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中国精品科技期刊2020
严峰, 杨路瑶, 汪伦. 基于电感耦合等离子质谱检测对虾中重金属及其健康风险评价[J]. 食品工业科技, 2019, 40(12): 254-258,264. DOI: 10.13386/j.issn1002-0306.2019.12.041
引用本文: 严峰, 杨路瑶, 汪伦. 基于电感耦合等离子质谱检测对虾中重金属及其健康风险评价[J]. 食品工业科技, 2019, 40(12): 254-258,264. DOI: 10.13386/j.issn1002-0306.2019.12.041
YAN Feng, YANG Lu-yao, WANG Lun. Analytical Method Based on Inductively Coupled Plasma Mass Spectrometry and Health Risk of Heavy Metal Elements in Prawns[J]. Science and Technology of Food Industry, 2019, 40(12): 254-258,264. DOI: 10.13386/j.issn1002-0306.2019.12.041
Citation: YAN Feng, YANG Lu-yao, WANG Lun. Analytical Method Based on Inductively Coupled Plasma Mass Spectrometry and Health Risk of Heavy Metal Elements in Prawns[J]. Science and Technology of Food Industry, 2019, 40(12): 254-258,264. DOI: 10.13386/j.issn1002-0306.2019.12.041

基于电感耦合等离子质谱检测对虾中重金属及其健康风险评价

Analytical Method Based on Inductively Coupled Plasma Mass Spectrometry and Health Risk of Heavy Metal Elements in Prawns

  • 摘要: 本文建立一种微波辅助消解电感耦合等离子质谱方法用于测定海南市售对虾中重金属的含量并评估其对消费者的健康风险。结果表明在0.4、1.0和2.0 μg/g的加标水平,9种重金属元素的加标回收率处于可接受范围之间。此外本文利用该方法分析了GBW10050(GSB-28)大虾成分标准物质中的9种重元素含量(Cr、Mn、Co、Ni、Cu、Zn、As、Cd、Pb),各元素的测定值与标准值的相对标准偏差小于10%。9种重金属元素在所有的海口市售对虾样品中均有检出,Zn、Cu和Mn三种常量元素的检出率与检出浓度最高,检出率均为100%,其他6种元素为32.2%~96.4%。对虾中Cr和As对消费者的5%、均值、中值和95%致癌风险分别为4.16×10-6、1.06×10-5、9.05×10-6和2.14×10-5,表明存在潜在的风险但尚不严重。对虾中9种重金属对消费者的5%、均值、中值和95%非致癌风险均远小于1,表明市售对虾中的9种重金属对消费者不存在明显的非致癌风险。因此微波辅助消解ICP-MS方法可以有效地测定对虾中重金属的含量的测定;海口市售对虾中重金属含量不存在明显的非致癌风险。

     

    Abstract: A analytical method based on microwave assisted digestion and inductively coupled plasma mass spectrometry for analyzing the concentrations of heavy metal elements in prawns of Haikou city,which were used to assess the health risk for consumers. The results suggested that at the spiked levels of 0.4,1.0 and 2.0 μg/g,the recovery rates of nine metal elements at acceptable levels,indicating a good perform of this method. In addition,the concentrations of 9 heavy metal elements(Cr,Mn,Co,Ni,Cu,Zn,As,Cd and Pb)in GBW10050(GSB-28)prawns were analyzed based on this method,and the relative standard deviations between measured values and true values below 10%. The 9 heavy metal elements were detectable in prawns of Haikou city. The concentrations and detection rates of Zn,Cu and Mn(100%)were the greatest among 9 elements. These for another 6 kind of elements ranged from 32.2% to 96.4%. The 5%,media,mean and 95% cancer risk of Cr and As in prawns for consumers were 4.16×10-6,1.06×10-5,9.05×10-6 and 2.14×10-5,respectively,indicating a potential risk but not serious. The non-cancer risk values of 9 elements were lower than 1,which indicated that no obvious non-carcinogenic effects occurred. In general,the analytical method could effectively analyze heavy metal elements in prawns and the pollution of heavy metal elements in prawns of Haikou city was not serious.

     

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