Preparation Process Optimization and Property Analysis of Nano-cellulose-Starch Film Based on Corn Stalk

ZHANG Aiwu; SONG Ting; ZHANG Liyuan; YU Runzhong

doi:10.13386/j.issn1002-0306.2022010187

Volume 43 Issue 11

May 2022

Turn off MathJax

Article Contents

Abstract

References

Science and Technology of Food Industry > 2022 > 43(11): 252-259. > DOI: 10.13386/j.issn1002-0306.2022010187

ZHANG Aiwu, SONG Ting, ZHANG Liyuan, et al. Preparation Process Optimization and Property Analysis of Nano-cellulose-Starch Film Based on Corn Stalk[J]. Science and Technology of Food Industry, 2022, 43(11): 252−259. (in Chinese with English abstract). doi: 10.13386/j.issn1002-0306.2022010187.

Citation:

PDF (2822 KB)

Preparation Process Optimization and Property Analysis of Nano-cellulose-Starch Film Based on Corn Stalk

1.
College of Food Science, Heilongjiang Bayi Agricultural University, Daqing 163319, China
2.
College of Information and Electrical Engineering, Heilongjiang Bayi Agricultural University, Daqing 163319, China

More Information

Received Date: January 20, 2022
Available Online: May 05, 2022

Graphical Abstract

Abstract

Abstract

In this work, corn stalk nano-cellulose and corn stalk starch were used as film-forming substrates to prepare corn stalk nano-cellulose-starch film by blending-flow casting method. The properties of nano-cellulose-starch film were determined on the basis of single factor and orthogonal test. The effects of each material of film-forming on mechanical properties, moisture permeability, light transmittance, water solubility and oxygen permeability of nano-cellulose-starch film were investigated. Finally, the optimal formula combination of film-forming liquid was determined as follows: The starch was 10.0% (W/V), nano-cellulose was 5% (W/V), sodium carboxymethyl cellulose was 1.6% (W/V) and glycerol was 2.3% (V/V). Under optimal conditions, the nano-cellulose-starch film has the best comprehensive effect. The performance indexes were measured, and the membrane thickness was (0.063±0.050) mm, tensile strength was 14.92 MPa, elongation at break was 64.75%, moisture permeability coefficient was 2.19×10⁻¹² g·m/m²·s·Pa, light transmittance was 87.60%, hydrolysis time was 97.00 s, oxygen permeability was 2.75×10⁻¹⁴ cm³·cm/cm²·s·Pa.
- corn straw nano-cellulose (CSNC),
- corn straw starch (CSS),
- CSNC-CSS film,
- mechanical properties,
- moisture permeability coefficient

FullText(HTML)

References (29)

References

[1]	徐丽萍, 姜喆, 葛英亮, 等. 利用Illumina高通量测序技术筛选低温降解玉米秸秆真菌[J]. 食品工业科技,2020,41(20):99−103. [XU L P, JIANG Z, GE Y L, et al. Application of Illumina high-throughput sequencing technology to screening maize straw degradation fungi[J]. Science and Technology of Food Industry,2020,41(20):99−103.
[2]	谷芳, 马嘉欣, 车春波. 玉米秸秆制备羧甲基纤维素的研究及结构表征[J/OL]. 中国粮油学报, 1−10 [2022-03-19]. https://kns.cnki.net/kcms/detail/11.2864.TS.20211229.1943.028.html GU F, MA J X, CHE C B. Preparation and characterization of carboxymethyl cellulose from corn straw[J/OL]. Chinese Journal of Grain and Oil, 1−10 [2022-03-19]. https://kns.cnki.net/kcms/detail/11.2864.TS.20211229.1943.028.html
[3]	王聪, 刘玲玲, 孔德巍, 等. 黑龙江省玉米秸秆肥料化利用技术模式浅析[J]. 农业科技通讯,2021(2):16−18. [WANG C, LIU L L, KONG D W, et al. Analysis on technical model of maize straw fertilizer utilization in Heilongjiang Province[J]. Journal of Agricultural Science and Technology,2021(2):16−18. doi: 10.3969/j.issn.1000-6400.2021.02.005
[4]	聂德超, 张卓, 赵琛, 等. 蒸汽爆破技术在玉米秸秆饲料化利用中的研究进展[J]. 中国畜牧兽医,2021,48(12):4488−4496. [NIE D C, ZHANG Z, ZHAO C, et al. Research progress of steam blasting technology in fodder utilization of corn straw[J]. China Animal Husbandry and Veterinary Medicine,2021,48(12):4488−4496.
[5]	ÓSCAR R L, ISABEL R, SARA I, et al. Effect of whey protein purity and glycerol content upon physical properties of edible films manufactured therefrom[J]. Food Hydrocolloids,2013,30(1):110−122. doi: 10.1016/j.foodhyd.2012.05.001
[6]	张丽恒, 宋亭, 方鑫碧, 等. 玉米秸秆纤维素基保鲜膜制备条件优化[J]. 食品工业,2021,42(12):206−209. [ZHANG L H, SONG T, FANG X B, et al. Optimization of preparation conditions of cellulose-based plastic film from corn straw[J]. The Food Industry,2021,42(12):206−209.
[7]	WANG W B, LIU Q R, QI J, et al. Oregano essential oil loaded soybean polysaccharide films: Effect of pickering type immobilization on physical and antimicrobial properties[J]. Food Hydrocolloids,2019,87:165−172. doi: 10.1016/j.foodhyd.2018.08.011
[8]	BEMARDO C N, KLING I C S, FERRERIA W H, et al. Starch films containing starch nanoparticles as produced in a single step green route[J]. Industrial Crops & Products,2022:177.
[9]	FEMANDA I D, et al. Nanocrystalline cellulose extracted from pine wood and corncob[J]. Carbohydrate Polymers,2017,157:1577−1585. doi: 10.1016/j.carbpol.2016.11.036
[10]	胡建雪. 纳米纤维素纤维的制备及其在食品中的应用[D]. 无锡: 江南大学, 2015. HU J X. Preparation of nanocellulose fiber and its application in food[D]. Wuxi: Jiangnan University, 2015.
[11]	袁本振. 蒸汽闪爆预处理制备纳米纤维及其结构与性能研究[D]. 青岛: 青岛大学, 2014. YUAN B Z. Preparation of nanofibers by steam flash detonation pretreatment and its structure and properties[D]. Qingdao: Qingdao University, 2014.
[12]	涂晓丽. 柚皮纳米微晶纤维制备及对羧甲基淀粉膜流变的影响[J]. 农业机械学报,2020,51(S2):499−506. [TU X L. Preparation of pomelo peel nanocrystalline fiber and its effect on rheology of carboxymethyl starch film[J]. Transactions of the Chinese Society for Agricultural Machinery,2020,51(S2):499−506. doi: 10.6041/j.issn.1000-1298.2020.S2.062
[13]	SILVA J B A. Cassava starch-based films plasticized with sucrose and inverted sugar and reinforced with cellulose nanocrystals[J]. Journal of Food Science,2012,77(6):14−19.
[14]	宋亭, 张丽媛, 于润众. 玉米秸秆纳米纤维素制备的工艺优化[J]. 现代食品科技,2022,38(1):264−270. [SONG T, ZHANG L Y, YU R Z. Preparation technology optimization of corn straw nanocellulose[J]. Modern Food Science and Technology,2022,38(1):264−270.
[15]	孙海涛. 玉米秸秆纤维素及玉米磷酸酯淀粉基可食膜的研究[D]. 长春: 吉林大学, 2017. SUN H T. Study on corn straw cellulose and corn phosphate starch based edible membrane[D]. Changchun: Jilin University, 2017.
[16]	中国国家标准化管理委员会. GB/T 1040.3-2006. 薄塑和薄片的拉伸性能测试标准方法[S]. 北京: 中国标准出版社, 2006. Standardization Administration of China. GB/T 104.3-2006. Standard method for testing tensile properties of thin plastics and sheets[S]. Beijing: Standards Press of China, 2006.
[17]	中国国家标准化管理委员会. GB/T 16928-1997. 包装材料试验方法透湿率[S]. 北京: 中国标准出版社, 1997. Standardization Administration of China. GB/T 16928-1997. Packaging materials test method moisture permeability[S]. Beijing: Standards Press of China, 1997.
[18]	中国国家标准化管理委员会. GB/T 2410-80-2008. 透明塑料透光率和雾度的测定[S]. 北京: 中国标准出版社, 2008. Standardization Administration of China. GB/T 2410-80-2008. Transparent plastics-determination of light transmittance and fog[S]. Beijing: Standards Press of China, 2008.
[19]	王锋棚. 可食性复合膜的制备及在包装中的应用[D]. 天津: 天津科技大学, 2014. WANG F P. Preparation of edible composite film and its application in packaging[D]. Tianjin: Tianjin University of Science and Technology, 2014.
[20]	中国国家标准化管理委员会. GB/T1038-2000. 塑料薄膜和薄片气体透过性试验方法[S]. 北京: 中国标准出版社, 2000. Standardization Administration of China. GB/T1038-2000. Test method for gas permeability of plastic film and sheet[S]. Beijing: Standards Press of China, 2000.
[21]	徐平, 郦丹妮, 余文怡, 等. 酚酸/淀粉复合膜的制备及抑菌性能研究[J]. 现代食品,2021(19):198−203. [XU P, LI D N, YU W Y, et al. Preparation and antibacterial properties of phenolic acid/starch composite membrane[J]. Modern Food,2021(19):198−203.
[22]	PMDF A , LBDV A , MESF B, et al. Nopal cladode as a novel reinforcing and antioxidant agent for starch-based films: A comparison with lignin and propolis extract[J]. International Journal of Biological Macromolecules,2021,183:614−626. doi: 10.1016/j.ijbiomac.2021.04.143
[23]	王思. 甘草渣纤维素基抗菌材料的制备及其性能研究[D]. 天津: 天津科技大学, 2019. WANG S. Preparation and properties of cellulose based antibacterial materials from licorice residue[D]. Tianjin: Tianjin University of Science and Technology, 2019.
[24]	汪友明, 谢梦, 鲍杰飞, 等. 基于响应面法的马铃薯淀粉膜制备工艺优化[J]. 徐州工程学院学报(自然科学版),2021,36(2):22−26. [WANG Y M, XIE M, BAO J F, et al. Optimization of potato starch film preparation process based on response surface method[J]. Journal of Xuzhou Institute of Technology (Natural Science Edition),2021,36(2):22−26.
[25]	程龙. 壳聚糖/纳米TiO₂/玉米淀粉可食膜的制备及性能研究[D]. 兰州: 兰州交通大学, 2021.50/5000. CHENG L. Preparation and properties of chitosan/nano-TiO₂/corn starch edible film[D]. Lanzhou: Lanzhou Jiaotong University, 2021.50/5000.
[26]	贾雪. 玉米淀粉基薄膜材料的制备及性质研究[D]. 无锡: 江南大学, 2018. JIA X. Preparation and properties of corn starch-based film materials[D]. Wuxi: Jiangnan University, 2018.
[27]	HARLEEN G, MANJU N. Synthesis, characterization, and utilization of potato starch nanoparticles as a filler in nanocomposite films[J]. International Journal of Biological Macromolecules,2021,186:155−162. doi: 10.1016/j.ijbiomac.2021.07.005
[28]	RODRIGUES F, SANTOS S, LOPES M, et al. Antioxidant films and coatings based on starch and phenolics from Spondias purpurea L.[J]. International Journal of Biological Macromolecules,2021,182:354−365. doi: 10.1016/j.ijbiomac.2021.04.012
[29]	张静, 马瑛. 多指标综合平衡法-正交试验优化九蒸九晒地黄炮制工艺[J]. 中国药房,2016,27(7):962−965. [ZHANG J, MA Y. Optimization of processing technology of radix rehmanniae radix by multi-index comprehensive balance method and orthogonal experiment[J]. China Pharmacy,2016,27(7):962−965. doi: 10.6039/j.issn.1001-0408.2016.07.30

Supplements (0)

Cited By

Cited by

Periodical cited type(6)

1.	吴思邈，蒋浩源，安莹，张丽冕，李彭. L-赖氨酸功能化纤维素对模拟苹果汁中铅的吸附特性研究. 食品工业科技. 2024(08): 97-109 . 本站查看
2.	张琳，马悦，张悦，陆辉杰，陈子琨，刘宏生. 科教融汇及思政育人新路径——食品包装技术课程创新实验设计. 农业工程. 2024(06): 133-137 .
3.	唐蓉萍，李秀壮，朱一剑，吴贝贝，李树龙. 玉米秸秆高值化利用研究进展. 南方农业. 2024(21): 143-146 .
4.	朱颍，李力，孙冰华，马森. 淀粉可食性膜性能的研究进展. 粮食科技与经济. 2024(06): 94-102 .
5.	曾仪雯，周恩弛，黄高瓴，冯静秋，李丹，张春红. 可食性膜在食品保鲜中的应用现状及研究进展. 保鲜与加工. 2023(04): 62-67 .
6.	任晚霞，宋亭，张丽媛. 纳米纤维素-淀粉膜对草莓保鲜效果的影响. 中国食品添加剂. 2023(11): 6-11 .