PENG Qiao, ZHAO Sijiu, FAN Guozhi, et al. Extraction, Acetylation Modification and Structure Characterization of Hemicelluloses from Corncob[J]. Science and Technology of Food Industry, 2022, 43(11): 45−51. (in Chinese with English abstract). doi: 10.13386/j.issn1002-0306.2021080087.
Citation: PENG Qiao, ZHAO Sijiu, FAN Guozhi, et al. Extraction, Acetylation Modification and Structure Characterization of Hemicelluloses from Corncob[J]. Science and Technology of Food Industry, 2022, 43(11): 45−51. (in Chinese with English abstract). doi: 10.13386/j.issn1002-0306.2021080087.

Extraction, Acetylation Modification and Structure Characterization of Hemicelluloses from Corncob

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  • Received Date: August 08, 2021
  • Available Online: March 29, 2022
  • Hemicellulose was extracted from corncob and further modified by acetylation. Ultrasonic-assisted alkali method was employed for the extraction, in which sulfuric acid (H2SO4) and elemental iodine (I2) were used as co-catalyst for the acetylation of hemicellulose, respectively. Corncob hemicellulose and its acetylated products were characterized by infrared spectroscopy (IR), thermogravimetric analysis (TGA) and nuclear magnetic resonance (NMR). The yield and extraction rate of corncob hemicellulose were 33.7% and 81.0%, and the hemicellulose content reached 85.3wt%. The acetylation of corncob hemicellulose gave 84.6% yield and 1.27 degree of substitution (DS), respectively. The separation of hemicellulose from corncob using alkali method was effectively shortened by ultrasonic assistance, and the yield and extraction rate of corncob hemicellulose were improved. Concentrated sulfuric acid (H2SO4) and elemental iodine (I2) were effective co-catalyst for the acetylation of corncob hemicellulose. The results of IR and NMR showed that hemicelluloses were acetylated successfully, and TGA revealed that the thermal stability of the acetylated hemicellulose was improved. Moreover, the DS value of the acetylated product was moderate. Therefore, the acetylated product is expected to be used to prepare biodegradable materials for food packaging.
  • [1]
    HOSSEINI S E, WAHID M A. Hydrogen production from renewable and sustainable energy resources: Promising green energy carrier for clean development[J]. Renewable and Sustainable Energy Reviews,2016,57(5):850−866.
    [2]
    刘明华. 生物质的开发与利用[M]. 北京: 化学工业出版社, 2012.

    LIU Minghua. Development and utilization of biomass[M]. Bejing: Chemical Industry Press, 2012.
    [3]
    CHEN H, LIU J, CHANG X, et al. A review on the pretreatment of lignocellulose for high-value chemicals[J]. Fuel Processing Technology,2017,160:196−206. doi: 10.1016/j.fuproc.2016.12.007
    [4]
    AREVALO-GALLEGOS A, AHMAD Z, ASGHER M, et al. Lignocellulose: A sustainable material to produce value-added products with a zero waste approach-A review[J]. International Journal of Biological Macromolecules,2017,99(6):308−318.
    [5]
    LOPEZ S D, TISSOT M, DELMAS M. Integrated cereal straw valorization by an alkaline pre-extraction of hemicellulose prior to soda-anthraquinone pulping. Case study of barley straw[J]. Biomass & Bioenergy,1996,10(4):201−211.
    [6]
    PENG P, PENG F, BIAN J, et al. Isolation and structural characterization of hemicellulose from the bamboo species Phyllostachys incarnata Wen[J]. Carbohydrate Polymers,2011,86(2):883. doi: 10.1016/j.carbpol.2011.05.038
    [7]
    罗兰萍, 李翔. 玉米芯半纤维素的制备及表征[J]. 粮食与油脂,2020,33(6):88−91. [LUO Lanping, LI Xiang. Preparation and characterization of corncob hemicellulose[J]. Cereals & Oils,2020,33(6):88−91. doi: 10.3969/j.issn.1008-9578.2020.06.024
    [8]
    SUN R C, TOMKINSON J. Characterization of hemicelluloses obtained by classical and ultrasonically assisted extractions from wheat straw[J]. Carbohydrate Polymers,2002,50(3):263−271. doi: 10.1016/S0144-8617(02)00037-1
    [9]
    XIE Y, GUO X, MA Z. Efficient extraction and structural characterization of hemicellulose from sugarcane bagasse pith[J]. Polymers,2020,12(3):608−620. doi: 10.3390/polym12030608
    [10]
    SUN R C, FANG J M, TOMKINSON J, et al. Acetylation of wheat straw hemicelluloses in N, N-dimethylacetamide/LiCl solvent system[J]. Industrial Crops & Products,1999,10(3):209−218.
    [11]
    XU F, JIANG J X, SUN R C, et al. Rapid esterification of wheat straw hemicelluloses induced by microwave irradiation[J]. Carbohydrate Polymers,2008,73(4):612−620. doi: 10.1016/j.carbpol.2008.01.002
    [12]
    FAN G, WANG M, LIAO C, et al. Islation of cellulose from rice straw and its conversion into cellulose acetate catalyzed by phosphotungstic acid[J]. Carbohydrate Polymers,2013,94(1):71−76. doi: 10.1016/j.carbpol.2013.01.073
    [13]
    李雅丽, 刘娟, 高锦红. 农作物秸秆的热值及纤维素含量分析[J]. 化学与生物工程,2016,33(9):67−70. [LI Yali, LIU Juan, GAO Jinhong. Analysis of calorific value and cellulose content of crop straw[J]. Chemistry & Bioengineering,2016,33(9):67−70. doi: 10.3969/j.issn.1672-5425.2016.09.016
    [14]
    WANG J Z, WANG Y X, FENG L I, et al. Determination of cellulose, hemicellulose and lignin in corn stalk[J]. Shandong Food Ferment,2010,3:44−47.
    [15]
    纪楷滨. 烟梗木质素的含量测定方法研究及结构表征[D]. 广州: 华南理工大学, 2013.

    JI Kaibin. Study on content determination method and structural characterization of lignin in tobacco stem[D]. Guangzhou: South China University of Technology, 2013.
    [16]
    RAN B, BERGLUND J, VILAPLANA F, et al. The degree of acetylation affects the microbial degradability of mannans[J]. Polymer Degradation and Stability,2016,133(nov.):36−46.
    [17]
    张冰. 不同竹龄慈竹半纤维素和LCC的结构表征[D]. 北京: 北京林业大学, 2016.

    ZHANG Bing. Structural characterization of hemicellulose and LCC of neosinocalamus affinis at different ages[D]. Beijing: Beijing Forestry University, 2016.
    [18]
    REN J L, SUN R C, LIU C F, et al. Acetylation of wheat straw hemicelluloses in ionic liquid using iodine as a catalyst[J]. Carbohydrate Polymers,2007,70(4):406−414. doi: 10.1016/j.carbpol.2007.04.022
    [19]
    AYOUB A, VENDITTI R A, PAWLAK J J, et al. Development of an acetylation reaction of switchgrass hemicellulose in ionic liquid without catalyst[J]. Industrial Crops & Products,2013,44:306−314.
    [20]
    LIU R, DU J, ZHANG Z, et al. Preparation of polyacrylic acid-grafted-acryloyl/hemicellulose (PAA-g-AH) hybrid films with high oxygen barrier performance[J]. Carbohydrate Polymers,2019,205(3):83−88.
    [21]
    HUANG Y, WANG Z, WANG L, et al. Analysis of lignin aromatic structure in wood fractions based on IR spectroscopy[J]. Journal of Wood Chemistry and Technology,2016,36(5):377−382. doi: 10.1080/02773813.2016.1179325
    [22]
    El-SAKHAWY M, KAMEL S, SALAMA A, et al. Preparation and infrared study of cellulose based amphiphilic materials[J]. Cellulose Chemistry and Technology,2018,52(3-4):193−200.
    [23]
    李蕊, 杨桂花, 吕高金, 等. 玉米秸秆半纤维素的逐级分离及其结构表征[J]. 中国造纸学报,2017,32(3):1−6. [LI Rui, YANG Guihua, LÜ Gaojin, et al. Separation and characterization of hemicelluloses of corn stalks[J]. Transactions of China Pulp and Paper,2017,32(3):1−6. doi: 10.11981/j.issn.1000-6842.2017.03.1
    [24]
    LIAN H F, LING Y M, YA Y L, et al. Comparative study of water-soluble and alkali-soluble hemicelluloses extracted by hydrothermal pretreatment[J]. Paper & Biomaterials,2017,2(1):1−9.
    [25]
    ABURTO J, THIEBAUD S, ALRIC I, et al. Properties of octanoated starch and its blends with polyethylene[J]. Carbohydrate Polymers,1997,34(1):101−112.
    [26]
    于庆雪. 玉米芯中半纤维素的水热法预提取及农林生物质半纤维素制备膜材料的研究[D]. 济南: 齐鲁工业大学, 2018.

    YU Qingxue. Corncob hemicelluloses with hot water extraction method and production of films prepared from agricultural and forestry biomass hemicelluloses[D]. Jinan: Qilu University of Technology, 2018.
    [27]
    FANG J M, SUN R C, TOMKINSON J, et al. Acetylation of wheat straw hemicellulose B in a new non-aqueous swelling system[J]. Carbohydrate Polymers,2000,41(4):379−387. doi: 10.1016/S0144-8617(99)00102-2
    [28]
    黄曹兴, 何娟, 闵斗勇, 等. 毛竹竹青和竹黄半纤维素的提取与结构表征[J]. 林产化学与工业,2015,35(5):29−36. [HUANG Caoxing, HE Juan, MIN Douyong, et al. Isolation and characterization of hemicellulose from moso bamboo green and bamboo yellow[J]. Chemistry and Industry of Forest Products,2015,35(5):29−36. doi: 10.3969/j.issn.0253-2417.2015.05.006
    [29]
    李赫龙. 作物秸秆木质素和半纤维素的分离纯化及结构表征[D]. 杨凌: 西北农林科技大学, 2016.

    LI Helong. Isolation and structure characterization of lignin and hemicellulose from crop straw[D]. Yangling: Northwest A&F University, 2016.
    [30]
    TELEMAN A, TENKANEN M, JACOBS A, et al. Characterization of O-acetyl-(4-O-methylglucurono) xylan isolated from birch and beech[J]. Carbohydrate Research,2002,337(4):373−377. doi: 10.1016/S0008-6215(01)00327-5
    [31]
    GABRIELII I, GATENHOLM P, GLASSER W G, et al. Separation characterization and hydrogel-formation of hemicellulose from aspen wood[J]. Carbohydrate Polymers,2001,43(4):367−374.
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