Study of application of 60Co- γ irradiation in degradation of four Sudan red dyes and two veterinary drugs residues in foods
-
摘要: 采用60Co-γ辐照分别对含有3-甲基-喹噁啉-2-羧酸(MQCA)、氯霉素和苏丹红ⅠⅣ的动物源食品进行处理,设置辐照剂量为010 k Gy,考察了其在不同辐照剂量下的降解情况。结果表明,当辐照剂量为9 k Gy时,鸡肉中MQCA和蛋液中苏丹红ⅠⅣ的降解效果非常显著,降解率分别为99.0%和83.5%95.7%;而蛋粉中的苏丹红ⅠⅣ的降解效果相对较差,降解率仅为9.3%22.3%;鳗鱼冻干粉中氯霉素的降解效果比较显著,降解率为75.3%。随着辐照剂量的增大,其降解率逐渐增大。研究表明辐照处理可对食品中某些化合物产生有效降解。
-
关键词:
- γ-辐照 /
- 氯霉素 /
- 3-甲基-喹噁啉-2-羧酸 /
- 苏丹红染料 /
- 降解
Abstract: The effects of radiation dose on the degradation rate of 3- methyl- quinoxaline- 2- carboxylic acid( MQCA),chloramphenicol and SudanⅠⅣ were studied.60Co- γ ray at different radiation doses( 0 ~10 k Gy) was applied for the foods of animal origin contaminated with residues.The results showed that60Co- γ irradiation could significantly degrade MQCA in chicken and Sudan Ⅰ~ Ⅳ in egg liquid.When the radiation dose was 9 k Gy,the degradation rates were up to 99.0% and 83.5% ~ 95.7%,respectively.The degrading effect of sudan Ⅰ~ Ⅳ in egg powder were not obvious,the degradation rates were only 9.3% ~ 22.3%. And the degradation of chloramphenicol was 75.3%.To all of them,the degradation rate went up with the increase of radiation dose.This study showed that irradiation treatment was effective to degrade some compounds in foods.-
Keywords:
- γ-radition /
- chloramphenicol /
- 3-methyl-quinoxaline-2-carboxylic acid /
- Sudan dyes /
- degradation
-
[1] 郭霞,丁义,孙振中,等.水产品中喹乙醇及其主要代谢物残留的研究进展[J].中国动物检疫,2012,(10):69-71. [2] Joint Expert Committee on Food Additives.FAO/WHO.Evaluation of Certain Veterinary Drug Residues in Food,Technical Series[R].Geneva:World Health Organization,1995:19.
[3] 薄永恒,杨林,陆庆泉,等.兽药喹乙醇的临床应用及安全性评价研究进展[J].兽医导刊,2014,02:37-38. [4] 曹巧玲,杨凯,武泽新,等.氯霉素的毒性作用和检测方法研究进展[J].职业与健康,2013,29(16):2095-2097. [5] 魏明,侯进.苏丹红的毒性研究进展[J].医学综述,2012,18(21):3619-3621. [6] 聂雪梅,李立,孙利,等.2008-2010年欧盟动物(源)产品兽药残留监控情况分析[J].中国动物检疫,2013,(12):35-38. [7] Wojciech Baran,Ewa Adamek,Justyna,et al.Effects of the presence of sulfonamides in the environment and their influence on human health[J].Journal of Hazardous Materials,2011,196:1-15.
[8] 董启武,何明才,刘和,等.浅谈兽药残留的危害及应对措施[J].上海畜牧兽医通讯,2014,(3):90-90,92. [9] 李存.动物源性食品兽药残留及其危害[J].兽医导刊,2013,(3):47-49,61. [10] 陆昌华,吴孜忞,胡肄农,等.疫病及兽药残留事件暴发的经济损失评估模型构建[J].江苏农业学报,2014,30(1):212-218. [11] Yuankun Liu,Jianlong Wang.Degradation of sulfamethazine by gamma irradiation in the presence of hydrogen peroxide[J].Journal of Hazardous Materials,2013,250-251:99-105.
[12] Yuanzhi Hong,Ao Ren,Yinhua Jiang,et al.Sol-gel synthesis of visible-light-driven Ni(1-x)Cu(x)Fe2O4photocatalysts for degradation of tetracycline[J].Ceramics International,2015,41(1):1477-1486.
[13] Xiang-Dong Zhu,Yu-Jun Wang,Rui-Juan Sun,et al.Photocatalytic degradation of tetracycline in aqueous solution by nanosized Ti O2[J].Chemosphere,2013,92(8):925-932.
[14] 马艳,高乃云,张东,等.UV-C辐照降解水中磺胺类药物[J].净水技术,2014,33(3):75-78,83. [15] Francisca C Moreira,Rui A R Boaventura,Enric Brillas,et al.Degradation of trimethoprim antibiotic by UVA photoelectroFenton process mediated by Fe(III)-carboxylate complexes[J].Applied Catalysis B:Environmental,2015,162:34-44.
[16] Falk Harnisch,Carla,Gimkiewicz,et al.On the removal of sulfonamides using microbial bioelectrochemical systems[J].Electrochemistry Communications,2013,26:77-80.
[17] Shao-Peng Rong,Ya-Bing Sun,Ze-Hua Zhao.Degradation of sulfadiazine antibiotics by water falling film dielectric barrier discharge[J].Chinese Chemical Letters,2014,25(1):187-192.
[18] 张振山,刘双燕,刘玉兰,等.辐照在食品工业中的应用研究进展[J].中国调味品,2013,38(11):113-116. [19] Alejandra Tomac,Rodolfo Horacio Mascheroni,María Isabel Yeannes.Modelling the effect of gamma irradiation on the inactivation and growth kinetics of psychrotrophic bacteria in squid rings during refrigerated storage.Shelf-life predictions[J].Journal of Food Engineering,2013,117(2):211-216.
[20] 李飞,陈绍军,曾红亮,等.辐照烤鳗质量风险评估[J].中国食品学报,2013,10:177-183. [21] 王锋,谢芳,周洪杰,等.辐照对蜂蜜中残留氯霉素和理化指标的影响[J].食品工业科技,2010,31(8):78-80,83. [22] Zhaobing Guo,Fei Zhou,Yongfu Zhao,et al.Gamma irradiation-induced sulfadiazine degradation and its removal mechanisms[J].Chemical Engineering Journal,2012,191:256-262.
[23] 王锋,谢芳,周洪杰,等.辐照蜂蜜和虾中残留氯霉素降解效果的研究[J].中国畜牧兽医,2010,37(5):221-223. [24] Tamás Csay,Gergely Rácz,Erzsébet Takács,et al.Radiation induced degradation of pharmaceutical residues in water:Chloramphenicol[J].Radiation Physics and Chemistry,2012,81(9):1489-1494.
[25] 黄佳佳,徐振林,罗翠红,等.电子束辐照在食品中兽药残留降解的应用[J].食品工业科技,2011,(1):313-317. [26] 李军,田毅峰,王爱芹,等.电子束辐照降解鸡肉中两种兽药残留的研究[J].食品研究与开发,2013,34(5):124-126. [27] 陈其勇,吴若昕,刘旸,等.电子束辐照降解人参口服液多种农药残留的可行性研究[J].核农学报,2013,27(7):952-956. [28] 郭照冰,周飞,赵永富,等.γ辐照降解水中磺胺嘧啶的研究[J].环境科学学报,2011,31(12):2629-2633.
计量
- 文章访问数: 149
- HTML全文浏览量: 11
- PDF下载量: 124