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中国精品科技期刊2020
吴思邈,陈建明,王爱廉,等. 正渗透技术浓缩苹果汁过程中反向溶质扩散的研究[J]. 食品工业科技,2021,42(24):172−180. doi: 10.13386/j.issn1002-0306.2021040109.
引用本文: 吴思邈,陈建明,王爱廉,等. 正渗透技术浓缩苹果汁过程中反向溶质扩散的研究[J]. 食品工业科技,2021,42(24):172−180. doi: 10.13386/j.issn1002-0306.2021040109.
WU Simiao, CHEN Jianming, WANG Ailian, et al. Study of Reverse Solute Flux in Apple Juice Concentration by Forward Osmosis[J]. Science and Technology of Food Industry, 2021, 42(24): 172−180. (in Chinese with English abstract). doi: 10.13386/j.issn1002-0306.2021040109.
Citation: WU Simiao, CHEN Jianming, WANG Ailian, et al. Study of Reverse Solute Flux in Apple Juice Concentration by Forward Osmosis[J]. Science and Technology of Food Industry, 2021, 42(24): 172−180. (in Chinese with English abstract). doi: 10.13386/j.issn1002-0306.2021040109.

正渗透技术浓缩苹果汁过程中反向溶质扩散的研究

Study of Reverse Solute Flux in Apple Juice Concentration by Forward Osmosis

  • 摘要: 反向渗透扩散(RSF)是正渗透技术中的一大挑战,本实验立足于研究正渗透技术浓缩苹果汁性能以及功能性汲取液(乙酸钠、碳酸氢钠、柠檬酸钠溶液)的溶质扩散规律。首先,利用NaCl溶液为汲取液研究正渗透膜的基础特性,通过改变NaCl溶液浓度、进水流速以及膜操作模式,探究正渗透体系的水通量、反向溶质扩散及截留率,分析对去离子水和苹果汁的浓缩能力及溶质扩散规律;其次,对比不同功能性汲取液对苹果汁浓缩的效果和对RSF的影响,以期达到将RSF化弊为利的目的。结果表明,汲取液浓度和膜操作模式影响浓缩效率和RSF;采用压力延迟渗透(PRO)模式,苹果汁浓缩倍数和RSF均比正渗透(FO)模式高,PRO模式下,5 mol·L−1 NaCl汲取液RSF达87.34±6.32 g·m−2·h−1;不同种类功能性汲取液浓缩苹果汁的能力不同,汲水能力:碳酸氢钠>氯化钠>乙酸钠>柠檬酸钠。RSF:乙酸钠>碳酸氢钠>氯化钠>柠檬酸钠。2 mol·L−1柠檬酸钠汲取液的RSF为29.61±2.19 g·m−2·h−1,仅为同浓度NaCl汲取液的一半,与传统的NaCl汲取液相比,柠檬酸钠汲取液可有效控制RSF。

     

    Abstract: Reverse solute flux(RSF) is a big challenge of forward osmosis(FO) technology. This experiment was based on the study of the performance of apple juice concentration by FO technology and the solute diffusion law of functional draw solution(sodium acetate, sodium bicarbonate and sodiumcitrate). Firstly, the basic properties of FO system were studied, including water flux, RSF and rejection rate, by varying the concentration of NaCl draw solution, influent flow rate and membrane operation mode. The concentration ability of deionized water and apple juice and solute diffusion law were analyzed. To achieve the purpose of converting the RSF into advantages, the effect of different functional draw solutions on apple juice concentration and RSF were compared. The results showed that the concentration efficiency and RSF were affected by the concentration of draw solution and membrane operation mode. The membrane mode of pressure retarded osmosis(PRO) led to the higher RSF and the concentration degree of apple juice than the FO mode. In the PRO mode, the RSF reach to 87.34±6.32 g·m−2·h−1 with the NaCl draw solution concentration of 5 mol·L−1. The ability of concentrating apple juice by different concentration of functional draw solution was various. The order of water extraction capacity from high to low was sodium bicarbonate, sodium chloride, sodium acetate, sodium citrate and the order of RSF from high to low was sodium citrate, sodium bicarbonate, sodium chloride, sodium citrate. The RSF was 29.61±2.19 g·m−2·h−1 with 2 mol·L−1 NaCl draw solution, which was only half of the same concentration of NaCl draw solution. Compared with traditional NaCl draw solution, sodium citrate draw solution could effectively control RSF.

     

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