Study on the difference of organic acids and free fatty acids in different Chinese rice wine
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摘要: 通过高效液相色谱、气相色谱法分别测定了全国不同地区的12种黄酒中的有机酸和游离脂肪酸含量,并以9种有机酸和5种游离脂肪酸为变量进行主成分分析。结果表明:黄酒有机酸中乳酸、乙酸和柠檬酸的含量最高,占总有机酸的80%以上;前4个主成分能代表12种样品中有机酸含量85.276%的信息,因子得分真实地反映了样品的产地、原料、工艺与有机酸的关联性。黄酒中游离脂肪酸种类丰富而且总量差异大,第一主成分、第二主成分累积贡献率达61.783%、83.822%,能够较好地代表原始数据所反映的信息,第一主成分包含C18∶0、C16∶0,第二主成分包含C14∶0、C18∶1,这4种物质对黄酒整体风味的作用可分为三种,即C18∶0和C16∶0、C14∶0、C18∶1。Abstract: The concentration of organic acids and free fatty acids in 12 kinds of Chinese rice wine from different areas were determined by high performance liquid chromatography (HPLC) and gas chromatography (GC) . Nine kinds of organic acids and five kinds of free fatty acids were studied further through principal component analysis (PCA) . Results showed that the content of lactic acid, acetic acid and citric acid were the most, which accounted for more than 80% of the total organic acids. First four principal components could represent 85.276% sample information. And the principal components value reflected that origin, raw materials and technology of Chinese rice wine were significantly correlation with the content of organic acids in Chinese rice wine. It was also found that there was a wide variety of free fatty acids in 12 kinds of Chinese rice wine, and the difference in the total content of free fatty acids in Chinese rice wine was significant. The accumulative contribution rate of the first principal component and the second principal component reached 61.783% and 83.822% respectively, which could indicate the original information. The first principal component comprised C18∶0and C16∶0and the second component comprised C14∶0and C18∶1. These 4 kinds of compounds which affected the overall flavor of Chinese rice wine could be divided into three types :C18∶0and C16∶0, C14∶0, C18∶1.
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Keywords:
- Chinese rice wine /
- organic acids /
- free fatty acids /
- PCA
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[1] 王家林, 张颖, 于秦峰.黄酒风味物质成分的研究进展[J].酿酒科技, 2011 (8) :96-98. [2] 寿虹志, 凌志勇, 杨旭, 等.浅析黄酒麦曲中的微生物与黄酒风味的关系[J].中国酿造, 2007 (8) :55-57. [3] 李红蕾, 冯涛.不同酒龄和类型黄酒中主要味觉物质的测定[J].中国酿造, 2012, 31 (1) :172-175. [4] 叶芙蓉, 陈细丹, 倪夏红.高效液相色谱法测定黄酒中有机酸[J].酿酒, 2013, 40 (2) :80-85. [5] 冯爱军, 赵文红, 白卫东, 等.不同黄酒中有机酸的测定[J].中国酿造, 2010 (8) :144-146. [6] 吴春.古越龙山黄酒的特征风味物质及其成因的初步研究[D].无锡:江南大学, 2009. [7] Chen E, Jamieson A M, Vangheluwe G.Release of fatty-acids as a consequence of yeast autolysis[J].Brewers Digest, 1979, 54 (6) :24.
[8] 余宁华, 陆震鸣, 许伟, 等.基于主成分分析的中国发酵食醋有机酸含量差异性分析[J].食品与发酵工业, 2010, 36 (10) :144-148. [9] Mo X, Xu Y, Fan W.Characterization of Aroma Compounds in Chinese Rice Wine Qu by Solvent-Assisted Flavor Evaporation and Headspace Solid-Phase Microextraction[J].Journal of Agricultural and Food Chemistry, 2010, 58 (4) :2462-2469.
[10] 郭兆阳, 刘明, 钟其顶, 等.主成分分析OAV值评价白酒风味组分的研究[J].食品工业, 2011 (7) :79-83. [11] 岳田利, 彭帮柱, 袁亚宏, 等.基于主成分分析法的苹果酒香气质量评价模型的构建[J].农业工程学报, 2007, 23 (6) :223-227. [12] 丁晔, 刘敦华, 雷建刚, 等.不同处理羊羔肉挥发性风味物质的比较及主成分分析[J].食品与机械, 2013, 29 (3) :16-33. [13] 燕雯, 张正茂.不同麦胚含量馒头香气物质的主成分分析[J].中国食品学报, 2013, 13 (2) :211-215. [14] 吕旭聪, 黄志清, 黄若兰, 等.反相高效液相色谱法同时快速测定黄酒和葡萄酒中有机酸的含量[J].食品与发酵工业, 2010, 36 (6) :132-136. [15] 冯德明, 朱长俊, 王玉洁, 等.黄酒发酵过程中乳酸含量分析及变化规律的研究[J].中国酿造, 2009 (7) :158-160. [16] 李学坤, 张昆, 高振, 等.富马酸的合成及应用[J].现代化工, 2005 (S1) :81-83. [17] Cao Y, Xie G, Wu C, et al.A Study on Characteristic Flavor Compounds in Traditional Chinese Rice Wine-Guyue Longshan Rice Wine[J].Journal of the Institute of Brewing, 2010, 116 (2) :182-189.
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