Preparation and Adsorption Properties of Chitosan/Active Clay Composite as Sugar Juice Decolorization Agent

HUANG Chengdu; AI Shuo; LIU Chunyou; REN Xian’e; ZHANG Kunming; HUANG Yongchun

doi:10.13386/j.issn1002-0306.2021070294

Volume 43 Issue 8

Apr. 2022

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Science and Technology of Food Industry > 2022 > 43(8): 76-84. > DOI: 10.13386/j.issn1002-0306.2021070294

HUANG Chengdu, AI Shuo, LIU Chunyou, et al. Preparation and Adsorption Properties of Chitosan/Active Clay Composite as Sugar Juice Decolorization Agent[J]. Science and Technology of Food Industry, 2022, 43(8): 76−84. (in Chinese with English abstract). doi: 10.13386/j.issn1002-0306.2021070294.

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Preparation and Adsorption Properties of Chitosan/Active Clay Composite as Sugar Juice Decolorization Agent

HUANG Chengdu^{1, 2,},
AI Shuo^{1, 2},
LIU Chunyou^{1, 2},
REN Xian’e^{1, 2},
ZHANG Kunming^{1, 2},
HUANG Yongchun^{1, 2, ,}

1.
Guangxi Key Laboratory of Green Processing of Sugar Resources (Guangxi University of Science and Technology), Liuzhou 545006, China
2.
Province and Ministry Co-sponsored Collaborative Innovation Center of Sugarcane and Sugar Industry, Nanning 530004, China

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Received Date: July 25, 2021
Available Online: February 13, 2022

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Abstract

Abstract

Chitosan/activated clay composite was prepared with chitosan solution and activated clay. With the decolorization ratio of sugar juice as an index, the effects of reaction temperature, reaction time, chitosan dosage and molecular weight on the preparation of chitosan/activated clay composite were investigated. The optimum conditions were obtained as follows: temperature 60 ℃, reaction time 7 h, chitosan dosage 2.0 g and molecular weight 2,000,000. The decolorization rate of the composite was up to 96.2%, which was significantly better than 56.7% of activated clay and 42.2% of chitosan. The decolorization rate of the structure of the composite was characterized by scanning electron microscopy, infrared spectroscopy, X-ray diffraction and thermogravimetric analysis. The results showed that chitosan was evenly distributed on the surface of activated clay, forming a more stable composite structure and maintaining the porous structure of activated clay. The thermal stability of the composite was higher than that of chitosan. The adsorption experiment of gallic acid in sugar juice showed that the adsorption kinetics of the composite conformed to the quasi second order kinetic model, the adsorption rate was controlled by the diffusion process outside the particles, and the adsorption process conformed to the Langmuir isothermal adsorption model, which was monolayer adsorption.

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References

[1]	HUGOT E. Handbook of cane sugar engineering[M]. Elsevier Publishing Company, 1960.
[2]	陈维均, 许斯欣. 甘蔗制糖原理与技术—蔗汁清净[M]. 北京: 中国轻工业出版社, 2001. CHEN Weijun, XU Sixin. Principle and technology of sugarcane sugar production-cane juice clean[M]. Beijing: China Light Industry Press, 2001.
[3]	THAI C C D, DOHERTY W O S. Characterisation of sugarcane juice particles that influence the clarification process[J]. International Sugar Journal,2012,114(1366):719−724.
[4]	崔越, 李利军, 黄彩幸, 等. 糖汁亚硫酸法絮凝澄清过程中的Zeta电位[J]. 食品科学,2014,35(9):30−33. [CUI Yue, LI Lijun, HUANG Caixing, et al. Changes in zeta potential of sugar liquor during flocculation and clarification by culfurous acid method[J]. Food Science,2014,35(9):30−33. doi: 10.7506/spkx1002-6630-201409007
[5]	SARANIN A. Technology of phosflotation of sugar melt[J]. Sugar Tech Rev,1972,2:1−72.
[6]	韦宇, 李岩, 卢家炯, 等. 甘蔗糖厂降低亚硫酸法产品残留量的初步研究[J]. 现代食品科技,2010,26(2):180−183. [WEI Yu, LI Yan, LU Jiajiong, et al. Primary study of residual sulfur content of sulfitation sugar mill product[J]. Modern Food Science & Technology,2010,26(2):180−183.
[7]	RODRIGUES R, SPERANDIO L C C, ANDRADE C M G. Investigation of color and turbidity in the clarification of sugarcane juice by ozone[J]. J Food Process Eng,2018,41:e12661. doi: 10.1111/jfpe.12661
[8]	EGGLESTON G, LEGENDRE D, PONTIF K, et al. Improved control of sucrose losses and clarified juice turbidity with lime saccharate in hot lime clarification of sugarcane juice and other comparisons with milk of lime[J]. Journal of Food Processing and Preservation,2014,38(1):311−325. doi: 10.1111/j.1745-4549.2012.00779.x
[9]	SONG X, CHAI Z, ZHU Y, et al. Preparation and characterization of magnetic chitosan-modified diatomite for the removal of gallic acid and caffeic acid from sugar solution[J]. Carbohydrate Polymers,2019,219:316−327. doi: 10.1016/j.carbpol.2019.04.043
[10]	曾德永, 张立钢, 赵玉红. 澄清剂对蓝靛果果汁活性成分和特性的影响[J]. 食品科学,2018,39(4):43−48. [ZENG Deyong, ZHANG Ligang, ZHAO Yuhong. Effects of clarifying agents on active Ingredients and characteristics of Haskap (Lonicera caerulea L.) juice[J]. Food Science,2018,39(4):43−48. doi: 10.7506/spkx1002-6630-201804008
[11]	谢捷, 刘小景, 朱兴一, 等. 壳聚糖澄清甜叶菊水提液及其澄清机理探讨[J]. 食品科学,2011,32(20):1−6. [XIE Jie, LIU Xiaojing, ZHU Xingyi, et al. Application of chitosan flocculation method in clarification of water extract from stevia rebaudiana bertoni leaves and flocculation mechanism analysis[J]. Food Science,2011,32(20):1−6.
[12]	OZGE TASTAN, TANER BAYSAL. Clarification of pomegranate juice with chitosan: Changes on quality characteristics during storage[J]. Food Chemistry,2015,180:211−218. doi: 10.1016/j.foodchem.2015.02.053
[13]	席超, 张赞, 闫振华, 等. 沸石负载壳聚糖对高酸苹果发酵酒的澄清工艺[J]. 食品科学,2010,31(22):164−169. [XI Chao, ZHANG Zan, YAN Zhenhua, et al. Effect of zeolite-loaded chitosan on the clarification of apple cider[J]. Food Chemistry,2010,31(22):164−169.
[14]	何惠欢, 谢志荣, 刘继栋, 等. 羧甲基壳聚糖糖用澄清剂的制备及结构表征[J]. 食品工业科技,2015,36(6):117−121. [HE Huihuan, XIE Zhirong, LIU Jidong, et al. Preparation and structural characterization of carboxymethyl chitosan as a sugar cane juice clarifying agent[J]. Science and Technology of Food Industry,2015,36(6):117−121.
[15]	任勤, 张佳欣, 雷财玉, 等. 壳聚糖及其衍生物在糖汁澄清过程中的研究进展[J]. 中国调味品,2017,42(4):159−162. [REN Qin, ZHANG Jiaxin, LEI Caiyu, et al. Research progress of chitosan and its derivative in the process of sugar juice clarification[J]. China Condiment,2017,42(4):159−162. doi: 10.3969/j.issn.1000-9973.2017.04.036
[16]	冯淑娟, 李利军, 夏兆博, 等. 活性炭负载壳聚糖的制备及其对糖汁清净性能研究[J]. 食品工业科技,2016,37(15):256−259. [FENG Shujuan, LI Lijun, XIA Zhaobo, et al. Preparation of activated carbon attached chitosan and its clarification performance for remelt syrup of brown granulated sugar[J]. Science and Technology of Food Industry,2016,37(15):256−259.
[17]	张旭, 王玉琦, 张鲁, 等. 响应面法脱除玉米油中色素及蜡质工艺优化[J]. 食品科学,2017,38(6):248−252. [ZHANG xu, WANG Yuqi, ZHANG Lu, et al. Optimization of processing conditions for removal of pigment and wax from com oil using response surface methodology[J]. Food Science,2017,38(6):248−252. doi: 10.7506/spkx1002-6630-201706039
[18]	宋恭帅, 彭茜, 张蒙娜, 等. 5种脱色剂对粗鱼油挥发性风味物质及脂肪酸组成的影响[J]. 食品科学,2018,39(18):35−41. [SONG Gongshuai, PENG Xi, ZHANG Mengna, et al. Volatile flavor compounds and fatty acid proﬁles of crude fish oil decolorized with five decoloring agent[J]. Food Chemistry,2018,39(18):35−41. doi: 10.7506/spkx1002-6630-201818006
[19]	S M SILVA, K A SAMPAIO, R CERIANI, et al. Adsorption of carotenes and phosphorus from palm oil onto acid activated bleaching earth: Equilibrium, kinetics and thermodynamics[J]. Journal of Food Engineering,2013,118(4):341−349. doi: 10.1016/j.jfoodeng.2013.04.026
[20]	JIMOH K ADEWOLE, TAYE S KAZEEM, TAJUDEEN A OYEHAN. Tuning the chemistry of seawater with activated clay: An application in smart water enrichment for enhanced oil recovery[J]. Journal of Petroleum Exploration and Production Technology,2020,10:1−12.
[21]	廖耀文, 黄承都, 黄永春. 过氧化氢-维生素C体系协同壳聚糖/蒙脱土复合物对甘蔗汁的脱色研究[J]. 甘蔗糖业,2020,49(4):59−67. [LIAO Yaowen, HUANG Chengdu, HUANG Yongchun. Decolorization of sugarcane juice by hydrogen peroxide-vitamin C system with chitosan/montmorillonite composite[J]. Sugarcane and Canesugar,2020,49(4):59−67.
[22]	高晓薇, 韦藤幼, 潘远凤, 等. 活性白土的化学改性及其作用机理研究[J]. 广西大学学报(自然科学版),2010,35(3):410−414,418. [GAO Xiaowei, WEI Tengyou, PAN Yuanfeng, et al. Study on chemical modification of activated clay and its mechanism[J]. Journal of Guangxi University(Nat Sci Ed),2010,35(3):410−414,418.
[23]	潘庆才, 徐启杰, 张昕, 等. 活性白土/壳聚糖复合物的制备及其吸附性能研究[J]. 化工新型材料,2016,44(4):161−163. [PAN Qingcai, XU Qijie, ZHANG Xin, et al. Study on the preparation and absorption property of activated clay/chitosan composite[J]. New Chemical Materials,2016,44(4):161−163.
[24]	徐启杰, 赵梦溪, 潘庆才, 等. 活性白土/壳聚糖复合物对多成分污染物的吸附行为研究[J]. 应用化工,2016,45(10):1908−1912. [XU Qijie, ZHAO Mengxi, PAN Qingcai, et al. Study on the adsorption behaviors of activated clay/chitosan composite on the multi-component pollutant[J]. Applied Chemical Industry,2016,45(10):1908−1912.
[25]	徐启杰, 孙楠, 李伟, 潘庆才, 等. 活性白土/壳聚糖复合物吸附剂对果汁的澄清作用研究[J]. 化学试剂,2017,39(3):247−250,312. [XU Qijie, SUN Nan, LI Wei, et al. Clarified effect of activated clay/chitosan composite on juice[J]. Chemical Reagents,2017,39(3):247−250,312.
[26]	徐启杰, 潘庆才, 耿电光, 等. 活性白土/羧甲基壳聚糖复合物对蔬菜汁的澄清作用[J]. 化学研究,2018,29(4):405−410. [XU Qijie, PAN Qingcai, GENG Dianguang, et al. Clarified effect of activated clay/carboxymethyl chitosan composite on vegetable juice[J]. Chemical Research,2018,29(4):405−410.
[27]	黄承都, 黄永春, 任仙娥, 等. CTS/MMT糖用澄清剂的制备及其糖汁脱色工艺研究[J]. 中国调味品,2019,44(12):31−34,49. [HUANG Chengdu, HUANG Yongchun, REN Xian’e, et al. Research on preparation of CTS/MMT as sugarcane clarifying agent and decolorization process of sugar juice[J]. China Condiment,2019,44(12):31−34,49. doi: 10.3969/j.issn.1000-9973.2019.12.007
[28]	华南工学院, 等编. 制糖工业分析[M]. 北京: 轻工业出版社, 1981. South China Institute of Technology, et al. Analysis of sugar industry[M]. Beijing: Light Industry Press, 1981.
[29]	黄承都, 艾硕, 黄永春, 等. 壳聚糖/蒙脱土复合糖用澄清剂的制备工艺及优化[J]. 中国食品添加剂,2020,31(4):35−41. [HUANG Chengdu, AI Shuo, HUANG Yongchun, et al. Preparation technology and optimization of chitosan/montmorillonite composite as sugarcane clarifying agent[J]. China Food Additives,2020,31(4):35−41.
[30]	GRANT S, BLAIR H S, MCKAY G. Structural studies on chitosan and other chitin derivatives[J]. Macromolecular Chemistry and Physics,1989,190:2279−2286. doi: 10.1002/macp.1989.021900928
[31]	于海琴, 闫良国, 辛晓东, 等. CTMAB和PDMDAAC有机改性膨润土的制备及其表征[J]. 光谱学与光谱分析,2011(5):1393−1397. [YU Haiqin, YAN Liangguo, XIN Xiaodong, et al. Synthesis and characterization of CTMAB and PDMDAAC modified organobentonite[J]. Spectroscopy and Spectral Analysis,2011(5):1393−1397. doi: 10.3964/j.issn.1000-0593(2011)05-1393-05
[32]	田玉红, 徐想丽, 李利军, 等. 新生磷酸钙对没食子酸的吸附性能研究[J]. 食品工业科技,2014,35(8):126−130. [TIAN Yuhong, XU Xiangli, LI Lijun, et al. Adsorption characteristics of gallic acid on fresh calcium phosphate[J]. Science and Technology of Food Industry,2014,35(8):126−130.
[33]	金科, 李振兴, 吴玟静, 等. 蛤蜊壳羟基磷灰石的制备及对Pb²⁺的吸附性能[J]. 食品科学,2013,34(13):39−44. [JIN Ke, LI Zhenxing, WU Wenjing, et al. Preparation of hydroxyapatite from clam shell and its adsorption capacity for Pb²⁺[J]. Food Science,2013,34(13):39−44. doi: 10.7506/spkx1002-6630-201313009
[34]	刘漫, 李和生, 徐祥浩. 乌贼墨黑色素对Pb²⁺的吸附特性研究[J]. 食品工业科技,2014,35(4):131−134,139. [LIU Man, LI Hesheng, XU Xianghao, et al. Study on adsorption characteristics of sepia melanin adsorbing Pb²⁺[J]. Science and Technology of Food Industry,2014,35(4):131−134,139.
[35]	孙俊, 于雷, 胡坤雅, 等. 新型磁性纳米载体的制备及其对溶菌酶吸附特性研究[J]. 食品工业科技,2013,34(22):119−123. [SUN Jun, YU Lei, HU Kunya, et al. Study on preparation of the novel magnetic nanoparticles and their application to lysozyme adsorption[J]. Science and Technology of Food Industry,2013,34(22):119−123.

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