Determination of Inorganic Arsenic in Mineral Water and Tea Beverages by Pipette-tip Solid Phase Extraction Combined with Hydride Generation-Atomic Fluorescence Spectroscopy

YANG Dayu; ZHAO Deyi; HUANG Rui; ZOU Ting; DAI Xinxian; LI Si; YAN Zhiming

doi:10.13386/j.issn1002-0306.2022030137

Volume 44 Issue 1

Dec. 2022

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Science and Technology of Food Industry > 2023 > 44(1): 292-298. > DOI: 10.13386/j.issn1002-0306.2022030137

YANG Dayu, ZHAO Deyi, HUANG Rui, et al. Determination of Inorganic Arsenic in Mineral Water and Tea Beverages by Pipette-tip Solid Phase Extraction Combined with Hydride Generation-Atomic Fluorescence Spectroscopy[J]. Science and Technology of Food Industry, 2023, 44(1): 292−298. (in Chinese with English abstract). doi: 10.13386/j.issn1002-0306.2022030137.

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Determination of Inorganic Arsenic in Mineral Water and Tea Beverages by Pipette-tip Solid Phase Extraction Combined with Hydride Generation-Atomic Fluorescence Spectroscopy

College of Food Science, Fujian Agriculture and Forestry University, Fuzhou 350002, China

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Received Date: March 10, 2022
Available Online: November 05, 2022

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Abstract

Abstract

Objective: Establishing a simple and convenient method for the analysis of inorganic arsenic in mineral water and tea beverages. Methods: Amino-functioned polyacrylonitrile nanofibers (NH₂-PAN nanofibers) was fabricated and used as adsorbent for pipette-tip solid-phase extraction (PT-SPE) of inorganic arsenic in mineral water and tea beverages followed by hydride generation-atomic fluorescence spectrometry (HG-AFS) analysis. Results: The optimal extraction conditions of pipette-tip solid phase extraction were that the pH of the sample solution was 8, the adsorbent was 12 mg NH₂-PAN nanofibers, and the elution solution was 5 mL HCl with a concentration of 0.01 mol/L. Under the optimum conditions, the established method showed good linearity in the range of 0.0235~60 μg/L with correlation coefficient greater than 0.994 and a precision of less than 6%. The spiked recoveries of inorganic arsenic were above 85% for both mineral water and tea beverages at two levels of spiked concentrations. Conclusion: The established NH₂-PAN nanofibers based PT-SPE/HG-AFS method is simple, accurate and expected to provide a prospective solution for the detection of inorganic arsenic.

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