolia Agricultural University, 2018.

[1]	LU Qi, XUE Shujing, YANG De, WANG Shaohua, LI Lu. Effects of Different Processing Methods on the Volatile Components and Antioxidant Ability of the Water Extracts from Stropharia rugosoannulata[J]. Science and Technology of Food Industry, 2021, 42(23): 41-48. DOI: 10.13386/j.issn1002-0306.2021020072
[2]	SHIAU Syyu, LI Ying, PAN Weicheng. Physico-chemical and Antioxidant Properties of Noodle Enriched with Beetroot Puree[J]. Science and Technology of Food Industry, 2021, 42(13): 33-38. DOI: 10.13386/j.issn1002-0306.2020070353
[3]	ZHANG Li-hui, WANG Chao, LIAO Li, WANG Jun, CHEN Xue-ling, QIAO Yu. Antioxidant Activity of Alcohol Extracts from Different Varieties of Yam Peel[J]. Science and Technology of Food Industry, 2019, 40(4): 27-33. DOI: 10.13386/j.issn1002-0306.2019.04.005
[4]	CHENG Yong-jie, CHEN Xiao-wei, ZHANG Sha-sha, LOU Jian, ZHANG Ting, WANG Zhen-zhen, MAO Yang-chen, SHA Ru-yi, MAO Jian-wei. Analysis of amino acids and in vitro antioxidant activity of Cudrania tricuspidata Jiaosu[J]. Science and Technology of Food Industry, 2018, 39(6): 1-7,12. DOI: 10.13386/j.issn1002-0306.2018.06.001
[5]	LIU Yu-ge, FU Qiong, MA Fei-yue, ZHANG Xiu-mei. Antioxidant activities of papaya leaf extracts with different extraction solvents[J]. Science and Technology of Food Industry, 2017, (21): 12-16. DOI: 10.13386/j.issn1002-0306.2017.21.003
[6]	WU Hui-lun, ZHANG Yi-ming, GUAN Man, JIANG Hai-yun, XIE Jing, SUN Tao. The Maillard reaction of inulin with arginine and the antioxidant activity of inulin derivatives[J]. Science and Technology of Food Industry, 2016, (06): 179-181. DOI: 10.13386/j.issn1002-0306.2016.06.028
[7]	LIANG Kai, JIANG Yu-mei, LI Ji-xin, MI Lan, ZHANG Bing-jing. Active compound extraction from sea-buckthorn fruit and antioxidation activity research[J]. Science and Technology of Food Industry, 2014, (24): 264-269. DOI: 10.13386/j.issn1002-0306.2014.24.048
[8]	Antioxidant activities of oregano oil, carvacrol, citral and cinnamaldehyde[J]. Science and Technology of Food Industry, 2013, (14): 311-313. DOI: 10.13386/j.issn1002-0306.2013.14.079
[9]	茶多酚对色拉油的抗氧化作用[J]. Science and Technology of Food Industry, 1999, (06): 27-28. DOI: 10.13386/j.issn1002-0306.1999.06.069
[10]	柿叶乙醇提取物在猪油中的抗氧化性研究[J]. Science and Technology of Food Industry, 1999, (05): 22-23. DOI: 10.13386/j.issn1002-0306.1999.05.006

Supplements (0)

Cited By

Cited by

Periodical cited type(6)

1.	毕泗伟. 食品安全监督抽检在食品监管中的作用. 食品安全导刊. 2025(05): 36-38 .
2.	韩世鹤，江逸楠，李红，李家琦，李立，王亚珅. 基于食品抽检数据的区域性风险预警模型构建. 食品工业. 2024(10): 112-117 .
3.	代亚男，左莹，刘峻，章若红. 关于食品相关产品生产许可中限量物质检测方法标准研究. 轻工标准与质量. 2023(02): 30-32 .
4.	吴庆勇，金鹏，李红. 食品中有机氯农药残留超标危害与检测技术. 食品安全导刊. 2023(17): 180-182 .
5.	蓝小飞，谢琳，张丽娟，陈婷，施文婷. 食品安全指数法评价嘉兴市售水产品污染物残留风险. 湖北农业科学. 2023(S1): 200-204 .
6.	黄财源. 食品安全抽检工作面临的问题与对策研究. 中国食品工业. 2023(24): 54-55+91 .