Performance Research and Characterization of UV-shielding Alginate Films Crosslinked with Fe<sup>3+</sup> and H<sup>+</sup>

ZHUANG Xiaowen; ZHAO Yun; CHEN Chunmei; BAI Yu; XU Jiachao; GAO Xin; FU Xiaoting

doi:10.13386/j.issn1002-0306.2020120243

Volume 42 Issue 16

Aug. 2021

Turn off MathJax

Article Contents

Abstract

References

Science and Technology of Food Industry > 2021 > 42(16): 75-82. > DOI: 10.13386/j.issn1002-0306.2020120243

ZHUANG Xiaowen, ZHAO Yun, CHEN Chunmei, et al. Performance Research and Characterization of UV-shielding Alginate Films Crosslinked with Fe³⁺ and H⁺[J]. Science and Technology of Food Industry, 2021, 42(16): 75−82. (in Chinese with English abstract). doi: 10.13386/j.issn1002-0306.2020120243.

Citation:

PDF (2049 KB)

Performance Research and Characterization of UV-shielding Alginate Films Crosslinked with Fe³⁺ and H⁺

1.
Department of Seaweed Chemistry and Application, Ocean University of China, Qingdao 266003, China
2.
Qingdao Zao Yun Bio-Technology Co., Ltd., Qingdao 266100, China

More Information

Received Date: December 27, 2020
Available Online: June 07, 2021

Graphical Abstract

Abstract

Abstract

Taken sodium alginate as raw material, ion-bonded UV-resistant fiber film was prepared in this subject. The stability of the aqueous solution of the fiber membrane, the stability of ultraviolet radiation, and the thermal stability were preliminary analyzed. The scanning electron microscope (SEM), infrared spectroscopy (ATR-FTIR), and XRD were used to analyze the microstructure of the fiber membrane. The results showed that when the cross-linking conditions were 0.6% FeCl₃ and 0.4% HCl complex solution for 15 min, the comprehensive performance of Fe³⁺-H⁺ alginate fiber membrane was the best, that is, the long-wave ultraviolet transmittance was 2.92%, the tensile strength was up to 33.75 MPa, and the elongation at break rate was good at 19.54%. The Fe³⁺-H⁺ alginate fiber membrane had high crosslink densities, the internal bonding was close and the stability was good, which would provide a valuable lesson for the research and development of UV-resistant fiber materials.
- UV protection,
- alginate fiber,
- sodium alginate,
- ionic crosslink

FullText(HTML)

References (30)

References

[1]	刘杰, 吴凤芹, 姚超, 等. TiO₂/ZnO/凹土复合材料的制备表征及紫外线屏蔽性能的研究[J]. 化工新型材料,2016,44(4):119−121.
[2]	金莉莉, 何清, 曹兴. 紫外辐射研究概述[J]. 沙漠与绿洲气象,2009,3(3):1−6. doi: 10.3969/j.issn.1002-0799.2009.03.001
[3]	P. Gallagher R, Lee T K. Adverse effects of ultraviolet radiation: A brief review[J]. Progress in Biophysics Molecular Biology,2006,92(1):119−131. doi: 10.1016/j.pbiomolbio.2006.02.011
[4]	Hinds, Colm P O'Donnell, Mahbub Akhter, et al. Principles and mechanisms of ultra violet light emitting diode technology for food industry applications[J]. Innovative Food Science Emerging Technologies,2019,56:102153. doi: 10.1016/j.ifset.2019.04.006
[5]	Yasuhiro M, Honnavara N A. Short-term and long-term cellular and molecular events following UV irradiation of skin: Implications for molecular medicine[J]. Expert Reviews in Molecular Medicine,2002,4(26):1−22.
[6]	Jobanputra M C, Durstock M F, Clarson S J. Investigation of plasma polymerized benzene and furan thin films for application in opto-electronic devices[J]. Journal of Applied Polymer Science,2003,87(3):523−528. doi: 10.1002/app.11450
[7]	Anthony L A, Halim S H, Ayako T. Effects of climate change and UV-B on materials[J]. Photochemical & Photobiological Sciences: Official Journal of the European Photochemistry Association and the European Society for Photobiology,2003,2(1):68−72.
[8]	曾明朗. 食品接触材料中光稳定剂的分析测定及迁移研究[D]. 厦门: 厦门大学, 2019.
[9]	Su X, Chen B. Transparent, UV-proof and mechanically strong montmorillonite /alginate/ Ca²⁺ nanocomposite hydrogel films with solvent sensitivity[J]. Applied Clay Science,2018,165:223−233. doi: 10.1016/j.clay.2018.07.044
[10]	李华, 高小林. 防紫外线纤维及防紫外线纺织品整理工艺研究[J]. 科技经济导刊,2019,27(30):72.
[11]	程腾, 邓小雪, 赵芸, 等. 海藻酸钠/田菁胶复合膜的性能研究与表征[J]. 食品工业科技, 2021, 42(5): 211-215.
[12]	邓小雪, 程腾, 赵芸, 等. 海藻酸钠/浒苔多糖复合膜的制备及性能[J]. 渔业科学进展, 2021, 42(4): 208-214.
[13]	杨丽丽, 葛永红, 门衍玉, 等. 魔芋甘聚糖-海藻酸钠复合涂膜对生姜的保鲜性能[J]. 中国食品学报,2020,20(5):204−212.
[14]	Guo L L, Xu J C, et al. Effects of ionic crosslinking on physical and mechanical properties of alginate mulching films[J]. Carbohydrate Polymers,2016,156:435−442.
[15]	Costa M J, Marques A M, Pastrana L M, et al. Physicochemical properties of alginate-based films: Effect of ionic crosslinking and mannuronic and guluronic acid ratio[J]. Food Hydrocolloids,2018,81:442−448. doi: 10.1016/j.foodhyd.2018.03.014
[16]	王盛东, 王军辉, 王辰辰, 等. 壳聚糖/海藻酸钠可食性保鲜膜的研究进展[J]. 广东化工,2020,47(15):81−82. doi: 10.3969/j.issn.1007-1865.2020.15.036
[17]	曲丽君, 田明伟, 迟淑丽, 等. 部分石墨烯复合纤维与制品的研发[J]. 纺织学报,2016,10(37):170−177.
[18]	Bai Y, Zhao Y, Li Y, et al. UV-shielding alginate films crosslinked with Fe³⁺ containing EDTA[J]. Carbohydrate Polymers,2020:239.
[19]	ASTM. Standard test method for tensile properties of thin plastic sheeting[S]. Philadelphia: In Annual Book of ASTM Standards American Society for Testing and Materials, 2012: 882.
[20]	Rhim J-W. Physical and mechanical properties of water resistant sodium alginate films[J]. LWT-Food Science and Technology,2004,37(3):323−330. doi: 10.1016/j.lwt.2003.09.008
[21]	张万锋, 王书民. 火焰原子吸收法测定海带中的铁、钙和钴[J]. 商洛学院学报,2007(2):42−44. doi: 10.3969/j.issn.1674-0033.2007.02.012
[22]	Wang B, Kong Q, Quan F, et al. Preparation of nanostructured porous carbon composite fibers from ferrum alginate fibers[J]. Journal of Applied Polymer Science,2012,128(3):2216−2223.
[23]	Wang P, Jiang X L, Jiang Y H, et al. Structure-function relationship of anti-ultraviolet radiation in series of marine derived characteristic oligosaccharides[J]. Natural Product Research and Development,2011,23(5):874−530.
[24]	Zhao Y, Qiu J, Xu J, et al. Effects of crosslinking modes on the film forming properties of kelp mulching films[J]. Algal Research,2017,26:74−83. doi: 10.1016/j.algal.2017.07.006
[25]	Paşcalău V, Popescu V, Popescu G L, et al. The alginate/k-carrageenan ratio’s influence on the properties of the cross-linked composite films[J]. Journal of Alloys and Compounds,2012,536(Suppl 1):S418−S423.
[26]	Paula G A, Benevides N M B, Cunha A P, et al. Development and characterization of edible films from mixtures of κ-carrageenan, ι-carrageenan, and alginate[J]. Food Hydrocolloids,2015,47:140−145. doi: 10.1016/j.foodhyd.2015.01.004
[27]	Gómez-Ordóñez E, Rupérez P. FTIR-ATR spectroscopy as a tool for polysaccharide identification in edible brown and red seaweeds[J]. Food Hydrocolloids,2011,25(6):1514−1520. doi: 10.1016/j.foodhyd.2011.02.009
[28]	Hoang-Minh T, Le T L, Kasbohm J, et al. UV-protection characteristics of some clays[J]. Applied Clay Science,2010,48(3):349−357. doi: 10.1016/j.clay.2010.01.005
[29]	朱静敏, 党乐平, 卫宏远. 单宁酸对海藻酸钠/壳聚糖微球性能的影响[J]. 化学工业与工程,2021,38(1):61−68.
[30]	Lee K Y, Mooney D J. Alginate:Properties and biomedical applications[J]. Progress in Polymer Science,2012,37(1):106−126. doi: 10.1016/j.progpolymsci.2011.06.003

Supplements (0)

Cited By

Cited by

Periodical cited type(5)

1.	孙兆敏，黄水木，阎光宇，李颖，刘萌，余蕾. 食品中丙烯酰胺的来源、毒性及减控措施研究进展. 福建轻纺. 2023(07): 18-21+31 .
2.	何名芳，涂家涛. 焙烤食品添加剂的使用及发展探讨. 食品安全导刊. 2022(03): 139-141 .
3.	周媛，吴岳，许蕊，闫瑞霞，张娟，张中兴. 各种添加物对食品中丙烯酰胺的影响. 食品工业. 2021(07): 195-198 .
4.	金山，孙小凡. 食品中丙烯酰胺的形成、检测及其抑制和管理研究进展. 食品安全质量检测学报. 2021(15): 5915-5922 .
5.	刘旖旎，刘芳，王德宝，孙芝兰，吴海虹. 纳米抗菌纤维的静电纺丝制备技术及其抗菌活性研究进展. 中国食品学报. 2021(12): 358-368 .