Science and Technology of Food Industry

ISSN 1002-0306
CN   11-1759/TS
High-quality sci-tech periodicals
Menu
Volume 42 Issue 2
Jan.  2021
Turn off MathJax
Article Contents
Abstract
References
Related Articles
LIU Huawen, SU Haiyan, LU Xiaokang, XUE Yaxin, LV Min, ZHANG Ronglin, MO Ying. Determination of 28 Kinds of Pesticide Residues in Tea by QuEChERS/Ultra Performance Liquid Chromatography-Tandem Mass Spectrometry[J]. Science and Technology of Food Industry, 2021, 42(2): 223-229,236. DOI: 10.13386/j.issn1002-0306.2020040021
Citation: LIU Huawen, SU Haiyan, LU Xiaokang, XUE Yaxin, LV Min, ZHANG Ronglin, MO Ying. Determination of 28 Kinds of Pesticide Residues in Tea by QuEChERS/Ultra Performance Liquid Chromatography-Tandem Mass Spectrometry[J]. Science and Technology of Food Industry, 2021, 42(2): 223-229,236. DOI: 10.13386/j.issn1002-0306.2020040021
shu

Determination of 28 Kinds of Pesticide Residues in Tea by QuEChERS/Ultra Performance Liquid Chromatography-Tandem Mass Spectrometry

  • Guang xi-Asean Center Food Control, Nanning 530021, China

More Information
  • Received Date: April 02, 2020
  • Available Online: January 20, 2021
    Graphical Abstract
    • Abstract
  • A QuEChERS/ultra performance liquid chromatography - tandem mass spectrometry(UPLC-MS/MS)method was developed for the determination of 28 kinds pesticide residues in green tea. The tested samples were extracted with 1% glacial acetic acid acetonitrile,and then purified using QuEChERS method. Analysis on the targets was performed by electrospray ionization mass spectrometry in positive mode,multiple reaction monitoring(MRM)mode was used for collection,and matrix matched standard curve method was selected for quantitation. Results showed that 28 analytes showed good linearities in their respective ranges,with correlation coefficients(r)between 0.990 and 0.998.The limits of detection(LOD,S/N≥3)were 0.08~1.26 μg/kg while the limits of quantitation(LOQ,S/N≥10)were 0.28~4.20 μg/kg. Recoveries for the target analytes at spiked levels of 10,50 and 80 μg/kg ranged from 72.5% to 118.5%,with relative standard deviations(n=6)of 0.8%~16.3%. The method is simple,rapid,replicable and high stable,and can satisfy meet the requirements for determination of 28 pesticide residues in tea.
    • FullText(HTML)
    • References (28)
  • [1]
    兰岚,周恒,李雯婷,等.QuEChERS-超高效液相色谱-串联质谱法测定葡萄中388种农药残留[J].食品工业科技,2019,40(21):256-261

    ,267.
    [2]
    Sharma D,Nagpal A,Pakade Y B,et al.Analytical methods for estimation of organophosphorus pesticide residues in fruits and vegetables:A review[J].Talanta,2010,82(4):1077-1089.
    [3]
    王继红.农药残留对人体的危害及预防措施[J].农业与技术,2018,38(16):29.
    [4]
    孙玲,黄健祥,邓义才,等.广东省主要叶菜农药残留膳食暴露风险评估研究[J].食品科学,2017,38(17):223-227.
    [5]
    赵彦涛.蔬菜农残检测中的问题及其对策分析[J].南方农业,2018,12(14):154,156.
    [6]
    国家食品药品监督管理总局,国家卫生和计划生育委员会.GB 2763-2016食品安全国家标准,食品中农药最大残留限量[S].北京:中国标准出版社,2017.
    [7]
    Hu J H,Chen Y Q,Ni D J.Effect of superfine grinding on quality and antioxidant property of fine green tea powders[J]. LWT-Food Science and Technology,2012,45(1):8-12.
    [8]
    Carneiro B M,Batista M N,Braga A C S,et al.The green tea molecule EGCG inhibits Zika virus entry[J].Virology,2016,496:215-218.
    [9]
    Gramza-Michałowska A,Kobus-Cisowska J,Kmiecik D,et al.Antioxidative potential,nutritional value and sensory profiles of confectionery fortified with green and yellow tea leaves(Camellia sinensis)[J].Food Chemistry,2016,211:448-454.
    [10]
    Kobayashi M,Ikeda I.Mechanisms of inhibition of cholesterol absorption by green tea catechins[J].Food Science and Technology Research,2017,23(5):627-636.
    [11]
    霍丹群,付贝贝,李俊杰,等.基于液体阵列比色传感器鉴别不同茶叶的新方法[J].高等学校化学学报,2016,37(5):873-880.
    [12]
    张娅婷,秦广雍,孔令军,等.利用亚临界丁烷分离茶树鲜叶中的阿维菌素[J].分析化学,2017,45(6):844-850.
    [13]
    Yue N,Kuang H,Sun L,et al.An empirical analysis of the impact of EU's new food safety standards on China's tea export[J].International Journal of Food Science & Technology,2010,45(4):745-750.
    [14]
    Hou X,Lei S R,Qiu S T,et al.A multi-residue method for the determination of pesticides in tea using multi-walled carbon nanotubes as a dispersive solid phase extraction absorbent[J]. Food Chemistry,2014,153:121-129.
    [15]
    Li J X,Zhang Z J,Sun M Y,et al.Use of a headspace solid-phase microextraction-based methodology followed by gas chromatography-tandem mass spectrometry for pesticide multiresidue determination in teas[J].Chromatographia,2018,81(5):809-821.
    [16]
    Fang Y,Tian W,Pei F,et al.Simultaneous determination of pesticide residues and antioxidants in blended oil using a liquid-liquid extraction combined with dispersive solid phase extraction method[J].Food Chemistry,2017,229:347-353.
    [17]
    Kadir H A,Abas F,Zakaria O,et al.Analysis of pesticide residues in tea using accelerated solvent extraction with in-cell cleanup and gas chromatography tandem mass spectrometry[J]. Analytical Methods,2015,7(7):3141-3147.
    [18]
    张新忠,罗逢健,张芬,等.分散固相萃取净化气相色谱串联质谱法测定茶叶、西葫芦和芒果中噻螨酮和噻嗪酮残留量[J].分析化学,2012,40(11):1686-1692.
    [19]
    Anastassiades M,Lehotay S J,Štajnbaher D,et al.Fast and easy multiresidue method employing acetonitrile extraction/partitioning and "dispersive solid-phase extraction" for the determination of pesticide residues in produce[J].Journal of AOAC International,2003,86(2):412-431.
    [20]
    Kaczyński P,Łozowicka B.One-step QuEChERS-based approach to extraction and cleanup in multiresidue analysis of sulfonylurea herbicides in cereals by liquid chromatography-tandem mass spectrometry[J].Food Analytical Methods,2017,10(1):147-160.
    [21]
    叶江雷,金贵娥,吴云辉,等.QuEChERS法提取净化结合气-质联法快速检测茶叶中农药残留[J].食品科学,2013,34(12):265-271.
    [22]
    李俊,蔡滔,杜楠,等.QuEChERS-气相色谱-串联质谱法测定茶青中28种农药残留[J].农药学学报,2017,19(3):366-373.
    [23]
    付晓芳,林雁飞,李晶,等.茶叶中氟虫腈残留量的检测[J].食品科学,2010,31(10):279-282.
    [24]
    吴伟斌,刘文超,李泽艺,等.基于高光谱的茶叶含水量检测模型建立与试验研究[J].河南农业大学学报,2018,52(5):818-824.
    [25]
    兰韬,初侨,郝东宇,等.Sin-QuEChERS结合UPLC-MS/MS同时检测茶叶中10种有机磷农药残留[J].质谱学报,2019,40(3):268-279.
    [26]
    Tyler T.Evaluation of EN15662:2008 Food of plant origin-Deterninationg of Pesticide Residues in Food of Plant Origin,by an Automated QuEChERS Solution[R]. EPRW,2014.
    [27]
    张聪,周常义,江锋,等.超高效液相色谱-串联质谱法测定动物性食品中10种拟除虫菊酯类农药残留[J].分析测试学报,2018,37(8):887-893.
    [28]
    国家食品药品监督管理总局,国家卫生和计划生育委员会. GB 23200.13-2016食品安全国家标准,茶叶中448种农药及相关化学品残留量的测定,液相色谱-质谱法[S].北京:中国标准出版社,2017.
    • Related Articles

  • Related Articles

    [1]XIE Qilan, ZHANG Yuxi, ZOU Zhiyun, MA Xue, WU Yaxuan, CUI Xinxin, WANG Yilang, HE Honghong, WANG Linlin. Effects of Different Types of Starch and Pretreatment Temperature on the Gel Properties of Grounded Tibetan Mutton[J]. Science and Technology of Food Industry, 2024, 45(22): 46-54. DOI: 10.13386/j.issn1002-0306.2023120107
    [2]TAN Hongyuan, LING Yuzhao, HUANG Liqi, XIONG Guangquan, QIAO Yu, WEI Lingyun. Effects of Different Pretreatment on the Quality Characteristics and Microstructure of Hot Air Dried Yam Slices[J]. Science and Technology of Food Industry, 2023, 44(20): 43-52. DOI: 10.13386/j.issn1002-0306.2022110328
    [3]HANG Yuyu, YU Shuchi, SHANG Wenhui, QI Dan. Effect of Passion Fruit Peel Powder on the Gelation Characteristics of Non-rinsed Tilapia Surimi[J]. Science and Technology of Food Industry, 2022, 43(19): 92-97. DOI: 10.13386/j.issn1002-0306.2021120308
    [4]LI Shuai, ZHAO Yanyan, ZENG Yingnan, GU Yu. Effect of Low-temperature Plasma Pretreatment on Hot-air with Thin-layer Drying Characteristics of Potatos[J]. Science and Technology of Food Industry, 2022, 43(9): 87-92. DOI: 10.13386/j.issn1002-0306.2021080161
    [5]SUN Qingyun, ZHANG Zongchao, JIA Zhenchao, HAN Menglong, ZHAO Feng. Effects of Physical Pretreatment Methods and Hot Air Temperatures on the Hot Air Drying Characteristics and Quality of Yangxincai (Sedum aizoon L.)[J]. Science and Technology of Food Industry, 2021, 42(13): 210-215. DOI: 10.13386/j.issn1002-0306.2020100184
    [6]GAO Qi, YU Hao-rui, CHEN Jia-nan, WANG Xiao-wen, ZHANG Jun-wei, XUE You-lin. Gelation Properties of Yam Soluble Protein[J]. Science and Technology of Food Industry, 2019, 40(10): 32-36,42. DOI: 10.13386/j.issn1002-0306.2019.10.006
    [7]ZHANG Pan, CHEN Xin, XIONG Shuang-li, XUE Chao-yun. Effects of Different Pretreatments on Physicochemical Properties of Pectin from Premna microphylla Turcz Leaves[J]. Science and Technology of Food Industry, 2019, 40(1): 82-86,91. DOI: 10.13386/j.issn1002-0306.2019.01.015
    [8]LI Xiao-ying, GAO Yan-xiang, YUAN Fang. Research progress on the effects of ultra-high pressure on gelation property of food[J]. Science and Technology of Food Industry, 2017, (07): 385-389. DOI: 10.13386/j.issn1002-0306.2017.07.066
    [9]SHI Dan, SUN Xiang-dong, ZHANG Yun, LAN Yu, LIU Chun-yu. Study on gelation characteristics of corn germ proteins[J]. Science and Technology of Food Industry, 2016, (07): 67-70. DOI: 10.13386/j.issn1002-0306.2016.07.005
    [10]QI Hai-ling, YIN Zhong-yi, GU Ya-jing, ZHENG Xu-xu. Effect of ultrasonic pretreatment on alkali extraction process and characteristics of coral ginger starches[J]. Science and Technology of Food Industry, 2015, (12): 244-248. DOI: 10.13386/j.issn1002-0306.2015.12.043
    • Supplements (0)

  • Cited by

    Periodical cited type(2)

    1. 伍蓉，贺灵芝，谭美玲，张华，阎睿. 重庆市蜂产品中31种农兽药残留检测方法开发及其膳食暴露风险评估. 中国酿造. 2025(02): 273-280 .
    2. 蒋昆，余义冉，张雯雯，阮靖轩，石玉，陈雨，白红艳. 磺胺甲嗪(口恶)唑电化学检测方法的研究进展. 印染助剂. 2024(11): 13-16 .

    Other cited types(1)

Catalog

    Get Citation
    PDF
    XML

    Article Metrics

    Article views (413) PDF downloads (44) Cited by(3)
    Address：No. 70, Shazikou Road, Yongding gate, BeijingPostcode：100101
    Tel：010-87244116 87244117Fax :010-87287944
    RSS Email Alert

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return