PENG Yun, LI Guo, LIU Xueyan, et al. SPME/GC-MS Analysis of Aroma Quality of Black Tea from Different Producing Areas[J]. Science and Technology of Food Industry, 2021, 42(9): 228−235. (in Chinese with English abstract). doi: 10.13386/j.issn1002-0306. 2020060025.
Citation: PENG Yun, LI Guo, LIU Xueyan, et al. SPME/GC-MS Analysis of Aroma Quality of Black Tea from Different Producing Areas[J]. Science and Technology of Food Industry, 2021, 42(9): 228−235. (in Chinese with English abstract). doi: 10.13386/j.issn1002-0306. 2020060025.

SPME/GC-MS Analysis of Aroma Quality of Black Tea from Different Producing Areas

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  • Received Date: June 02, 2020
  • Available Online: March 02, 2021
  • In order to explore the material basis of black tea aroma and the characteristics of main aromatic components in Yunnan, Fujian and Yichang, the volatile aroma components of black tea from three different regions were analyzed by using sensory evaluation method and headspace solid phase microextraction (HS-SPME) combined with gas chromatography-mass spectrometry (GC-MS).The results showed that all the 6 kinds of black teas were dominated by sweet aroma, but dianhong had strong sweet aroma, fuding black tea had both floral fragrance and sweet aroma, and Yichang black tea had pure sweet aroma.A total of 67 kinds of aroma compounds were isolated and identified in 6 kinds of black tea by GC-MS, including alcohols, aldehydes, ketones, esters, olefins, alkanes and acids.Among them, the main aroma contribution components were alcohol compounds.The content of aroma components in various black tea was higher.The main aroma components include: Linalool and its oxides; 3,7,11-Trimethyldodeca-1,6,10-trien-3-ol; 5,9-Undecadien-2-one, 6,10-dimethyl-, (E)-;3-Buten-2-one, 4-(2,6,6-trimethyl-2-cyclohexen-1-yl)-, (E)-; 5,9-Undecadien-2-one, 6,10-dimethyl-, (E)-;Methyl Salicylateetc.Among them, linalool and its oxide were characteristic aroma components in Yunnan black tea;β-dihydroionone and β-cylinne were characteristic aroma components in Fuding black tea, while in Yichang black tea, geranyl alcohol and palmitic acid were the characteristic aroma components.The study clarified the chemical basis of the formation by the aroma quality of black tea from different origins from the perspective of aroma components, which provided a theoretical basis for the quality improvement and origin identification of black tea.
  • [1]
    V-R Sinija, Mishra H-N. Fuzzy analysis of sensory data for quality evaluation and ranking of instant green tea powder and granules[J]. Food and Bioprocess Technology,2011,4(3):408−416. doi: 10.1007/s11947-008-0163-x
    [2]
    刘飞, 王云, 张厅, 等. 红茶加工过程香气变化研究进展[J]. 茶叶科学,2018,38(1):9−19. doi: 10.3969/j.issn.1000-369X.2018.01.002
    [3]
    潘科, 冯林, 陈娟, 等. HS-SPME-GC-MS联用法分析不同通氧发酵加工工艺红茶香气成分[J]. 食品科学,2015,36(8):181−186. doi: 10.7506/spkx1002-6630-201508033
    [4]
    Ziyan Wang, Han Binsong, Jing Wangfang, et al. Effects of different steeping temperatures on the leaching of aroma components in black tea by SPME-GC-MS coupled with chemometric method[J]. Journal of Aoac International,2019,102(6):1834−1844. doi: 10.1093/jaoac/102.6.1834
    [5]
    王梦琪, 朱荫, 张悦, 等. 茶叶挥发性成分中关键呈香成分研究进展[J]. 食品科学,2019,40(23):341−349. doi: 10.7506/spkx1002-6630-20181015-132
    [6]
    Sine Yener, Sanchez-Lopez Jose-A, Granitto Pablo-M, et al. Rapid and direct volatile compound profiling of black and green teas (Camellia sinensis) from different countries with PTR-ToF-MS[J]. Talanta,2016:15245−53.
    [7]
    杨娟, 李中林, 袁林颖, 等. 重庆不同茶树品种加工工夫红茶香气成分分析[J]. 西南大学学报(自然科学版),2019,41(6):21−27.
    [8]
    张娅楠, 欧伊伶, 覃丽, 等. 红茶中香气物质的形成及工艺对其影响的研究进展[J]. 食品工业科技,2019,40(11):351−357.
    [9]
    刘聪, 张文杰, 严亮, 等. 顶空固相微萃取结合GC/MS分析玫瑰香型滇红茶香气成分[J]. 食品科技,2017,42(8):300−305.
    [10]
    宛晓春. 茶叶生物化学[M]. 北京: 中国农业出版社, 2003.
    [11]
    徐元骏, 何靓, 贾玲燕, 等. 不同地区及特殊品种红茶香气的差异性[J]. 浙江大学学报(农业与生命科学版),2015,41(3):323−330.
    [12]
    Xiaohua Chen, Chen Dejing, Jiang Hai, et al. Aroma characterization of Hanzhong black tea (Camellia sinensis) using solid phase extraction coupled with gas chromatography-massspectrometry and olfactometry and sensory analysis[J]. Food Chemistry,2019:274130−136.
    [13]
    王秋霜, 陈栋, 许勇泉, 等. 中国名优红茶香气成分的比较研究[J]. 中国食品学报,2013,13(1):195−200.
    [14]
    任洪涛, 周斌, 夏凯国, 等. 不同级别云南工夫红茶香气成分比较分析[J]. 南方农业学报,2012,43(4):489−492. doi: 10.3969/j:issn.2095-1191.2012.04.489
    [15]
    任洪涛, 周斌, 秦太峰, 等. 基于多元统计分析的云南红茶香气质量评价[J]. 现代食品科技,2013,29(12):3006−3013.
    [16]
    Chengying Ma, Li Junxing, Chen Wei, et al. Study of the aroma formation and transformation during the manufacturing process of oolong tea by solid-phase micro-extraction and gas chromatography-mass spectrometry combined with chemometrics[J]. Food Research International (Ottawa, Ont.),2018:108.
    [17]
    Zechang Liu, Wang Liping, Liu Yumei. Rapid differentiation of Chinese hop varieties (Humulus lupulus) using volatile fingerprinting by HS-SPME-GC-MS combined with multivariate statistical analysis[J]. Journal of the Science of Food and Agriculture,2018,98(10):3758−3766. doi: 10.1002/jsfa.8889
    [18]
    Patcharee Pripdeevech, Rothwell Joseph, D'Souza Priya-E, et al. Differentiation of volatile profiles of Thai Oolong tea No. 12 provenances by SPME-GC-MS combined with principal component analysis[J]. International Journal of Food Properties,2018:203S2450−S2462.
    [19]
    程超, 杜芬妮, 李伟, 等. 基于9种风味物质的利川红SPME优化及PLS-DA风味识别[J/OL]. 食品科学: 1-13[2021-02-19]. http://kns.cnki.net/kcms/detail/11.2206.TS.20200601.1400.044.html.
    [20]
    P-Okinda Owuor, Obanda Martin, Nyirenda Hastings-E, et al. Influence of region of production on clonal black tea chemical characteristics[J]. Food Chemistry,2008,108(1):263−271. doi: 10.1016/j.foodchem.2007.09.017
    [21]
    Kele-A-C Vespermann, Paulino Bruno-N, Barcelos Mayara-C-S, et al. Biotransformation of α- and β-pinene into flavor compounds[J]. Applied Microbiology and Biotechnology,2017,101(5):1805−1817. doi: 10.1007/s00253-016-8066-7
    [22]
    章港, 黄文静, 徐珩, 等. 基于气质联用技术的“祁门香”特征性成分分析[J]. 茶叶通讯,2020,47(1):96−101. doi: 10.3969/j.issn.1009-525X.2020.01.017
    [23]
    X-Q Zheng, Li Q-S, Xiang L-P, et al. Recent advances in volatiles of teas[J]. Molecules,2016,21(3):338. doi: 10.3390/molecules21030338
    [24]
    金友兰, 黄甜, 蒋容港, 等. 不同类型发花砖茶特征香气成分研究[J/OL]. 食品与发酵工业: 1−11[2021-02-19]. https://doi.org/10.13995/j.cnki.11-1802/ts.025075.
    [25]
    肖凌. 十种香型凤凰单丛茶香气成分分析[D]. 重庆: 西南大学, 2018.
    [26]
    Suyoung Kang, Yan Han, Zhu Yin, et al. Identification and quantification of key odorants in the world's four most famous black teas[J]. Food Research International,2019:12173−83.
    [27]
    S Lv, Wu Y, Li C, et al. Comparative analysis of Pu-erh and Fuzhuan teas by fully automatic headspace solid-phase microextraction coupled with gas chromatography-mass spectrometry and chemometric methods[J]. J Agric Food Chem,2014,62(8):1810−1818. doi: 10.1021/jf405237u
    [28]
    马士成, 刘春梅, 王梦琪, 等. 六堡茶挥发性成分中的关键香气成分研究[J]. 食品科学,2020,41(20):191−197.
    [29]
    王维皓, 杨立新. 羌活挥发性成分GC-MS分析[J]. 中国实验方剂学杂志,2020,26(23):153−160.
    [30]
    M-Q Wang, Ma W-J, Shi J, et al. Characterization of the key aroma compounds in Longjing tea using stir bar sorptive extraction (SBSE) combined with gas chromatography-mass spectrometry (GC-MS), gas chromatography-olfactometry (GC-O), odor activity value (OAV), and aroma recombination[J]. Food Res Int,2020:130108908.
    [31]
    王秋霜, 乔小燕, 操君喜, 等. 广东单丛茶树品种红茶香气成分的GC-MS分析[J]. 食品科学,2015,36(4):114−118.
    [32]
    Robin Joshi, Gulati Ashu. Fractionation and identification of minor and aroma-active constituents in Kangra orthodox black tea[J]. Food Chemistry,2015:167290−298.
    [33]
    曹晓念, 周志磊, 刘青青, 等. 基于香气成分的红茶品种比较分析[J]. 食品与发酵科技,2020,56(3):118−122.
    [34]
    罗学平, 李丽霞. SPME-GC-MS联用分析川红、滇红和祁红香气成分[J]. 宜宾学院学报,2016,16(6):102−107. doi: 10.3969/j.issn.1671-5365.2016.06.025
    [35]
    廉明, 吕世懂, 吴远双, 等. 我国4种红茶的挥发性成分分析[J]. 热带亚热带植物学报,2015,23(3):301−309. doi: 10.11926/j.issn.1005-3395.2015.03.011
    [36]
    赵瑶, 宋晓东, 黄啟亮, 等. 宜昌红茶代表产品的香气成分研究[J]. 湖北农业科学,2016,55(24):6493−6497.
    [37]
    郑鹏程, 刘盼盼, 龚自明, 等. 湖北红茶特征性香气成分分析[J]. 茶叶科学,2017,37(5):465−475. doi: 10.3969/j.issn.1000-369X.2017.05.005
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