Determination of Hydrogen Peroxide Migration Amount from Bamboo and Wooden Chopsticks to Food Simulants and Its Migration Law

FANG Zhengjie; WU Luming; SUN Teng; MENG Dong

doi:10.13386/j.issn1002-0306.2021010084

Volume 42 Issue 18

Sep. 2021

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Science and Technology of Food Industry > 2021 > 42(18): 57-63. > DOI: 10.13386/j.issn1002-0306.2021010084

FANG Zhengjie, WU Luming, SUN Teng, et al. Determination of Hydrogen Peroxide Migration Amount from Bamboo and Wooden Chopsticks to Food Simulants and Its Migration Law[J]. Science and Technology of Food Industry, 2021, 42(18): 57−63. (in Chinese with English abstract). doi: 10.13386/j.issn1002-0306.2021010084.

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Determination of Hydrogen Peroxide Migration Amount from Bamboo and Wooden Chopsticks to Food Simulants and Its Migration Law

Xuzhou Comprehensive Center for Inspection and Testing of Quality and Technical Supervision, Xuzhou 221000, China

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Received Date: January 12, 2021
Available Online: July 19, 2021

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Abstract

Objective: Established a measurement method of hydrogen peroxide in different food simulants, studied the migration amount of hydrogen peroxide from bamboo and wooden chopsticks to different food simulants and its migration laws. Method: Used spectrophotometer to determine hydrogen peroxide, established a standard curve of hydrogen peroxide mass in different food simulants (water-based non-acid food simulators, water-based acid food simulators, alcohol food simulators, oil-based food simulators) and absorbance, used correlation coefficient, accuracy and precision as inspection indicators to verify the methodology, taking the type of the food simulants, time, frequency and temperature as investigating factors, the migration rule of hydrogen peroxide from bamboo and wooden chopsticks to the food simulants was initially explored. Result: The correlation coefficient of the obtained standard curve was greater than 0.999, the recovery rate of standard addition was 84%~113%, the maximum relative deviation (RSD) between spiked parallel samples were all lessed than 10%. The migration amount of hydrogen peroxide from bamboo and wood chopsticks to the oil-based simulant was smallest under the same conditions, the migration of hydrogen peroxide from bamboo and wooden chopsticks had a short rapid release process, and then converted to a long-term slow migration release, the migration was a long time repeated process, and there was still migration detected at the 8th time, as the temperature increased, the amount of migration increased significantly. Conclusion: Spectrophotometric determination of hydrogen peroxide amount in different food simulants was accurate and reliable, hydrogen peroxide migration were detected in different food simulants of some bamboo and wood chopsticks by this method, its migration law was a long time and repeated process, the migration rate could be significantly increased by increased the temperature, the remigration amount of hydrogen peroxide in bamboo and wood chopsticks could effectively lowered by boiled in water at 100 °C.
- bamboo and wooden chopsticks,
- hydrogen peroxide,
- food simulants,
- migration law

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References

[1]	禄春强, 孙衎, 沈霞. 筷子安全危害源分析[J]. 食品安全质量检测学报,2019,10(12):3679−3682. [Lu C Q, Sun Y, Shen X. Hazard analysis of chopstick safety[J]. Journal of Food Safety and Quality Inspection,2019,10(12):3679−3682. doi: 10.3969/j.issn.2095-0381.2019.12.007
[2]	杨永前, 张雪仑, 何凤等. 慈竹竹片漂白机理及其工艺研究[J]. 农村科学实验,2020,8:100−103. [Yang Y Q, Zhang X L, He F, et al. Study on bleaching mechanism and technology of Neosinocalamus[J]. Rural Scientific Experiment,2020,8:100−103.
[3]	方正杰, 石丽珠, 吴路明. 筷子中有害物质分析及检测方法研究进展[J]. 食品安全质量检测学报,2020,11(18):6494−6503. [Fang Z J, Shi L Z, Wu L M. Research progress on analysis and detection methods of harmful substances in chopsticks[J]. Journal of food safety and quality inspection,2020,11(18):6494−6503.
[4]	鲍敏振, 陈玉和, 李能, 等. 竹材防腐技术的研究现状及发展趋势[J]. 西北林学院学报,2019,34(6):197−201, 239. [Bao M Z, Chen Y H, Li N, et al. Research Status and development trend of bamboo anticorrosion technology[J]. Journal of Northwest Forestry College,2019,34(6):197−201, 239. doi: 10.3969/j.issn.1001-7461.2019.06.31
[5]	中国国家标准化管理委员会. GB/T 24398-2009 植物纤维一次性筷子[S]. 北京: 中国标准出版社, 2009. Standardization Administration of China. GB/T 24398-2009 Fiber plants disposable chopsticks[S]. Beijing: China Standards Press, 2009.
[6]	中国国家标准化管理委员会. GB/T 19790.1-2005 一次性筷子第1部分: 木筷[S]. 北京: 中国标准出版社, 2005. Standardization Administration of China. GB/T 19790.1-2005 Disposable chopsticks-part 1: Wooden Chopsticks[S]. Beijing: China Standards Press, 2005.
[7]	中国国家标准化管理委员会. GB/T 19790.2-2005 一次性筷子第2部分: 竹筷[S]. 北京: 中国标准出版社, 2005. Standardization Administration of China. GB/T 19790.2-2005 Disposable Chopsticks Part 2: Bamboo Chopsticks[S]. Beijing: China Standards Press, 2005.
[8]	潘争光, 陈丰云, 贺磊, 等. 一次性竹木筷产品质量安全风险分析[J]. 食品安全质量检测学报,2018,9(24):6390‒6394. [Pan Z G, Chen F Y, He L, et al. Risk analysis on quality and safety of disposable bamboo and wooden chopsticks[J]. Journal of Food Safety and Quality Inspection,2018,9(24):6390‒6394.
[9]	丁宇, 杨磊, 王晨光, 等. 食品级过氧化氢在细胞水平的毒理学研究[J]. 食品研究与开发,2017,38(23):198‒201. [Ding Y, Yang L, Wang C G, et al. Toxicological study of food grade hydrogen peroxide at the cellular level[J]. Food Research and Development,2017,38(23):198‒201.
[10]	江国虹, 杨溢, 白世基, 等. 一起过氧化氢污染学生奶事件的调查报告[J]. 中华预防医学杂志, 2003, 37(5): 391. Jiang G H, Yang Y, Bai S J, et al. Investigation report on an incident of hydrogen peroxide pollution in student milk[J]. Chinese Journal of Preventive Medicine. 2003, 37(5): 391.
[11]	石晶, 王金美, 孟一娟, 等. 食品级过氧化氢及其在食品工业中的应用[J]. 中国食品添加剂, 2009(4): 64, 45. Shi J, Wang J M, Meng Y J, et al. Food grade hydrogen peroxide and its application in food industry[J]. Chinese Food Additives, 2009(4): 64, 45.
[12]	程楠, 董凯, 何景, 等. 食品中过氧化氢残留快速检测试纸的研制与应用[J]. 农业生物技术学报,2013,21(12):1403‒1412. [Cheng N, Dong K, He J, et al. Development and application of test paper for rapid determination of hydrogen peroxide residue in food[J]. Journal of Agricultural Biotechnology,2013,21(12):1403‒1412.
[13]	王志琴, 王军, 薛正芬, 等. 牛奶掺过氧化氢快速检测试纸研制[J]. 草食家畜,2010(3):26‒28. [Wang Z Q, Wang J, Xue Z F, et al. Development of test paper for rapid detection of milk adulterated with hydrogen peroxide[J]. Herbivorous Livestock,2010(3):26‒28.
[14]	李梦瑶, 翟晨, 何景, 等. 食品中过氧化氢快速定量检测的研究及应用[J]. 现代食品,2019(12):158−163. [Li M Y, Zhai C, He J, et al. Study and application of rapid quantitative determination of hydrogen peroxide in food[J]. Modern Food,2019(12):158−163.
[15]	Zhou Biyan, Wang Jihua, Guo Zhenfei, et al. A simple colorimetric method for determination of hydrogen peroxide in plant tissues[J]. Plant Growth Regulation, 2006, 49(29): 113–118.
[16]	金露, 汪倩, 虞选柯, 等. 固体试剂比色法测定食品中过氧化氢的研究[J]. 食品研究与开发,2014,35(4):75‒78. [Jin L, Wang Q, Yu X K, et al. Study on determination of hydrogen peroxide in food by solid reagent colorimetry[J]. Food Research and Development,2014,35(4):75‒78.
[17]	覃大元, 刘兴举, 李波. 食品中双氧水残留含量的快速测定[J]. 食品安全导刊,2013(5):31−32. [Tan D Y, Liu X J, Li B. Rapid determination of hydrogen peroxide residue in food[J]. Food Safety Guide,2013(5):31−32.
[18]	韩莉, 陶菡, 张义明, 等. 两种过氧化氢检测方法的对比研究[J]. 现代化工,2014,34(4):165‒167. [Han L, Tao H, Zhang Y M, et al. Comparison of two methods for determination of hydrogen peroxide[J]. Modern Chemical Industry,2014,34(4):165‒167.
[19]	方馨, 吴秀明, 王光丽. 基于石墨相氮化碳的荧光法检测过氧化氢[J]. 分析实验室,2016,35(4):402‒405. [Fang Q, Wu X M, Wang G L. Determination of hydrogen peroxide by fluorescence method based on graphite phase carbon nitride[J]. Analytical Laboratory,2016,35(4):402‒405.
[20]	程川川, 马保凯, 程永发, 等. 辣根过氧化物酶-金属有机骨架纳米纤维复合物生物传感器的制备及其用于食品中过氧化氢残留检测的研究[J]. 食品工业科技,2020,48(8):199−204. [Cheng C C, Ma B K, Cheng Y F, et al. Preparation of Horseradish Peroxidase Nanofiber biosensor and its application in the determination of hydrogen peroxide residues in food[J]. Science and Technology of Food Industry,2020,48(8):199−204.
[21]	陈林林, 范天娇, 李伟. 功能化纳米金修饰电极检测食品中H₂O₂的残留量[J]. 食品工业科技,2020,41(20):212−217. [Chen L L, Fan T J, Li W. Determination of H₂O₂residue in food by functionalized gold nanoparticles modified electrode[J]. Science and Technology of Food Industry,2020,41(20):212−217.
[22]	徐军军, 吴甜甜, 席慧婷, 等. 一种新型过氧化氢传感器的构建及其在牛奶中的应用[J]. 食品工业科技,2020,41(22):253−259. [Xu J J, Wu T T, Xi H T, et al. Construction of a novel hydrogen peroxide sensor and its application in milk[J]. Science and Technology of Food Industry,2020,41(22):253−259.
[23]	董哲, 邢天华. 铜纳米粒子的制备及在食品中H₂O₂残留量的测定[J]. 化工新型材料,2020,48(8):290−293. [Dong Z, Xin T H. Preparation of copper nanoparticles and determination of H₂O₂ residue in food[J]. New Materials for Chemical Industry,2020,48(8):290−293.
[24]	Yun Long Zeng, Ya Jing Wang, Zhong Hua Su, et al. Determination of hydrogen peroxide residue in food using CdS quantum dots as fluorescence probes[J]. Advanced Materials Research, 2012, 455(1528): 1189-1194.
[25]	Anastasia S, Anna D, Sergey V, et al. Method for determination of hydrogen peroxide in adulterated milk using high performance liquid chromatography[J]. Food Chemistry,2019,283(15):431−436.
[26]	Tarvin M, Mccord B, Mount K, et al. Analysis of hydrogen peroxide field samples by HPLC/FD and HPLC/ED in DC mode[J]. Forensic Sci Int,2011,209(1):166‒172.
[27]	中华人民共和国国家卫生和计划生育委员会. GB 31604.1-2015 食品安全国家标准食品接触材料及制品迁移实验通则[S]. 北京: 中国标准出版社, 2015. National Health and Family Planning Commission. GB 31604.1-2015 National Standards for Food Safety General Rules for migration testing of food contact materials and products[S]. Beijing: China Standards Press, 2015.
[28]	中国人民共和国国家卫生和计划生育委员会. GB 5009.156-2016 食品安全国家标准食品接触材料及制品迁移实验预处理方法通则[S]. 北京: 中国标准出版社, 2016. National Health and Family Planning Commission. GB 5009.156-2016 National Standards for Food Safety General Rules for pretreatment methods of migration test of food contact materials and products[S]. Beijing: China Standards Press, 2016.

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