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中国精品科技期刊2020
壳聚糖溶液的Cross拟合和动态粘弹性分析[J]. 食品工业科技, 2013, (13): 116-118. DOI: 10.13386/j.issn1002-0306.2013.13.041
引用本文: 壳聚糖溶液的Cross拟合和动态粘弹性分析[J]. 食品工业科技, 2013, (13): 116-118. DOI: 10.13386/j.issn1002-0306.2013.13.041
Cross fitting and dynamic viscoelastic analysis of chitosan solution[J]. Science and Technology of Food Industry, 2013, (13): 116-118. DOI: 10.13386/j.issn1002-0306.2013.13.041
Citation: Cross fitting and dynamic viscoelastic analysis of chitosan solution[J]. Science and Technology of Food Industry, 2013, (13): 116-118. DOI: 10.13386/j.issn1002-0306.2013.13.041

壳聚糖溶液的Cross拟合和动态粘弹性分析

Cross fitting and dynamic viscoelastic analysis of chitosan solution

  • 摘要: 在25℃条件下运用Cross模型对壳聚糖溶液(0.005~0.025g/mL)的流动曲线进行了拟合,运用频率扫描和复合波温度扫描分析了壳聚糖溶液的动态粘弹性。结果表明:壳聚糖溶液(0.005~0.025g/mL)符合流变学的Cross模型,且浓度越高,其临界剪切变稀速率越小;损耗模量(G″)始终大于储能模量(G’),且随着扫描频率的增大G″和G’值逐渐接近,低频率扫描条件下表现为类似于流体的粘弹性行为,高频率扫描下有网状交联结构形成。复合粘度随着温度的升高和频率的增大而降低,在温度和振荡频率同时变化的情况下建立了粘度-温度-频率的流变学模型。 

     

    Abstract: The cross model was used to fit the flowability curves of chitosan solution (0.005~0.025g/mL) at 25℃, and the frequency sweep and multiwave temperature sweep were used to analyse the dynamic viscoelasticity of the solution.The results showed that chitosan solutions ( 0.005~0.025g/mL) were all accorded with the cross model of rheology, and the higher the concentration, the smaller the critical shear thinning rate. The loss modulus ( G″) was always greater than the storage modulus ( G') , and the difference between the value of G' and G' approached gradually with the frequency increased.The fluid-like viscoelastic behavior was found at the lower frequency and the network crosslinked structure was formed at the higher frequency. The complex viscosity reduced with the increase of temperature and frequency. The rheological model about viscosity-temperature-frequency was established under the condition of temperature and frequency changed synchronously.

     

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