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中国精品科技期刊2020
张晓梅, 申亮, 苏红, 郭芮, 刘红英. 环境因子对羊栖菜粉吸附Pb2+效果的影响[J]. 食品工业科技, 2018, 39(17): 22-26,32. DOI: 10.13386/j.issn1002-0306.2018.17.004
引用本文: 张晓梅, 申亮, 苏红, 郭芮, 刘红英. 环境因子对羊栖菜粉吸附Pb2+效果的影响[J]. 食品工业科技, 2018, 39(17): 22-26,32. DOI: 10.13386/j.issn1002-0306.2018.17.004
ZHANG Xiao-mei, SHEN Liang, SU Hong, GUO Rui, LIU Hong-ying. Effects of Environmental Factors on Biosorption of Pb2+ by Sargassum fusiforme Powder[J]. Science and Technology of Food Industry, 2018, 39(17): 22-26,32. DOI: 10.13386/j.issn1002-0306.2018.17.004
Citation: ZHANG Xiao-mei, SHEN Liang, SU Hong, GUO Rui, LIU Hong-ying. Effects of Environmental Factors on Biosorption of Pb2+ by Sargassum fusiforme Powder[J]. Science and Technology of Food Industry, 2018, 39(17): 22-26,32. DOI: 10.13386/j.issn1002-0306.2018.17.004

环境因子对羊栖菜粉吸附Pb2+效果的影响

Effects of Environmental Factors on Biosorption of Pb2+ by Sargassum fusiforme Powder

  • 摘要: 以非活性羊栖菜粉为吸附剂,研究了pH、羊栖菜粉浓度、Pb2+初始浓度、干扰离子强度、温度等环境因子的变化对Pb2+去除率及吸附容量的影响。结果显示,Pb2+初始浓度为10 mg/L 时,羊栖菜粉对Pb2+的吸附在pH为2.0~5.0的范围内有较高的去除率,其中pH为3.0左右时,有最高去除率97.05%;羊栖菜粉对Pb2+的去除率随羊栖菜粉浓度的增大而增大,但吸附容量却随之降低,在Pb2+初始浓度为60 mg/L,羊栖菜粉浓度0.5 g/L的条件下,羊栖菜粉对Pb2+的去除率可达94%以上;溶液中其他阳离子的存在会干扰羊栖菜粉对Pb2+的吸附,其中Ca2+比Na+的干扰性强,Cu2+比Cd2+的干扰性强,溶液中多种离子存在时对吸附的干扰性大于单一离子的干扰性,且吸附容量与干扰离子强度的平方根呈一定的线性关系,其相关系数均在0.95以上;在20~60 ℃范围内,适当升高温度有利于吸附过程的进行。羊栖菜粉可应用于Pb2+的去除,且对其表现出良好的吸附性能。

     

    Abstract: The effects of environmental factors such as pH, the concentration of Sargassum fusiforme (S.fusiforme) powder, initial concentration of Pb2+, interference ionic strength and temperature on the removal rate and adsorption capacity of Pb2+ were studied, with the non-active S.fusiforme as adsorbent. When the initial concentration of Pb2+ was 10 mg/L, the adsorption rate of Pb2+ by S.fusiforme powder was higher in the range of pH2.0~5.0, and the highest removal rate was 97.05% at pH3.0. The removal rate of Pb2+ by S.fusiforme powder increases with the increase of S.fusiforme powder concentration, but the adsorption capacity reacts against it. When the initial concentration of Pb2+ was 60 mg/L and the concentration of S.fusiforme powder was 0.5 g/L, the removal rate of Pb2+ was up to 94%. The presence of other cations in the solution interferes with the adsorption of Pb2+ by S.fusiforme powder, in which Ca2+ was more disturbed than Na+ and Cu2+ was more harmful than Cd2+. What's more, the interference of multiple ions in the adsorption was greater than the interference of a single ion, the square root of adsorption capacity and interference ionic strength showed a certain linear relationship, the correlation coefficients were above 0.95.In the range of 20~60℃, an appropriate increase in temperature facilitated the adsorption process. S.fusiforme powder could be used to remove Pb2+and showed a good adsorption performance in the adsorption of Pb2+.

     

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