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中国精品科技期刊2020
电感耦合等离子体质谱法测定巧克力中的18种元素[J]. 食品工业科技, 2013, (08): 88-90. DOI: 10.13386/j.issn1002-0306.2013.08.021
引用本文: 电感耦合等离子体质谱法测定巧克力中的18种元素[J]. 食品工业科技, 2013, (08): 88-90. DOI: 10.13386/j.issn1002-0306.2013.08.021
Study on the determination of 18 elements in chocolate by inductively coupled plasma mass spectrometry[J]. Science and Technology of Food Industry, 2013, (08): 88-90. DOI: 10.13386/j.issn1002-0306.2013.08.021
Citation: Study on the determination of 18 elements in chocolate by inductively coupled plasma mass spectrometry[J]. Science and Technology of Food Industry, 2013, (08): 88-90. DOI: 10.13386/j.issn1002-0306.2013.08.021

电感耦合等离子体质谱法测定巧克力中的18种元素

Study on the determination of 18 elements in chocolate by inductively coupled plasma mass spectrometry

  • 摘要: 采用微波消解处理巧克力样品,建立了电感耦合等离子体质谱(ICP-MS)法测定Na、Mg、P、K、Ca、V、Cr、Mn、Fe、Co、Ni、Cu、Zn、As、Se、Sr、Mo、Pb等18种微量元素的分析方法。样品采用HNO3+H2O2混合酸微波辅助消解,优化了仪器的最佳条件。通过添加标准液进行加标回收,结果表明,所有待测元素的相对标准偏差(RSD)均小于4.60%,回收率在89.60%~106.12%之间。该法准确度高,精密好,并能同时进行多种元素测定等优点,完全能满足样品测定要求,可为巧克力中无机元素的快速检测提供科学依据。 

     

    Abstract: Samples of chocolate were digested by microwave digestion, and trace elements amounts of Na, Mg, P, K, Ca, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Se, Sr, Mo and Pb in sample solutions were determined by inductively coupled plasma mass spectrometry (ICP-MS) . HNO3 +H2O2 were used to achieve the complete decomposition of the organic matrix in a closed - vessel microwave oven . Working parameters of the instrument were optimized. Results showed that the relative standard deviation (RSD) was less than 4.6% for all the elements, and the recovery was 89.60% 106.12% by adding standard recovery experiment. This method was simple, sensitive, precise and could perform simultaneous multi -elements determination of chocolate, which could satisfy the sample examination request and provide scientific rationale for determining inorganic elements of chocolate.

     

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