Composition Analysis of Xilin Fire Ginger Oleoresins
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摘要: 以西林火姜干姜片为原料,通过索氏提取分别制备石油醚姜油树脂(ginger oleoresin extracted by petroleum ether,PEGO)和无水乙醇姜油树脂(ginger oleoresin extracted by absolute ethanol,AEGO)并研究其成分组成。结果显示:PEGO和AEGO经GC-MS分别鉴定出46、38种挥发性成分,主要为姜烯、β-倍半水芹烯,α-法呢烯、β-红没药烯、α-姜黄烯、α-柠檬醛、β-柠檬醛、β-水芹烯、桉叶油醇、2-茨醇等萜烯类化合物和6-姜酚、6-姜烯酚、8-姜烯酚等难挥发性姜辣素化合物。另外,还检测出丰富的脂肪酸、总酚、黄酮和甾醇等非挥发性成分,脂肪酸均主要为棕榈酸、亚油酸、羊脂酸、月桂酸、硬脂酸、低羊脂酸、豆蔻酸、反油酸、油酸等,不饱和脂肪酸以亚油酸和油酸为主,其中亚油酸含量均高达20%以上;PEGO和AEGO总酚含量分别为118.61±1.55、105.36±1.09 mg GAE/g;黄酮含量分别为15.72±0.51、13.36±0.03 mg RE/g;总甾醇含量分别为4.86±0.02、3.54±0.07 mg/g,且组成均为菜油甾醇、豆甾醇、β-谷甾醇。研究表明,西林火姜姜油树脂含有丰富的营养物质、风味物质和活性物质,并且提取溶剂对姜油树脂的物质组成和含量都具有一定影响。Abstract: Took dry ginger slices of Xilin ginger as raw materials, ginger oleoresin extracted by petroleum ether(PEGO) and ginger oleoresin extracted by absolute ethanol(AEGO) were obtained by Soxhlet extraction to study their compositions. PEGO and AEGO were identified 46 and 38 volatile components by GC-MS, respectively. They mainly were terpenes which included(-) -zingiberene, β-sesquiphellandrene, α-farnesene, β-bisabolene, α-curcumene, α-citral, β-citral, β-phellandrene, eucalyptol, endo-borneol, and pungents which included 6-gingerol, 6-shogaol, cis-8-shogaol.In addition, a large numberof fatty acids, total phenols, flavonoids, and sterols as non-volatile components were also detected.Their main fatty acids were palmitic acid, linoleic acid, caprylic acid, lauric acid, stearic acid, low-caprylic acid, myristic acid, trans-oleic acid, oleic acid and so on, linoleic acid and oleic acid were dominant unsaturated fatty acid, and the contents of linoleic acid of them were above 20%;In PEGO and AEGO, the total phenolic content was 118.61±1.55 and 105.36±1.09 mg GAE/g;flavonoid content was 15.72±0.51 and 13.36±0.03 mg RE/g;the total sterol content was 4.86±0.02 and 3.54±0.07 mg/g, and all made up of campesterol, stigmasterol and β-sitosterol. It could be concluded that oleoresins from Xilin fire ginger contained the compounds which contribute to nutrition, distinctive flavor and bioactive function, and the extraction solvent had a certain influence on the composition and content of ginger oleoresins.
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Keywords:
- ginger oleoresin /
- volatile components /
- fatty acid /
- total phenols /
- flavonoids /
- sterols
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