纳米SiO2抑制PVC中增塑剂DOP迁移的研究
Effect of Nano-SiO2 on suppression of plasticizers DOP migration from PVC
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摘要: 实验通过添加纳米粒子SiO2,研究抑制软质聚氯乙烯(PVC)中增塑剂邻苯二甲酸二辛脂(DOP)迁移规律,评价PVC样品溶剂抽出率,对挥发损失率、拉伸性能和邵氏硬度的测定分析,得出以下结论:纳米粒子SiO2可以抑制软质PVC中DOP的迁移。用正己烷浸泡PVC样品,随浸泡时间的延长,溶剂抽出率增大;随着添加的纳米SiO2含量的增加,样品的溶剂抽出率降低。在浸泡24h后,添加5份纳米SiO2样品PVC的溶剂抽出率为18.9%,比对照(25.6%)降低了26.2%。添加少量的纳米SiO2并没有使样品的挥发损失率明显降低,添加1~5份不同量的纳米SiO2的样品的挥发损失率均比不添加纳米SiO2的对照样品低。随着无机纳米粒子含量的增加,样品的拉伸强度和断裂伸长率反而降低,硬度有所增加。Abstract: Nano-particles SiO2 was employed to curb DOP migration from PVC sheets.The DOP extraction rate, DOP volatilization rate, tensile properties and shore hardness of PVC samples were studied.The approaches of suppressing DOP migration were researched.The results showed that DOP migration can be resisted by addition of nano-particles SiO2 in soft PVC matrix.After PVC samples soaked with n-hexane, solvent extraction rate increases with the immersion time.Conversely, the rate of solvent extraction reduces.with the increasing of nano-SiO2 content.The addition of 5 phr nano-SiO2 reduced the DOP extraction (18.9 %) rate by 26.2% compared to the reference (25.6%) after immersing for 24h.Adding a little of nano-SiO2 could not reduce the volatilization loss rate significantly.The volatilization loss rate of containing differents amount nano-SiO2 lower than the control samples (without nano-SiO2) .The tensile strength and elongation at break of PVC reduced as the increasing content of nano-SiO2.The hardness of PVC was strengthened as the nano-SiO2.