干酪乳清废水的回收、处理与高值化利用研究进展

张博; 刘悦; 宋礼; 罗丽; 王明阳; 齐燕姣

doi:10.13386/j.issn1002-0306.2022030404

干酪乳清废水的回收、处理与高值化利用研究进展

doi: 10.13386/j.issn1002-0306.2022030404

张博^1,,
刘悦²,
宋礼³,
罗丽³,
王明阳²,
齐燕姣^4, ,

1.
西北民族大学化工学院，甘肃兰州 730000
2.
环境友好复合材料国家民委重点实验室，西北民族大学，甘肃兰州 730000
3.
甘肃华羚乳品股份有限公司，甘肃合作 747000
4.
甘肃省高校环境友好复合材料及生物质利用省级重点实验室，西北民族大学，甘肃兰州 730000

基金项目: 中央高校基本科研业务项目(31920210012)。

详细信息

作者简介:
张博（1998−），男，硕士研究生，研究方向：生物质复合材料加工利用，E-mail：1263690133@qq.com

通讯作者:
齐燕姣（1981−），女，博士，副教授，研究方向：天然产物的开发应用，E-mail：qiajiao@163.com

中图分类号: TS252.9
计量
- 文章访问数: 34
- HTML全文浏览量: 28
- PDF下载量: 4
- 被引次数: 0
出版历程
- 收稿日期: 2022-04-01
- 网络出版日期: 2022-12-16
- 刊出日期: 2023-01-17

Research Progress on Recovery, Treatment and High-value Utilization of Cheese Whey Wastewater

ZHANG Bo^1
,,
LIU Yue²,
SONG Li³,
LUO Li³,
WANG Mingyang²,
QI Yanjiao^{4
, ,}

1.
College of Chemical Engineering, Northwest University for Nationalities, Lanzhou 730000, China
2.
Key Laboratory of Environmentally Friendly Composites State Civil Committee, Northwest University for Nationalities, Lanzhou 730000, China
3.
Gansu Hualing Dairy Co., Ltd., Hezuo 747000, China
4.
Provincial Key Laboratory of Environmentally Friendly Composite Materials and Biomass Utilization in Universities of Gansu Province, Northwest University for Nationalities, Lanzhou 730000, China

摘要

摘要: 干酪生产中产生大量的有机废水，未经处理排放不仅对环境危害极大，同时浪费大量的资源。本文在介绍干酪乳清废水主要成分的基础上，综述了近年来国内外干酪乳清废水的处理方法和资源化利用方面的相关研究报道。着重介绍了干酪乳清废水中主要成分的膜法回收技术、干酪乳清废水的处理技术以及通过物理、化学和生物方法完成由乳清废水向生物燃料（氢气、甲烷和乙醇）、电能和化学商品（乳酸、丙酸和生物聚合物）的转化。针对上述研究现状，展望了干酪乳清废水处理方法的实施前景，旨在将不同回收利用路线进行更合理的整合，以确定干酪乳清废水的最佳处理方式。
- 干酪乳清 /
- 有机废水 /
- 成分 /
- 生物转化 /
- 回收利用
Abstract: Cheese production produces a large amount of organic wastewater, and untreated discharge is extremely harmful to the environment, which also wastes many resources. Based on introducing the main components of cheese whey wastewater, this paper reviews the treatment methods and resource utilization of cheese whey wastewater at home and abroad that have been used in recent years. The paramount manners of whey wastewater treatment and use are the membrane recovery technology of the main components of the cheese whey wastewater, the treatment technology of cheese whey wastewater, and the physical, chemical, and biological conversion of whey wastewater into biofuels (hydrogen, methane, and ethanol), electrical energy, and chemical commodities (lactic acid, propionic acid, and biopolymers). In view of the above research status, the prospect of the implementation of cheese whey wastewater treatment method is prospected, which aims to integrate different recycling routes more reasonably to determine the best treatment method for cheese whey wastewater.
- cheese whey /
- organic wastewater /
- ingredients /
- biotransformation /
- recycling

HTML全文

图 1 干酪生产过程中产生的废液

Figure 1. Waste liquid produced during cheese production

下载: 全尺寸图片幻灯片

表 1 废弃乳清与牛奶营养成分比较

Table 1. Comparison of nutrient composition between waste whey and milk

成分	废弃乳清	牛奶
水分（%）	92.5~93.6^[12]	87~92^[13]
蛋白质（%）	0.6~1.0^[12]	3.0~3.5^[13]
脂肪（%）	0.3~0.5^[12]	3.0~4.0^[13]
乳糖（%）	4.2~4.5^[12]	4.5~5.0^[13]
无机盐（%）	0.5~0.7^[14]	0.6~0.8^[15]
Ca（mg/L）	48^[14]	100~125^[15]
P（mg/L）	50^[14]	86~96^[15]
Fe（mg/L）	-	0.1~0.2^[15]
V_B₁	0.03^[14]	0.03~0.04^[13]
V_B₂	0.10^[14]	0.10~0.25^[13]
注：Ca：钙；P：磷；Fe：铁；V_B₁：维生素B₁；V_B₂：维生素B_2。

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表 2 干酪乳清废水生物处理方法

Table 2. Biological treatment method of cheese whey wastewater

处理废水类型	实验条件				实验结果
处理废水类型	工艺条件	pH	T（℃）	HRT（d）	COD去除率（%）
干酪乳清废水	EGSB	6.82~7.62	25.2~28	6.00~8.00	90
干酪乳清废水	UASB	-	33~37	0.50~2.00	80
干酪乳清废水	EGSB	7.56~8.6	30	0.25~8.00	80
干酪乳清废水	IC	7.0~7.5	35	0.20~0.25	80
干酪乳清废水	CSRT+UASB	6.3	31	0.91~2.36	95
注：HRT：水力停留时间；EGSB：膨胀颗粒污泥床；UASB：上流式厌氧污泥床；COD：化学需氧量；IC：内循环生物反应器；CSRT：连续搅拌釜式反应器。

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表 3 基本控制项目最高允许排放浓度（日均值）

Table 3. Maximum allowable emission concentration of essential control items (daily average)

序号	基本控制项目	一级A标准	一级B标准
1	化学需氧量（COD，mg/L）	50	60
2	生化需氧量（BOD，mg/L）	10	20
3	悬浮物（SS，mg/L）	10	20
4	动植物油（mg/L）	1	3
5	石油类（mg/L）	1	3
6	阴离子表面活性剂（mg/L）	0.5	1
7	总氮（以N计，mg/L）	15	20
8	氨氮（以N计，mg/L）	5（8）	8（15）
9	总磷（以P计，mg/L）	0.5	1
10	色度（稀释倍数，mg/L）	30	30
11	pH	6～9
12	类大肠菌群数（个/L）	10³	10⁴
注:下列情况下按去除率指标执行：当进水COD大于350 mg/L时，去除率应大于60%；BOD大于160 mg/L时，去除率应大于50%。氨氮对应行括号外数值为水温>12 ℃时的控制指标，括号内数值为水温≤12 ℃时的控制指标。

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