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中国精品科技期刊2020
张乃片, 王承明, 奥文芳, 李克超, 白娟. 植酸分子印迹聚合物的制备、表征及吸附性能[J]. 食品工业科技, 2017, (17): 75-79. DOI: 10.13386/j.issn1002-0306.2017.17.015
引用本文: 张乃片, 王承明, 奥文芳, 李克超, 白娟. 植酸分子印迹聚合物的制备、表征及吸附性能[J]. 食品工业科技, 2017, (17): 75-79. DOI: 10.13386/j.issn1002-0306.2017.17.015
ZHANG Nai-pian, WANG Cheng-ming, AO Wen-fang, LI Ke-chao, BAI Juan. Preparation and characterization of phytic acid molecularly imprinted polymer and its adsorption performance[J]. Science and Technology of Food Industry, 2017, (17): 75-79. DOI: 10.13386/j.issn1002-0306.2017.17.015
Citation: ZHANG Nai-pian, WANG Cheng-ming, AO Wen-fang, LI Ke-chao, BAI Juan. Preparation and characterization of phytic acid molecularly imprinted polymer and its adsorption performance[J]. Science and Technology of Food Industry, 2017, (17): 75-79. DOI: 10.13386/j.issn1002-0306.2017.17.015

植酸分子印迹聚合物的制备、表征及吸附性能

Preparation and characterization of phytic acid molecularly imprinted polymer and its adsorption performance

  • 摘要: 以植酸为模板分子,甲基丙烯酸(MAA)为功能单体,N,N’-乙烯基丙烯酰胺(EBA)为交联剂,过硫酸铵为引发剂,采用本体聚合法制备对植酸具有高特异选择性的植酸分子印迹聚合物(MIPs)。通过扫描电镜观察了分子印迹聚合物表面的结构,利用红外光谱进一步对其化学结构进行表征。通过动态吸附、静态吸附和选择性吸附考察了其吸附性能。研究表明植酸分子印迹聚合物对植酸的吸附高于对肌醇的吸附,植酸在印迹聚合物中的印迹因子为1.70,而与植酸结构相似物肌醇的印迹因子为1.46。解吸80 min,MIPs解吸达到稳定,解吸率达到89.59%。植酸分子印迹聚合物对植酸的吸附特异性强,对植酸的吸附量为21.38μmol·g-1,解吸效果好,进行吸附-解吸附循环5次后,植酸印迹聚合物的性能稳定,对植酸吸附容量为65.62μmol·g-1,是第一次吸附容量的90.00%,可重复使用。 

     

    Abstract: The molecularly imprinted polymer ( MIPs) were prepared by bulk polymerization using phytic acid ( PA) as template molecule, MAA as functional monomer, N, N'-Ethylenebis ( acrylamide) as crosslinker, Ammonium persulphate as initiator.Surface structure of molecularly imprinted polymers was observed by SEM, the chemical structure of MIPs was characterized by FT-IR. MIPs adsorption performance were investigated by dynamic adsorption, static adsorption and selective adsorption experiments. The experimental results showed that the PA MIPs exhibited good adsorption and recognition abilities, with imprinted factors of 1.70, while myo-inositol ( MI) was 1.46.The adsorption reaction reached equilibrium after 80 min, and the desorption ratio of ractopamine reached 89.59%.The experimental results showed that MIPs not only have specific recognition selectivity, but also have good desorption property for PA, and the adsorption capacity of phytic acid was 21.38 μmol·g-1.After adsorption-desorption 5 times, MIPs were stable and reusable, the adsorption capacity of phytic acid was 65.62 μmol·g-1, which was 90.00% of the first adsorption capacity and could be cycle used.

     

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