CHENG Hao, SUN Liming, TANG Tingfan. Preparation of Spherical Porous Magnesium Silicate and Its Application in Decolorization of Sugar Juice[J]. Science and Technology of Food Industry, 2021, 42(5): 18-25. DOI: 10.13386/j.issn1002-0306.2020040084
Citation: CHENG Hao, SUN Liming, TANG Tingfan. Preparation of Spherical Porous Magnesium Silicate and Its Application in Decolorization of Sugar Juice[J]. Science and Technology of Food Industry, 2021, 42(5): 18-25. DOI: 10.13386/j.issn1002-0306.2020040084

Preparation of Spherical Porous Magnesium Silicate and Its Application in Decolorization of Sugar Juice

More Information
  • Received Date: April 09, 2020
  • Available Online: March 02, 2021
  • Objective:To study the preparation of spherical porous magnesium silicate and its application in decolorization of sugar juice. Methods:The porous magnesium silicate was prepared by hydrothermal synthesis method and template method with magnesium chloride and silica gel as precursors. XRD,FTIR and SEM were used to characterize the porous magnesium silicates. The effects of spherical porous magnesium silicate,adsorption temperature,adsorption time and pH value on decolorization performance of raw sugar solution were investigated by using spherical porous magnesium silicate as sorbent,taking raw sugar solution as research object and decolorization rate index. The adsorption process of porous magnesium silicate on sugar pigment was investigated. Results:The characterization results showed the spherical porous magnesium silicates was obtained. The results of decoloration showed that when the dosage was 0.10 g,the adsorption temperature was 30 ℃,the adsorption time was 40 min,and the pH value was 6.0,the decoloring rate of the juice was 69.8%. Under the experiment conditions the adsorption of sugar cane juice on spherical porous magnesium silicate follows quasi-secondary kinetic equation and Langmuir isothermal adsorption equation. Conclusions:The results can provide new methods and theoretical basis for the development of the sugar production technology and process use magnesium.
  • [1]
    Thai C C,Bakir H,Doherty W O. Insights to the clarification of sugar cane juice expressed from sugar cane stalk and trash[J]. Journal of Agricultural & Food Chemistry,2012,60(11):2916-2923.
    [2]
    姚延志,胡乃仁,刘汉木,等.甘蔗的磷酸亚硫酸法澄清工艺条件的优化[J].甘蔗糖业,2015(1):25-29.
    [3]
    陈树功.现代制糖工艺理论[M].北京:轻工业出版社,1988.
    [4]
    Song X R,Chei Z H,Zhu Y,et al. Preparation and characterization of magnetic chitosan-modified diatomite for the removal of gallic acid and caffeic acid from sugar solution[J]. Carbohydrate Polymers,2019(219):316-327.
    [5]
    向富友,李利军,程昊.新生亚硫酸钙在糖汁清净过程中的机理[J].食品科学,2017,38(23):39-44.
    [6]
    夏兆博,冯淑娟,李利军,等. 多孔磷酸钙的制备及其对糖汁清净工艺的研究[J]. 食品工业,2017,38(3):22-27.
    [7]
    Seyed M N,Sara A,Mohammad S. Removal of coloured compounds from date syrup using activated carbon:A kinetic study[J]. Journal of Food Engineering,2012(3):490-495.
    [8]
    黄承都,黄永春,刘斌,等.维生素C改性膨润土的制备及其在蔗汁脱色中的应用[J].中国食品添加剂,2020,31(3):125-131.
    [9]
    Alonso J.Evaluation of different types of carbons in the decolourization process in sugar refining[R].Cuban Sugar Research Institute Report,1985:68-73
    [10]
    宗宝,孙卫东,刘容,等.改性沸石在蔗汁脱色中的应用研究[J].绿色科技,2012(5):280-282.
    [11]
    黄承都,艾硕,黄永春,等.壳聚糖/蒙脱土复合糖用澄清剂的制备工艺及优化[J].中国食品添加剂,2020,31(4):35-41.
    [12]
    冯淑娟,李利军,夏兆博,等. 多孔氧化镁的制备及其对糖汁的吸附性能研究[J]. 食品与发酵工业,2016,42(8):121-127.
    [13]
    郑春明. 多孔无机/聚合物复合材料的制备,表征及在制糖工业的中试应用[D]. 天津:南开大学,2009:1-20.
    [14]
    高慧慧,邓小龙,黄金昭,等.生物硅源制备花状硅酸镁及其对放射性核素U(Ⅵ)的去除[J].中国科学:化学,2019,49(1):103-112.
    [15]
    Gui C X,Wang Q Q,Hao S M,et al. Sandwichlike magnesium silicate/reduced graphene oxide nanocomposite for enhanced Pb2+ and methylene blue adsorption[J]. ACS Applied Materials & Interfaces,2014,6:14653-14659.
    [16]
    赵春燕. 多孔硅酸镁的制备及吸附性能研究[D]. 北京:北京化工大学,2018:1-27.
    [17]
    Clowutimon W,Kitchaiya P,Assawasaengrat P,et al. Adsorption of free fatty acid from crude palm oil on magnesium silicate derived from rice husk[J]. Engineering Journal,2011,15(3):15-26.
    [18]
    程昊,孙黎明,唐婷范,等.多孔硅酸镁的表征及其对糖汁中没食子酸的吸附[J].食品工业科技,2020,41(9):8-13.
    [19]
    朴金花,林福兰. 糖品分析实验技术[M]. 广州:华南理工大学出版社,2015.
    [20]
    周友全,唐婷范,程昊,等.壳聚糖对蔗糖溶液中单宁酸的吸附性能研究[J].食品工业科技,2020,41(3):12-15

    ,21.
    [21]
    Xu X,Gao B,Wang W Y,et al. Adsorption of phosphate from aqueous solutions onto modified wheat residue:Characteristics,kinetic and column studies[J]. Colloids and Surfaces B,2009,70(1):46-52.
    [22]
    Yu H,Shan H O. Second-order kinetic model for the sorption of cadmiumonto tree fern:A comparison of linear and non-linear methods[J]. Water Research,2006(40):119-125.
    [23]
    王丽雄,古梅,杨亮,等. 硅酸镁吸附剂的制备及性能表征[J]. 核化学与放射化学,2013,35(6):364-370.
    [24]
    何树珍,于淑娟,张平军,等. 色素在黄冰糖中的存在形式[J]. 食品工业科技,2012,33(6):153-155.
    [25]
    Wang Y,Wang G,Wang H,et al. Chemical-template synthesis of micro/nanoscale magnesium silicate hollow spheres for waste-water treatment[J]. Chemistry-A European Journal,2010,16(11):3497-3503.
    [26]
    方娴韵,俞淑佳,陈旖婷,等. 硅酸镁纳米空心球的制备及对蛋白质负载和释放性能的研究[J]. 北京生物医学工程,2018,37(6):589-596.
  • Cited by

    Periodical cited type(7)

    1. 陈金足,韦晓雯,农晶晶,韩丽芳,冯学,唐婷范,李利军,程昊. 氢氧化镁-活性炭复合材料的制备及其对糖浆脱色工艺优化. 食品工业科技. 2025(01): 201-207 . 本站查看
    2. 蔡全龙,程昊,唐婷范,张文康,卫政涛,李利军. 双极性MgO纳米棒的制备、表征及其在原糖回溶糖浆脱色的应用. 食品研究与开发. 2025(03): 125-131 .
    3. 干莉娜,张文康,赵家欣,唐婷范,卫政涛,程昊. 壳聚糖-甘蔗渣活性炭复合材料的制备及在糖汁清净中的应用. 中国调味品. 2024(04): 25-31 .
    4. 林华,唐婷范,陈金足,苏萍萍,程昊. 水热法制备多孔硅酸镁及其对糖汁的脱色性能分析. 广西糖业. 2024(06): 419-425 .
    5. 唐婷范,任逸,朱家庆,黄芳丽,程昊. 氢氧化镁对蔗糖溶液中单宁酸的吸附性能研究. 中国调味品. 2022(08): 46-50 .
    6. 田鑫莉 ,张文康 ,李利军 ,卫政涛 ,程昊 . 硅酸镁-石灰乳法对原糖回溶糖浆脱色性能的研究. 食品工业. 2022(09): 51-55 .
    7. 王琪浩,王余莲,王楠,李闯,张俊,朱益斌,刘珈伊,时天骄,林永瑾,田伊笛,苏德生,袁志刚. 高比表面积羟基硅酸镁的制备及其形成机理研究. 沈阳理工大学学报. 2022(06): 58-65 .

    Other cited types(2)

Catalog

    Article Metrics

    Article views (333) PDF downloads (21) Cited by(9)

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return