不同提取溶剂对余甘子核仁油品质的影响

张雯雯; 李坤; 郑华; 刘兰香; 葛双双; 张弘

doi:10.13386/j.issn1002-0306.2017.02.042

不同提取溶剂对余甘子核仁油品质的影响

张雯雯¹,
李坤^1,2,
郑华^1,2,
刘兰香¹,
葛双双¹,
张弘^1,2

1. 中国林业科学研究院资源昆虫研究所
2. 国家林业局特色森林资源工程技术研究中心

基金项目:

中央级公益性科研院所基本科研业务费专项(riricaf2015003M)；国家重点研发计划项目(2016YFD0600806)；

详细信息

作者简介:
张雯雯(1985-),女,硕士,助理研究员,研究方向:天然产物开发与利用,E-mail:zhangwenwen1105@163.com。;

张弘(1963-),男,研究员,研究方向:林业生物资源化学与工程,E-mail:kmzhhong@163.com。;

中图分类号: TS224
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出版历程
- 收稿日期: 2016-07-17

Quality analysis of Phyllanthus emblic L.seed oil extracted by different solvents

Research Institute of Resources Insects,Chinese Academy of Forestry
Research Center of Engineering and Technology of Characteristic Forest Resources,State Forestry Administration

摘要

摘要: 研究旨在探寻不同提取溶剂对余甘子核仁油品质的影响,为余甘子核仁油的进一步开发与利用提供参考依据。以机械压榨法为参照,对比了8种不同类型提取溶剂对余甘子核仁油品质的影响,结果发现:采用压榨法提取余甘子核仁油的含油量仅为4.71%,与压榨法相比,溶剂法更适合余甘子核仁油的提取,含油量均大于14%。在此基础上,以GC-MS（气相色谱质谱联用）法对提取所得余甘子核仁油的脂肪酸组成进行分析后发现,余甘子核仁油的主要脂肪酸组成为α-亚麻酸、亚油酸、油酸、棕榈酸和硬脂酸等5种脂肪酸,其相对百分含量之和达98%以上。余甘子核仁油中的多不饱和脂肪酸为α-亚麻酸和亚油酸,二者相对百分含量之和超过60%,其中含量最高的多不饱和脂肪酸为α-亚麻酸,其相对百分含量超过44%。通过整体分析看出,在选取的8种不同类型溶剂中,长链小极性溶剂更有利于提高余甘子核仁油的品质。其中,正己烷为余甘子核仁油的理想溶剂,不仅油脂提取率高,油脂色泽和透明度优于其他几种溶剂,P/S值（不饱和脂肪酸与饱和脂肪酸含量的比值）也相对较高,且含有微量菜油甾醇。
- 余甘子核仁油; /
- 理化性质; /
- 脂肪酸; /
- 品质分析; /
Abstract: The purpose of this study was to explore the influence of different solvents on quality of Phyllanthus emblica L.seed oil,and provide the theory basis for further development.Phyllanthus emblica L.seed oil was extracted by 8 kinds of solvents,the quality of them were compared,at the same time mechanical crushing method was to be referenced. The results showed that Phyllanthus emblica L.seed oil extraction rate was 4.71% by mechanical crushing method while solvent extraction rate was more than 14%,solvent extraction was more suitable compared with mechanical crushing method.Fatty compositions were detected by gas chromatography- mass spectrometry,α- linolenic acid,linoleic acid,oleic acid,palmitic acid and stearic acid were the main components in Phyllanthus emblica L. seed oil,the relative contents of these five kinds of fatty acids were above 98%.α- linolenic acid and linoleic acid were polyunsaturated fatty acids in the oil,the relative content of them were more than 60%,while α- linolenic acid was more than 44%.It was found that the quality of oil extracted by long chain and small- polar solvents was better than others we selected.N- hexane was a kind of ideal solvent,the oil extracted by n- hexane was better than other solvents in extraction rate,lovibond colour,transparency and P / S,furthermore,trace amount of campesterol was detected in it.
- Phyllanthus emblica L; /
- seed oil; /
- physicochemical properties; /
- fatty acid; /
- quality analysis;

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参考文献(36)

[1]	潘颉,钟秋平,赵新河.余甘子功能性成分研究和多酚的提取[J].食品工业科技,2009,30(8):234-235,318.
[2]	许仕杰,李耿,陈建南,等.余甘子果酒镇咳祛痰的药效研究[J].中国中医药咨讯,2010,2(15):165-167.
[3]	中华人民共和国卫生部药典委员会.中华人民共和国药典[M].北京:化学工业出版社,2010:167.
[4]	吴少雄,周玲仙.余甘果的营养成分研究[J].昆明医学院学报,1995,16(2):27-28.
[5]	王辉.余甘子的化学成分和药理作用研究进展[J].中国现代中药,2011,13(11):52-56.
[6]	Xu M,Zhu H T,Cheng R R,et al.Antioxidant and hyaluronidase inhibitory activities of diverse phenolics in Phyllanthus emblica[J/OL].Natural Product Research,2016,http://dx.doi.org/10.1080/14786419.2015.1137573.
[7]	Liu X L,Zhao M M,Wu K G,et al.Immunomodulatory and anticancer activities of phenolics from emblica fruit(Phyllanthus emblica L.)[J].Food Chemistry,2012,131:685-690.
[8]	Singh B,Sharma R A.Antioxidant and Antimicrobial Activitiesof Callus Culture and Fruits of Phyllanthus emblica L.[J].Journal of Herbs,Spices&Medicinal Plants,2015,21(3):230-242.
[9]	Mahesh T,Vaithinathan S,Leonidas T,et al.Protective effects of Phyllanthus emblica against myocardial ischemia-reperfusion injury:the role of PI3-kinase/glycogen synthase kinase 3β/β-catenin pathway[J].Journal of Physiology and Biochemistry,2015,71(4):623-633.
[10]	Lu C C,Yang S H,Hsia S M,et al.Inhibitory effects of Phyllanthus emblica L.on hepatic steatosis and liver fibrosis in vitro[J].Journal of Functional Foods,2016,20:20-30.
[11]	赵谋明,刘晓丽.余甘子的保健功能及其作为食品资源的潜力[J].食品科学,2005,26(增刊1):98-101.
[12]	Colucci R,Dragoni F,Conti R,et al.Evaluation of an oral supplement containing Phyllanthus emblica fruit extracts,vitamin E,and carotenoids in vitiligo treatment[J].Dermatologic Therapy,2015,28(1):17-21.
[13]	余小林,徐步前,曾贤强.余甘子-椪柑复合果汁饮料加工工艺研究[J].食品工业科技,2006,27(2):139-141.
[14]	Poltanov E A,Shikov A N,Dorman H J D,et al.Chemical and antioxidant evaluation of Indian gooseberry(Emblica officinalis Gaertn.,syn.Phyllanthus emblica L.)supplements[J].Phytotherapy Research,2009,23:1309-1315.
[15]	张雯雯,张弘,郑华,等.余甘子核仁油的微波辅助萃取工艺优化及脂肪酸组成分析[J].食品科学,2013,34(20):13-18.
[16]	胡国庆,熊常健,朱岳麟,等.余甘子果核油组分性质及介电精制研究[J].天津理工大学学报,2012,28(4-5):41-45.
[17]	Pawlosky R J,Hibbeln J R,Novotny J A,et al.Physiological compartmental analysis ofα-linolenic acid metabolism in adult humans[J].Journal of Lipid Research,2001,42:1257-1265.
[18]	Denis I,Potier B,Heberden C,et al.Omega-3polyunsaturated fatty acids and brain aging[J].Current Opinion in Clinical Nutrition and Metabolic Care,2015,18(2):139-146.
[19]	孙翔宇,高贵田,段爱莉,等.多不饱和脂肪酸的研究进展[J].食品工业科技,2012(7):418-423.
[20]	赵谋明,刘晓丽,罗维,等.超临界CO2萃取余甘子籽油及其成分研究[J].林产化学与工业,2007,27(5):107-112.
[21]	王海波,李昌宝,李杰民,等.闪式提取法提取余甘子籽油[J].食品工业科技,2013,34(7):286-289.
[22]	张德权,胡晓丹.食品超临界CO2流体加工技术[M].北京:化学工业出版社,2005:3.
[23]	蔺建学,徐速,江连洲.油料作物制油工艺现状与冷榨制油的研究进展[J].大豆科技,2013(1):29-35.
[24]	何志勇,夏文水.两种不同橄榄核仁油中脂肪酸组成的GC/MS分析[J].食品科学,2006,27(3):188-190.
[25]	陆占国,李伟,刘向阳.不同溶剂中超声波辅助萃取酸浆果籽油脂及GC/MS成分分析[J].北京工商大学学报:自然科学版,2010,28(4):16-20.
[26]	陆占国,郑国臣,余善明.超临界CO2流体萃取的酸浆籽油的成分分析[J].食品与机械,2007,23(2):88-89,113.
[27]	王渊,谭晓风,谢鹏,等.油茶优良无性系的理化性质及脂肪酸的分析[J].中南林业科技大学学报,2011,31(6):70-74.
[28]	毕艳兰.油脂化学[M].北京:化学工业出版社,2005:264.
[29]	陈友根.油脂的理化测定值及其意义(译文)[J].粮食贮藏,1979(4):48-54.
[30]	邓立阳,王若兰,王永.气调储藏条件下茶籽品质变化规律的研究[J].农产品加工·学刊:下,2014(9):13-16.
[31]	周立新,黄凤洪,严兴初,等.α-亚麻酸与γ-亚麻酸[J].西部粮油科技,2000,25(6):46-48.
[32]	李高阳,丁霄霖.亚麻籽油中脂肪酸成分的GC-MS分析[J].食品与机械,2005,21(5):30-32.
[33]	许万乐,李会珍,张志军,等.紫苏籽油理化性质测定及脂肪酸组分分析[J].中国粮油学报,2013,28(12):106-109.
[34]	欧阳玉祝,张晓旭,唐顼婉.制备方法对八月瓜果籽油化学成分的影响[J].食品科学,2015,36(22):142-146.
[35]	任建敏.食物中植物甾醇生理活性及药理作用研究进展[J].食品工业科技,2015,36(22):389-393,399.
[36]	文镜,樊蓉.植物甾醇和植物甾烷醇降胆固醇的功效和安全性[J].食品科学,2005,26(8):437-442.

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