多孔硅酸镁的表征及其对糖汁中没食子酸的吸附
Characterization of Porous Magnesium Silicate and Adsorption of Gallic Acid in Sugar Juice
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摘要: 本文结合水热合成法和模板法,以氯化镁和硅胶球为前驱体制备多孔硅酸镁,用作糖汁清净剂。运用XRD、FTIR和SEM等多种表征手段对多孔硅酸镁进行了表征。以多孔硅酸镁作为吸附剂,以吸附量为指标,考察了吸附时间、初始浓度对多孔硅酸镁吸附没食子酸性能的影响。由表征结果可知,制备的硅酸镁为孔径为5和22 nm为主的介孔球形多孔硅酸镁;吸附实验结果表明,当没食子酸的初始浓度分别为25、50、75 mg/L时,多孔硅酸镁对没食子酸的吸附过程均可用准二级动力学方程描述(R2分别为0.9965、0.9941、0.9941),附等温曲线符合Freundlich模型(R2=0.9926)。方法可为制糖工艺吸附脱色提供理论研究基础。Abstract: In this paper the porous magnesium silicate was prepared by hydrothermal synthesis method and template method with magnesium chloride and silica gel as precursors. The magnesium silicate was characterized by XRD,FTIR and SEM analysis. Porous magnesium silicate was used as adsorbent and adsorption as an index,the effects of adsorption time and initial concentration on the adsorption of gallic acid by porous magnesium silicate were investigated. The characterization results showed the mesoporous spherical porous magnesium silicates with a pore diameter of 5 nm and 22 nm was obtained. The adsorption results showed that the pseudo-second-order equation provided the best correlation to the experimental data(R2 was 0.9965、0.9941、0.9941)when the initial gallic acid concentration were 25,50,75 mg/L,and the adsorption isotherm could be described by Freundlich isothermal adsorption equation(R2=0.9926). The method can provide a theoretical research basis for the adsorption and decolorization of sugar industry.