Preparation and Application of Phase Change Cold Storage Material by Inverse Suspension Polymerization

KONG Qi; MU Honglei; HAN Yanchao; CHEN Hangjun; WANG Shaojin; GAO Haiyan

doi:10.13386/j.issn1002-0306.2021030350

Volume 42 Issue 24

Dec. 2021

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Science and Technology of Food Industry > 2021 > 42(24): 284-292. > DOI: 10.13386/j.issn1002-0306.2021030350

KONG Qi, MU Honglei, HAN Yanchao, et al. Preparation and Application of Phase Change Cold Storage Material by Inverse Suspension Polymerization[J]. Science and Technology of Food Industry, 2021, 42(24): 284−292. (in Chinese with English abstract). doi: 10.13386/j.issn1002-0306.2021030350.

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Preparation and Application of Phase Change Cold Storage Material by Inverse Suspension Polymerization

1.
College of Mechanical and Electronic Engineering, Northwest A & F University, Yangling 712100, China
2.
Institute of Food Science, Zhejiang Academy of Agricultural Sciences, Key Laboratory of Post-harvest Handling of Fruits, Ministry of Agriculture and Rural Affairs, Key Laboratory of Fruits and Vegetables Postharvest and Processing Technology Research of Zhejiang Province, Key Laboratory of Postharvest Preservation and Processing of Fruits and Vegetables, China National Light Industry, Hangzhou 310021, China

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Received Date: March 29, 2021
Available Online: October 13, 2021

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Abstract

Abstract

In order to elevate the water absorption capacity of the superabsorbent resin(SAR) and increase the latent heat when used as the cooling materials, the method of combining Box-Behnken test and single factor experiment were used to optimize the conditions for preparing SAR by reverse phase suspension polymerization. The storage experiments of Agaricus bisporus showed its cooling effect. The results showed that the optimal reaction conditions for preparing SAR: crosslinking agent was 0.06% of the monomer acrylic acid(AA) mass, initiator 0.9%, dispersant 4.38%, starch 10%, neutralization degree 75%, AMPS:AA=1:10, reaction temperature was 65 ℃, and the unit water absorption of the product was 573.26 g/g. The increase in water absorption improved the ability of preparing cold storage materials to keep the environment low in the incubator, and could basically maintain a low temperature environment below 10 ℃ within 12 hours under the condition of 25 ℃, furthermore, it could better maintain the color of Agaricus bisporus, inhibit weightlessness, off-odor and texture change, which indicated that the improvement of SAR water absorption could better maintain the storage quality of Agaricus bisporus.
- inverse suspension polymerization,
- cold storage material,
- preparation,
- application

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References

[1]	郜海燕, 杨海龙, 陈杭君, 等. 生鲜果蔬物流及包装技术研究与展望[J]. 食品与生物技术学报,2020,39(8):1−9. [GAO H Y, YANG H L, CHEN H J, et al. Progress and prospect of logistics and preservation technology on fresh fruit and vegetables[J]. Journal of Food Science and Biotechnology,2020,39(8):1−9. doi: 10.3969/j.issn.1673-1689.2020.08.001
[2]	BAI B, CHEN N, LI X Z. Application research of nano-storage materials in cold chain logistics of e-commerce freshagricultural products[J]. Results in Physics,2019,13(2019):102049.
[3]	KABIRI K, OMIDIAN H, ZOHURIAAN MEHR M J, et al. Superabsorbent hydrogel composites and nanocomposites: A review[J]. Polymer Composites,2011,32(2):277−289. doi: 10.1002/pc.21046
[4]	张芸. 一种可降解凝胶蓄冷剂的研制[D]. 无锡: 江南大学, 2013. ZHANG Y. The preparation of degradable gelatinous refrigerant[D]. Wuxi: Jiangnan University, 2013.
[5]	田建军, 马斐, 余响林, 等. 反相悬浮聚合法制备高吸水树脂工艺条件[J]. 武汉工程大学学报, 2012, 34(11): 9–13. TIAN J J, MA F, YU X L, et al. Technology process investigation of superabsorbent resin by inverse suspension polymerization[J]. Journal of Wuhan Institute of Technology, 2012, 34(11): 9–13.
[6]	ZHANG Y H, WANG L M, LI X H, et al. Salt-resistant superabsorbents from inverse-suspension polymerization of PEG methacrylate, acryamide and partially neutralized acrylic acid[J]. Journal of Polymer Research,2011,18(2011):157−161.
[7]	WANG G J, LI M, CHEN X F. Inverse suspension polymerization of sodium acrylate[J]. Journal of Applied Polymer Science,1997,65(4):789−794. doi: 10.1002/(SICI)1097-4628(19970725)65:4<789::AID-APP16>3.0.CO;2-O
[8]	ZHOU M, ZHAO J Z, PU W F, et al. Synthesis and characterization of salt resistance hydrogel microspheres by inverse suspension polymerization[J]. E-Polymers,2012,12(1):84.
[9]	马清华, 杨开, 孙培龙, 等. 聚乙烯醇基SiO₂/TiO₂纳米包装膜制备及对双孢菇保鲜效果[J]. 食品科学,2020,41(9):182−187. [MA Q H, YANG K, SUN P L, et al. Evaluation of polyvinyl alcohol-based SiO₂/TiO₂ nanocomposite films and their preservation effect on Agaricus bisporus[J]. Food Science,2020,41(9):182−187.
[10]	周振, 赵立, 郭圣伦, 等. 双孢菇涂膜保鲜技术研究[J]. 中国果菜,2018,38(11):1−5,14. [ZHOU Z, ZHAO L, GUO S L, et al. Study on the technology of coating preservation of Agaricus bisporus[J]. China Fruit & Vegetable,2018,38(11):1−5,14.
[11]	李瑜, 杨国浩, 詹丽娟, 等. 双孢菇中多酚氧化酶活性的影响因素[J]. 食品科学,2011,32(18):319−322. [LI Y, YANG G H, ZANG L J, et al. Affecting factors of polyphenol oxidase activity in Agaricus bisporus[J]. Food Science,2011,32(18):319−322.
[12]	史君彦, 夏春丽, 范林林, 等. 不同保鲜膜处理对双孢菇保鲜效果的影响[J]. 食品工业, 2016, 37（12）: 50−54. SHI J Y, XIA C L, FAN L L, et al. Effect of different fresh keeping films on preservation of Agaricus bisporus[J]. The Food Industry, 2016, 37（12）: 50−54.
[13]	HUANG Y W, ZEN M, REN J, et al. Preparation and swelling properties of graphene oxide/poly(acrylic acid-co-acrylamide) super-absorbent hydrogel nanocomposites[J]. Colloids & Surfaces A Physicochemical & Engineering Aspects,2012,401(2012):97−106.
[14]	HAN L L, QIN Y Y, LIU D, et al. Evaluation of biodegradable film packaging to improve the shelf-life of Boletus edulis wild edible mushrooms[J]. Innovative Food Science & Emerging Technologies,2015,29(2015):288−294.
[15]	RUX G, MAHAJAN P V, GEYER M, et al. Application of humidity-regulating tray for packaging of mushrooms[J]. Postharvest Biology and Technology,2015,108(2015):102−110.
[16]	张洪军, 潘艳娟, 王建清. 大蒜/肉桂精油复配PE膜对双孢菇的保鲜研究[J]. 包装与食品机械,2015,33(4):21−25. [ZHANG H J, PAN Y J, WANG J Q. Study on Agaricus bisporus fresh-keeping effect by garlic / cinnamon essential oil compound PE film[J]. Packaging and Food Machinery,2015,33(4):21−25. doi: 10.3969/j.issn.1005-1295.2015.04.005
[17]	GAO M S, FENG L F, JIANG T J. Browning inhibition and quality preservation of button mushroom(Agaricus bisporus) by essential oils fumigation treatment[J]. Food Chemistry,2014,149(2014):107−113.
[18]	JIANG T J. Effect of alginate coating on physicochemical and sensory qualities of buttonmushrooms(Agaricus bisporus) under a high oxygen modified atmosphere[J]. Postharvest Biology and Technology,2013,76(2013):91−97.
[19]	余响林, 饶聪, 秦天, 等. 反相悬浮聚合法制备高吸水树脂研究进展[J]. 化工新型材料,2014,42(10):20−22. [YU X L, RAO C, QIN T, et al. Research progress of preparation of superabsorbent polymer by inverse suspension polymerization[J]. New Chemical Materials,2014,42(10):20−22.
[20]	BAO Y, MA J Z, LI N. Synthesis and swelling behaviors of sodium carboxymethylcellulose-g-poly(AA-co-AM-co-AMPS)/ MMT superabsorbent hydrogel[J]. Carbohydrate Polymers,2011,84(1):76−82. doi: 10.1016/j.carbpol.2010.10.061
[21]	CZARNECKA E, NOWACZYK J. Semi-natural superabsorbents based on starch-g-poly(acrylic acid): Modification, synthesis and application[J]. Polymers,2020,12(8):1794. doi: 10.3390/polym12081794
[22]	QIAO D L, YU L, BAO X Y, et al. Understanding the microstructure and absorption rate of starch-based superabsorbent polymers prepared under high starch concentration[J]. Carbohydrate Polymers,2017,175(2017):141−148.
[23]	宋天文, 赵宇, 王万冠, 等. P (AA/AMPS)耐盐性高吸水树脂的合成及吸水性能[J]. 高分子通报,2015(11):71−77. [SONG T W, ZHAO Y, WANG W G, et al. Synthesis and water absorption performance of salt-resistant superabsorbents based upon the poly (acry acid-co-2-acrylamide-2-methyl propane sulfonic acid)[J]. Polymer Bulletin,2015(11):71−77.
[24]	GUAN H L, YONG D L, FAN M X, et al. Sodium humate modified superabsorbent resin with highersalt-tolerating and moisture-resisting capacities[J]. Journal of Applied Polymer Science,2018,46892:1−7.
[25]	DHANAPAL V, SUBRAMANIAN K. Recycling of textile dye using double network polymer from sodium alginate and superabsorbent polymer[J]. Carbohydrate Polymers,2014,108(2014):65−74.
[26]	LIU J, LI Q, SU Y, et al. Synthesis of wheat straw cellulose-g-poly(potassium acrylate)/PVA semi-IPNs superabsorbent resin[J]. Carbohydrate Polymers,2013,94(1):539−546. doi: 10.1016/j.carbpol.2013.01.089
[27]	XU X, GAO Y X, LIU G M, et al. Optimization of supercritical carbon dioxide extraction of sea buckthorn(Hippopha thamnoides L. ) oil using response surface methodology[J]. LWT-Food Science and Technology,2008,41(7):1223−1231. doi: 10.1016/j.lwt.2007.08.002
[28]	周孟颖, 张奋奋. 高分子吸水树脂作为蓄冷材料的性能研究[J]. 化工新型材料,2012,40(7):55−56. [ZHOU M Y, ZHANG F F. Study on the performance of super absorbent polymers as cool storage material[J]. New Chemical Materials,2012,40(7):55−56.
[29]	连欢, 吴元元, 王庆国, 等. 肉桂精油结合1-MCP对香菇采后褐变和感官品质的影响[J]. 北方园艺,2019(15):107−112. [LIAN H, WU Y Y, WANG Q G, et al. Combined effects of cinnamon essential oil and 1-MCP on browning and sensory quality of postharvest Lentinus edodes[J]. Northern Horticulture,2019(15):107−112.
[30]	王赵改, 杨慧, 朱广成, 等. 复方保鲜材料对双孢蘑菇保鲜效果的影响[J]. 河南农业科学,2014(1):93−96. [WANG Z G, YANG H, ZHU G C, et al. Effect of composite preservative on post-harvest fresh-keeping of Agaricus bisporus[J]. Journal of Henan Agricultural Sciences,2014(1):93−96.